Ferrocene–zeolite interactions measured by inelastic neutron scattering View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2002-12

AUTHORS

E. Kemner, A.R. Overweg, U.A. Jayasooriya, S.F. Parker, I.M. de Schepper, G.J. Kearley

ABSTRACT

. The measured inelastic neutron scattering vibrational spectrum of ferrocene, Fe(C5H5)2, in the supercages of KY zeolite is compared with that of solid ferrocene. Only small differences between these spectra are observed. It is shown that these differences are compatible with those calculated by ab initio calculations taking account only of the geometry of the ferrocene and ignoring the molecular environment. We conclude that the ferrocene–zeolite interactions are rather weak, and comparable with the intermolecular interactions in solid ferrocene. More... »

PAGES

s1368-s1370

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s003390101237

DOI

http://dx.doi.org/10.1007/s003390101237

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1049202552


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