Ontology type: schema:ScholarlyArticle
1999-05
AUTHORSKarel Dušek, Ján Šomvársky, Mirka Smrčková, William J. Simonsick Jr., Lech Wilczek
ABSTRACTA kinetic model of formation of hyperbranched polymers by step polyaddition of a BAf monomer including cyclization was developed. Reactions between acyclic-acyclic and acyclic-cyclic molecules and cyclization within acyclic molecules were considered. For cyclization within isomers of an x-mer, a bridging function between linear and spherical structures was used. Fractions of cyclic x-mers are predicted to increase with increasing degree of polymerization x and overall conversion of B groups. High fractions of cyclics were found in poly[2,2-bis(hydroxymethyl)propanoic acid] (poly (dimethylolpropionic acid)) by mass spectroscopy (ESI/FT MS) in a reasonable agreement with the model. More... »
PAGES489-496
http://scigraph.springernature.com/pub.10.1007/s002890050493
DOIhttp://dx.doi.org/10.1007/s002890050493
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