Cavity-enhanced absorption: detection of nitrogen dioxide and iodine monoxide using a violet laser diode View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2003-06

AUTHORS

V.L. Kasyutich, C.S.E. Bale, C.E. Canosa-Mas, C. Pfrang, S. Vaughan, R.P. Wayne

ABSTRACT

We present an application of cavity-enhanced absorption spectroscopy with an off-axis alignment of the cavity formed by two spherical mirrors and with time integration of the cavity-output intensity for detection of nitrogen dioxide (NO2) and iodine monoxide (IO) radicals using a violet laser diode at λ=404.278 nm. A noise-equivalent (1σ≡ root-mean-square variation of the signal) fractional absorption for one optical pass of 4.5×10-8 was demonstrated with a mirror reflectivity of ∼0.99925, a cavity length of 0.22 m and a lock-in-amplifier time constant of 3 s. Noise-equivalent detection sensitivities towards nitrogen dioxide of 1.8×1010 molecule cm-3 and towards the IO radical of 3.3×109 molecule cm-3 were achieved in flow tubes with an inner diameter of 4 cm for a lock-in-amplifier time constant of 3 s. Alkyl peroxy radicals were detected using chemical titration with excess nitric oxide (RO2+NO→RO+NO2). Measurement of oxygen-atom concentrations was accomplished by determining the depletion of NO2 in the reaction NO2+O→NO+O2. Noise-equivalent concentrations of alkyl peroxy radicals and oxygen atoms were 3×1010 molecule cm-3 in the discharge-flow-tube experiments. More... »

PAGES

691-697

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s00340-003-1153-3

DOI

http://dx.doi.org/10.1007/s00340-003-1153-3

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1037171448


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "University of Oxford", 
          "id": "https://www.grid.ac/institutes/grid.4991.5", 
          "name": [
            "Physical and Theoretical Chemistry Laboratory, University of Oxford, South Parks Road, Oxford OX1 3QZ, UK, UK"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Kasyutich", 
        "givenName": "V.L.", 
        "id": "sg:person.015022225306.08", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015022225306.08"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "University of Oxford", 
          "id": "https://www.grid.ac/institutes/grid.4991.5", 
          "name": [
            "Physical and Theoretical Chemistry Laboratory, University of Oxford, South Parks Road, Oxford OX1 3QZ, UK, UK"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Bale", 
        "givenName": "C.S.E.", 
        "id": "sg:person.011320170437.24", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011320170437.24"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "University of Oxford", 
          "id": "https://www.grid.ac/institutes/grid.4991.5", 
          "name": [
            "Physical and Theoretical Chemistry Laboratory, University of Oxford, South Parks Road, Oxford OX1 3QZ, UK, UK"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Canosa-Mas", 
        "givenName": "C.E.", 
        "id": "sg:person.016260302615.02", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016260302615.02"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "University of Oxford", 
          "id": "https://www.grid.ac/institutes/grid.4991.5", 
          "name": [
            "Physical and Theoretical Chemistry Laboratory, University of Oxford, South Parks Road, Oxford OX1 3QZ, UK, UK"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Pfrang", 
        "givenName": "C.", 
        "id": "sg:person.01151171124.34", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01151171124.34"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "University of Oxford", 
          "id": "https://www.grid.ac/institutes/grid.4991.5", 
          "name": [
            "Physical and Theoretical Chemistry Laboratory, University of Oxford, South Parks Road, Oxford OX1 3QZ, UK, UK"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Vaughan", 
        "givenName": "S.", 
        "id": "sg:person.01354516641.64", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01354516641.64"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "University of Oxford", 
          "id": "https://www.grid.ac/institutes/grid.4991.5", 
          "name": [
            "Physical and Theoretical Chemistry Laboratory, University of Oxford, South Parks Road, Oxford OX1 3QZ, UK, UK"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Wayne", 
        "givenName": "R.P.", 
        "id": "sg:person.011712010171.42", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011712010171.42"
        ], 
        "type": "Person"
      }
    ], 
    "datePublished": "2003-06", 
    "datePublishedReg": "2003-06-01", 
    "description": "We present an application of cavity-enhanced absorption spectroscopy with an off-axis alignment of the cavity formed by two spherical mirrors and with time integration of the cavity-output intensity for detection of nitrogen dioxide (NO2) and iodine monoxide (IO) radicals using a violet laser diode at \u03bb=404.278 nm. A noise-equivalent (1\u03c3\u2261 root-mean-square variation of the signal) fractional absorption for one optical pass of 4.5\u00d710-8 was demonstrated with a mirror reflectivity of \u223c0.99925, a cavity length of 0.22 m and a lock-in-amplifier time constant of 3 s. Noise-equivalent detection sensitivities towards nitrogen dioxide of 1.8\u00d71010 molecule cm-3 and towards the IO radical of 3.3\u00d7109 molecule cm-3 were achieved in flow tubes with an inner diameter of 4 cm for a lock-in-amplifier time constant of 3 s. Alkyl peroxy radicals were detected using chemical titration with excess nitric oxide (RO2+NO\u2192RO+NO2). Measurement of oxygen-atom concentrations was accomplished by determining the depletion of NO2 in the reaction NO2+O\u2192NO+O2. Noise-equivalent concentrations of alkyl peroxy radicals and oxygen atoms were 3\u00d71010 molecule cm-3 in the discharge-flow-tube experiments.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/s00340-003-1153-3", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1312262", 
        "issn": [
          "0946-2171", 
          "1432-0649"
        ], 
        "name": "Applied Physics B", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "6", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "76"
      }
    ], 
    "name": "Cavity-enhanced absorption: detection of nitrogen dioxide and iodine monoxide using a violet laser diode", 
    "pagination": "691-697", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "b1124a77f8c4ef5e8e33575da36bae38127cbb8424a425aad09d09df7974794a"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s00340-003-1153-3"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1037171448"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s00340-003-1153-3", 
      "https://app.dimensions.ai/details/publication/pub.1037171448"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T23:19", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8693_00000490.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1007/s00340-003-1153-3"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s00340-003-1153-3'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s00340-003-1153-3'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s00340-003-1153-3'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s00340-003-1153-3'


 

This table displays all metadata directly associated to this object as RDF triples.

96 TRIPLES      20 PREDICATES      27 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s00340-003-1153-3 schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author Ncf3b0597ea5542b98213876e39c1f0e3
4 schema:datePublished 2003-06
5 schema:datePublishedReg 2003-06-01
6 schema:description We present an application of cavity-enhanced absorption spectroscopy with an off-axis alignment of the cavity formed by two spherical mirrors and with time integration of the cavity-output intensity for detection of nitrogen dioxide (NO2) and iodine monoxide (IO) radicals using a violet laser diode at λ=404.278 nm. A noise-equivalent (1σ≡ root-mean-square variation of the signal) fractional absorption for one optical pass of 4.5×10-8 was demonstrated with a mirror reflectivity of ∼0.99925, a cavity length of 0.22 m and a lock-in-amplifier time constant of 3 s. Noise-equivalent detection sensitivities towards nitrogen dioxide of 1.8×1010 molecule cm-3 and towards the IO radical of 3.3×109 molecule cm-3 were achieved in flow tubes with an inner diameter of 4 cm for a lock-in-amplifier time constant of 3 s. Alkyl peroxy radicals were detected using chemical titration with excess nitric oxide (RO2+NO→RO+NO2). Measurement of oxygen-atom concentrations was accomplished by determining the depletion of NO2 in the reaction NO2+O→NO+O2. Noise-equivalent concentrations of alkyl peroxy radicals and oxygen atoms were 3×1010 molecule cm-3 in the discharge-flow-tube experiments.
7 schema:genre research_article
8 schema:inLanguage en
9 schema:isAccessibleForFree false
10 schema:isPartOf N43144a0e90594192891586f572ab966c
11 N459f31227af24a7cab27819ba5967a7e
12 sg:journal.1312262
13 schema:name Cavity-enhanced absorption: detection of nitrogen dioxide and iodine monoxide using a violet laser diode
14 schema:pagination 691-697
15 schema:productId Naa52a1c20628491c9760ba76980be5ff
16 Nb7874e2f3c2e4742ab4fa1dc3520a571
17 Nc66fe7198240486baf9e3c117b65a509
18 schema:sameAs https://app.dimensions.ai/details/publication/pub.1037171448
19 https://doi.org/10.1007/s00340-003-1153-3
20 schema:sdDatePublished 2019-04-10T23:19
21 schema:sdLicense https://scigraph.springernature.com/explorer/license/
22 schema:sdPublisher Nc3f81863aa294e3381327251dfabfeb2
23 schema:url http://link.springer.com/10.1007/s00340-003-1153-3
24 sgo:license sg:explorer/license/
25 sgo:sdDataset articles
26 rdf:type schema:ScholarlyArticle
27 N43144a0e90594192891586f572ab966c schema:volumeNumber 76
28 rdf:type schema:PublicationVolume
29 N44a595c6d92142959f3648c0abcffeb5 rdf:first sg:person.016260302615.02
30 rdf:rest Nc84dd7eb78874e8cb2312083c2ff3795
31 N459f31227af24a7cab27819ba5967a7e schema:issueNumber 6
32 rdf:type schema:PublicationIssue
33 N6b04c45508aa4ba997a15a0a0dc5a53a rdf:first sg:person.011320170437.24
34 rdf:rest N44a595c6d92142959f3648c0abcffeb5
35 N92ff613c1d3247c396db4e0bba268be5 rdf:first sg:person.011712010171.42
36 rdf:rest rdf:nil
37 Na07d9c70adf44372a17a3a573fd336c3 rdf:first sg:person.01354516641.64
38 rdf:rest N92ff613c1d3247c396db4e0bba268be5
39 Naa52a1c20628491c9760ba76980be5ff schema:name dimensions_id
40 schema:value pub.1037171448
41 rdf:type schema:PropertyValue
42 Nb7874e2f3c2e4742ab4fa1dc3520a571 schema:name readcube_id
43 schema:value b1124a77f8c4ef5e8e33575da36bae38127cbb8424a425aad09d09df7974794a
44 rdf:type schema:PropertyValue
45 Nc3f81863aa294e3381327251dfabfeb2 schema:name Springer Nature - SN SciGraph project
46 rdf:type schema:Organization
47 Nc66fe7198240486baf9e3c117b65a509 schema:name doi
48 schema:value 10.1007/s00340-003-1153-3
49 rdf:type schema:PropertyValue
50 Nc84dd7eb78874e8cb2312083c2ff3795 rdf:first sg:person.01151171124.34
51 rdf:rest Na07d9c70adf44372a17a3a573fd336c3
52 Ncf3b0597ea5542b98213876e39c1f0e3 rdf:first sg:person.015022225306.08
53 rdf:rest N6b04c45508aa4ba997a15a0a0dc5a53a
54 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
55 schema:name Chemical Sciences
56 rdf:type schema:DefinedTerm
57 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
58 schema:name Physical Chemistry (incl. Structural)
59 rdf:type schema:DefinedTerm
60 sg:journal.1312262 schema:issn 0946-2171
61 1432-0649
62 schema:name Applied Physics B
63 rdf:type schema:Periodical
64 sg:person.011320170437.24 schema:affiliation https://www.grid.ac/institutes/grid.4991.5
65 schema:familyName Bale
66 schema:givenName C.S.E.
67 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011320170437.24
68 rdf:type schema:Person
69 sg:person.01151171124.34 schema:affiliation https://www.grid.ac/institutes/grid.4991.5
70 schema:familyName Pfrang
71 schema:givenName C.
72 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01151171124.34
73 rdf:type schema:Person
74 sg:person.011712010171.42 schema:affiliation https://www.grid.ac/institutes/grid.4991.5
75 schema:familyName Wayne
76 schema:givenName R.P.
77 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011712010171.42
78 rdf:type schema:Person
79 sg:person.01354516641.64 schema:affiliation https://www.grid.ac/institutes/grid.4991.5
80 schema:familyName Vaughan
81 schema:givenName S.
82 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01354516641.64
83 rdf:type schema:Person
84 sg:person.015022225306.08 schema:affiliation https://www.grid.ac/institutes/grid.4991.5
85 schema:familyName Kasyutich
86 schema:givenName V.L.
87 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015022225306.08
88 rdf:type schema:Person
89 sg:person.016260302615.02 schema:affiliation https://www.grid.ac/institutes/grid.4991.5
90 schema:familyName Canosa-Mas
91 schema:givenName C.E.
92 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016260302615.02
93 rdf:type schema:Person
94 https://www.grid.ac/institutes/grid.4991.5 schema:alternateName University of Oxford
95 schema:name Physical and Theoretical Chemistry Laboratory, University of Oxford, South Parks Road, Oxford OX1 3QZ, UK, UK
96 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...