Microwave-assisted synthesis and micellization behavior of soy-based copoly(2-oxazoline)s View Full Text


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Article Info

DATE

2006-08

AUTHORS

Richard Hoogenboom, Mark A. M. Leenen, Haiying Huang, Charles-André Fustin, Jean-François Gohy, Ulrich S. Schubert

ABSTRACT

Polymers based on renewable resources are promising candidates for replacing common organic polymers, and thus, for reducing oil consumption. In this contribution we report the microwave-assisted synthesis of block and statistical copolymers from 2-ethyl-2-oxazoline and 2-"soy alkyl"-2-oxazoline via a cationic ring-opening polymerization mechanism. The synthesized copolymers were characterized by gel permeation chromatography and 1H-NMR spectroscopy. The micellization of these amphiphilic copolymers was investigated by dynamic light scattering and atomic force microscopy to examine the effect of hydrophobic block length and monomer distribution on the resulting micellar characteristics. More... »

PAGES

1313-1318

References to SciGraph publications

  • 2002-02-15. Polymers from Renewable Resources in DEGRADABLE ALIPHATIC POLYESTERS
  • 1970. Polymerization of Cyclic Imino Ethers. VIII. Block Copolymers in BLOCK POLYMERS
  • 2005-10-28. Block Copolymer Micelles in BLOCK COPOLYMERS II
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/s00396-006-1496-5

    DOI

    http://dx.doi.org/10.1007/s00396-006-1496-5

    DIMENSIONS

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    PUBMED

    https://www.ncbi.nlm.nih.gov/pubmed/24058241


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