A tunable green alkaline-earth silicon-oxynitride solid solution (Ca1−xSrx)Si2O2N2:Eu2+ and its application in LED View Full Text


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Article Info

DATE

2008-12

AUTHORS

M. Zhang, J. Wang, Z. Zhang, Q. Zhang, Q. Su

ABSTRACT

A series of (Ca1−x−ySrx)Si2O2N2:yEu2+ (x=0.0–0.97, y=0.03) phosphors were synthesized by high-temperature solid-state reaction. The XRD patterns confirm the formation of a solid solution of (Ca1−x−ySrx)Si2O2N2:yEu2+. An intense tunable green light is observed with the increasing ratio of Sr/Ca. With an increase in x, the excitation and emission spectra show a redshift and blueshift, respectively, due to large centroid shift and small Stokes shift. The temperature dependent luminescence is also investigated in the temperature range of 77–450 K. The Huang–Rhys factor and the thermal-quenching temperature are determined. Intense green LEDs were successfully fabricated based on the (Ca1−x−ySrx)Si2O2N2:yEu2+ phosphor and near-ultraviolet (∼395 nm) GaN/blue (460 nm) InGaN chips. All the results indicate that the solid solution (Ca1−x−ySrx)Si2O2N2:yEu2+ is a promising phosphor applicable to near-UV and blue LEDs for solid-state lighting. More... »

PAGES

829-835

References to SciGraph publications

  • 1997. The Blue Laser Diode, GaN Based Light Emitters and Lasers in NONE
  • 1994-01. Phase relationships in the Sr-Si-O-N system in JOURNAL OF MATERIALS SCIENCE LETTERS
  • 1985-03. Phase relations of the Si3N4-AIN-CaO system in JOURNAL OF MATERIALS SCIENCE LETTERS
  • Journal

    TITLE

    Applied Physics B

    ISSUE

    4

    VOLUME

    93

    Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/s00340-008-3232-y

    DOI

    http://dx.doi.org/10.1007/s00340-008-3232-y

    DIMENSIONS

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