Synthesis of polyaniline/Q-CdSe composite via ultrasonically assisted dynamic inverse emulsion polymerization View Full Text


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Article Info

DATE

2011-05

AUTHORS

Yuvaraj Haldorai, Van Hoa Nguyen, Jae-Jin Shim

ABSTRACT

In this communication, polyaniline/CdSe quantum dots (PANI/Q-CdSe) composite was successfully synthesized via in situ ultrasonically assisted dynamic inverse emulsion polymerization. The synthesized PANI-coated Q-CdSe composite was characterized by field emission transmission electron microscopy showed that the CdSe quantum dots have an average size of around ca. 5 nm were dispersed in the PANI matrix. X-ray diffraction, Fourier transform infrared spectrum (FT-IR) and UV-visible spectrum were used to characterize the structure of the obtained PANI/Q-CdSe composite. FT-IR spectra indicated that the polymer was highly doped and existed in conducting emeraldine salt form. The obtained PANI/Q-CdSe composite showed significant improvement in the thermal behavior as indicated by TGA thermograph. The presented dynamic polymerization process is very fast and produces stable colloidal dispersion. This approach provides a one-step, simple, general, and inexpensive method for the preparation of PANI/Q-CdSe composite. More... »

PAGES

849-854

Journal

TITLE

Colloid and Polymer Science

ISSUE

7

VOLUME

289

Author Affiliations

From Grant

  • Identifiers

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    http://scigraph.springernature.com/pub.10.1007/s00396-011-2400-5

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    http://dx.doi.org/10.1007/s00396-011-2400-5

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