Role of cyclization in the degree-of-polymerization distribution of hyperbranched polymers Modelling and experiments View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1999-05

AUTHORS

Karel Dušek, Ján Šomvársky, Mirka Smrčková, William J. Simonsick Jr., Lech Wilczek

ABSTRACT

A kinetic model of formation of hyperbranched polymers by step polyaddition of a BAf monomer including cyclization was developed. Reactions between acyclic-acyclic and acyclic-cyclic molecules and cyclization within acyclic molecules were considered. For cyclization within isomers of an x-mer, a bridging function between linear and spherical structures was used. Fractions of cyclic x-mers are predicted to increase with increasing degree of polymerization x and overall conversion of B groups. High fractions of cyclics were found in poly[2,2-bis(hydroxymethyl)propanoic acid] (poly (dimethylolpropionic acid)) by mass spectroscopy (ESI/FT MS) in a reasonable agreement with the model. More... »

PAGES

489-496

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s002890050493

DOI

http://dx.doi.org/10.1007/s002890050493

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1010341201


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0303", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Macromolecular and Materials Chemistry", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Institute of Macromolecular Chemistry", 
          "id": "https://www.grid.ac/institutes/grid.424999.b", 
          "name": [
            "Institute of Macromolecular Chemistry, Academy of Sciences of the Czech Republic, CR-162 06 Prague 6, Czech Republic, XX"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Du\u0161ek", 
        "givenName": "Karel", 
        "id": "sg:person.01151570140.64", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01151570140.64"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Macromolecular Chemistry", 
          "id": "https://www.grid.ac/institutes/grid.424999.b", 
          "name": [
            "Institute of Macromolecular Chemistry, Academy of Sciences of the Czech Republic, CR-162 06 Prague 6, Czech Republic, XX"
          ], 
          "type": "Organization"
        }, 
        "familyName": "\u0160omv\u00e1rsky", 
        "givenName": "J\u00e1n", 
        "id": "sg:person.011560071471.34", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011560071471.34"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Macromolecular Chemistry", 
          "id": "https://www.grid.ac/institutes/grid.424999.b", 
          "name": [
            "Institute of Macromolecular Chemistry, Academy of Sciences of the Czech Republic, CR-162 06 Prague 6, Czech Republic, XX"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Smr\u010dkov\u00e1", 
        "givenName": "Mirka", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "DuPont (United States)", 
          "id": "https://www.grid.ac/institutes/grid.416832.a", 
          "name": [
            "Marshall Laboratory, Du Pont de Nemours, Philadelphia, PA 19146, USA, MH"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Simonsick Jr.", 
        "givenName": "William J.", 
        "id": "sg:person.013045674747.70", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013045674747.70"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "DuPont (United States)", 
          "id": "https://www.grid.ac/institutes/grid.416832.a", 
          "name": [
            "Central Research & Development Department, Experimental Station, Du Pont de Nemours, Wilmington, DE 19880-0328, USA, US"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Wilczek", 
        "givenName": "Lech", 
        "id": "sg:person.011364511125.20", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011364511125.20"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1016/b978-0-08-096701-1.00242-1", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1041030684"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1119/1.1973944", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1062244419"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "1999-05", 
    "datePublishedReg": "1999-05-01", 
    "description": " A kinetic model of formation of hyperbranched polymers by step polyaddition of a BAf monomer including cyclization was developed. Reactions between acyclic-acyclic and acyclic-cyclic molecules and cyclization within acyclic molecules were considered. For cyclization within isomers of an x-mer, a bridging function between linear and spherical structures was used. Fractions of cyclic x-mers are predicted to increase with increasing degree of polymerization x and overall conversion of B groups. High fractions of cyclics were found in poly[2,2-bis(hydroxymethyl)propanoic acid] (poly (dimethylolpropionic acid)) by mass spectroscopy (ESI/FT MS) in a reasonable agreement with the model.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/s002890050493", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1123778", 
        "issn": [
          "0170-0839", 
          "1436-2449"
        ], 
        "name": "Polymer Bulletin", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "4", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "42"
      }
    ], 
    "name": "Role of cyclization in the degree-of-polymerization distribution of hyperbranched polymers Modelling and experiments", 
    "pagination": "489-496", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "31445df6a7e09c15e220130ce2d09552a2c30c599276de95de0db06e080b3747"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s002890050493"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1010341201"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s002890050493", 
      "https://app.dimensions.ai/details/publication/pub.1010341201"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-11T09:41", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000346_0000000346/records_99843_00000000.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://link.springer.com/10.1007%2Fs002890050493"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s002890050493'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s002890050493'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s002890050493'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s002890050493'


 

This table displays all metadata directly associated to this object as RDF triples.

98 TRIPLES      21 PREDICATES      29 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s002890050493 schema:about anzsrc-for:03
2 anzsrc-for:0303
3 schema:author N91e49f0fa2c6422c954e109bd402ad3a
4 schema:citation https://doi.org/10.1016/b978-0-08-096701-1.00242-1
5 https://doi.org/10.1119/1.1973944
6 schema:datePublished 1999-05
7 schema:datePublishedReg 1999-05-01
8 schema:description A kinetic model of formation of hyperbranched polymers by step polyaddition of a BAf monomer including cyclization was developed. Reactions between acyclic-acyclic and acyclic-cyclic molecules and cyclization within acyclic molecules were considered. For cyclization within isomers of an x-mer, a bridging function between linear and spherical structures was used. Fractions of cyclic x-mers are predicted to increase with increasing degree of polymerization x and overall conversion of B groups. High fractions of cyclics were found in poly[2,2-bis(hydroxymethyl)propanoic acid] (poly (dimethylolpropionic acid)) by mass spectroscopy (ESI/FT MS) in a reasonable agreement with the model.
9 schema:genre research_article
10 schema:inLanguage en
11 schema:isAccessibleForFree false
12 schema:isPartOf N534ca9e74d13421b935f59b547908f26
13 N98803af8f0cf457ba34c33b3324dbe5b
14 sg:journal.1123778
15 schema:name Role of cyclization in the degree-of-polymerization distribution of hyperbranched polymers Modelling and experiments
16 schema:pagination 489-496
17 schema:productId N04a60d203d39461b898b7af0226f57cb
18 N33d657c1375f41d0b9f67cb4c9f80087
19 N673f3f70d6084dbf928939075fba2196
20 schema:sameAs https://app.dimensions.ai/details/publication/pub.1010341201
21 https://doi.org/10.1007/s002890050493
22 schema:sdDatePublished 2019-04-11T09:41
23 schema:sdLicense https://scigraph.springernature.com/explorer/license/
24 schema:sdPublisher Nd1bf83acf30146bfb38096dc7aa9e844
25 schema:url https://link.springer.com/10.1007%2Fs002890050493
26 sgo:license sg:explorer/license/
27 sgo:sdDataset articles
28 rdf:type schema:ScholarlyArticle
29 N029e0e5f41f14085a0d44ea04b7c9a54 rdf:first sg:person.011364511125.20
30 rdf:rest rdf:nil
31 N04a60d203d39461b898b7af0226f57cb schema:name doi
32 schema:value 10.1007/s002890050493
33 rdf:type schema:PropertyValue
34 N337680374bdd44a6afda62a8a30471a4 rdf:first Nf88052992c6f424d80cf45eef042ba81
35 rdf:rest N9121b0dbb7a44965a2210c4df5fc10e9
36 N33d657c1375f41d0b9f67cb4c9f80087 schema:name dimensions_id
37 schema:value pub.1010341201
38 rdf:type schema:PropertyValue
39 N534ca9e74d13421b935f59b547908f26 schema:issueNumber 4
40 rdf:type schema:PublicationIssue
41 N673f3f70d6084dbf928939075fba2196 schema:name readcube_id
42 schema:value 31445df6a7e09c15e220130ce2d09552a2c30c599276de95de0db06e080b3747
43 rdf:type schema:PropertyValue
44 N9121b0dbb7a44965a2210c4df5fc10e9 rdf:first sg:person.013045674747.70
45 rdf:rest N029e0e5f41f14085a0d44ea04b7c9a54
46 N91e49f0fa2c6422c954e109bd402ad3a rdf:first sg:person.01151570140.64
47 rdf:rest Nc4541da124474e9db37e8c53b01de315
48 N98803af8f0cf457ba34c33b3324dbe5b schema:volumeNumber 42
49 rdf:type schema:PublicationVolume
50 Nc4541da124474e9db37e8c53b01de315 rdf:first sg:person.011560071471.34
51 rdf:rest N337680374bdd44a6afda62a8a30471a4
52 Nd1bf83acf30146bfb38096dc7aa9e844 schema:name Springer Nature - SN SciGraph project
53 rdf:type schema:Organization
54 Nf88052992c6f424d80cf45eef042ba81 schema:affiliation https://www.grid.ac/institutes/grid.424999.b
55 schema:familyName Smrčková
56 schema:givenName Mirka
57 rdf:type schema:Person
58 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
59 schema:name Chemical Sciences
60 rdf:type schema:DefinedTerm
61 anzsrc-for:0303 schema:inDefinedTermSet anzsrc-for:
62 schema:name Macromolecular and Materials Chemistry
63 rdf:type schema:DefinedTerm
64 sg:journal.1123778 schema:issn 0170-0839
65 1436-2449
66 schema:name Polymer Bulletin
67 rdf:type schema:Periodical
68 sg:person.011364511125.20 schema:affiliation https://www.grid.ac/institutes/grid.416832.a
69 schema:familyName Wilczek
70 schema:givenName Lech
71 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011364511125.20
72 rdf:type schema:Person
73 sg:person.01151570140.64 schema:affiliation https://www.grid.ac/institutes/grid.424999.b
74 schema:familyName Dušek
75 schema:givenName Karel
76 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01151570140.64
77 rdf:type schema:Person
78 sg:person.011560071471.34 schema:affiliation https://www.grid.ac/institutes/grid.424999.b
79 schema:familyName Šomvársky
80 schema:givenName Ján
81 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011560071471.34
82 rdf:type schema:Person
83 sg:person.013045674747.70 schema:affiliation https://www.grid.ac/institutes/grid.416832.a
84 schema:familyName Simonsick Jr.
85 schema:givenName William J.
86 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013045674747.70
87 rdf:type schema:Person
88 https://doi.org/10.1016/b978-0-08-096701-1.00242-1 schema:sameAs https://app.dimensions.ai/details/publication/pub.1041030684
89 rdf:type schema:CreativeWork
90 https://doi.org/10.1119/1.1973944 schema:sameAs https://app.dimensions.ai/details/publication/pub.1062244419
91 rdf:type schema:CreativeWork
92 https://www.grid.ac/institutes/grid.416832.a schema:alternateName DuPont (United States)
93 schema:name Central Research & Development Department, Experimental Station, Du Pont de Nemours, Wilmington, DE 19880-0328, USA, US
94 Marshall Laboratory, Du Pont de Nemours, Philadelphia, PA 19146, USA, MH
95 rdf:type schema:Organization
96 https://www.grid.ac/institutes/grid.424999.b schema:alternateName Institute of Macromolecular Chemistry
97 schema:name Institute of Macromolecular Chemistry, Academy of Sciences of the Czech Republic, CR-162 06 Prague 6, Czech Republic, XX
98 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...