Synthesis of N-vinylformamide and 1-vinyl-(1-methacryloyl)-3,5-dimethylpyrazole copolymers and their extraction ability in relation to histidine in water-salt media View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2017-06-12

AUTHORS

Vyacheslav A. Kuznetsov, Maria S. Lavlinskaya, Irina V. Ostankova, Gennadiy V. Shatalov, Khidmet S. Shikhaliev, Elena A. Ryzhkova

ABSTRACT

Copolymers of N-vinylformamide (VF) with 1-vinyl-3,5-dimethylpyrazole (VDMP) and 1-methacryloyl-3,5-dimethylpyrazole (MDMP) are synthesized by free radical copolymerization in dioxane. The compositions of copolymers are determined by means of UV-spectroscopy and FTIR, and copolymerization constants r1 and r2 are calculated. N-vinylformamide demonstrates higher reactivity than pyrazole-containing monomers in both cases. Solubility of the synthesized copolymers in water was studied. VF–VDMP copolymers are water soluble at VF content higher than 0.65 molar fractions, and VF–MDMP copolymers—at VF content over 0.8 molar fractions. The formation of complexes between water-soluble copolymers and essential α-amino acid histidine in aqueous solutions is confirmed by UV-spectroscopy, FTIR, dynamic light scattering (DLS), and transition electron microscopy. It is found via DLS that the interactions between the amino acid with copolymer macromolecules lead to conformation changes in macromolecular coils. It is shown that VF–VDMP and VF–MDMP copolymers are effective extragents for histidine. Extraction is carried out at different pH values. The highest extraction degree (98%) is achieved in an acidic medium. More... »

PAGES

1237-1251

References to SciGraph publications

  • 2016-02-25. Aqueous dispersions of cross-linked poly-N-vinylcaprolactam stabilized with hydrophobically modified polyacrylamide: synthesis, colloidal stability, and thermosensitive properties in COLLOID AND POLYMER SCIENCE
  • 2002-02. The surface tension of aqueous polyvinylamine and copolymers with N-vinylformamide in COLLOID AND POLYMER SCIENCE
  • 2012-04-24. Luminophore-containing polymer particles: Synthesis and optical properties of thin films on their basis in NANOBIOTECHNOLOGY REPORTS
  • 2016-07-26. Polymer brush synthesis on surface modified carbon nanotubes via in situ emulsion polymerization in COLLOID AND POLYMER SCIENCE
  • 2003-02-05. High-pressure studies on the coacervation of copoly(N-vinylformamide–vinylacetate) and copoly(N-vinylacetylamide–vinylacetate) in COLLOID AND POLYMER SCIENCE
  • 2015-02. Low-basic anion exchangers based on glycidyl methacrylate for selective sorption of endotoxin in RUSSIAN JOURNAL OF APPLIED CHEMISTRY
  • 2015-10-26. Synthesis and characterization of multi-sensitive microgel-based polyampholyte hydrogels with high mechanical strength in COLLOID AND POLYMER SCIENCE
  • 2012-08. Hydrodynamic, molecular, and conformational characteristics of macromolecules of a random copolymer of N-Methyl-N-vinylacetamide and N-Methyl-N-vinylamine Hydrochloride in RUSSIAN JOURNAL OF APPLIED CHEMISTRY
  • 2007-08. Copolymerization of N-vinylcaprolactam with N-vinyl(benz)imidazoles and the properties of aqueous solutions of the copolymers in POLYMER SCIENCE, SERIES B
  • 1999. Heterocyclic Chemistry, Volume II: Five-Membered Heterocycles in NONE
  • 2010-09. Properties of aqueous solutions containing blends of poly-N-vinylformamide with carboxymethyl cellulose of various degrees of ionization and of composite films of these polymers in RUSSIAN JOURNAL OF APPLIED CHEMISTRY
  • 2006-10. Bifunctional monodisperse microspheres of copolymers of methyl methacrylate and N-vinylformamide in RUSSIAN JOURNAL OF APPLIED CHEMISTRY
  • 2002-02. Synthesis and flocculation performance of graft copolymer of N -vinylformamide and poly(dimethylaminoethyl methacrylate) methyl chloride macromonomer in COLLOID AND POLYMER SCIENCE
  • 2008-01-05. Low Cationic Proportion Ampholytic Polymer: Synthesis, Solution Properties and Interaction with Anionic Surfactant in POLYMER BULLETIN
  • 2012-09. Compatibility of carboxymethyl cellulose ionized to various degrees with poly-N-vinylformamide in composite films in RUSSIAN JOURNAL OF APPLIED CHEMISTRY
  • 2016-01. Copolymers of N-vinylcaprolactam with 1-vinyl- and 1-methacryloyl-3,5-dimethylpyrazole as sorbents of essential α-amino acids in liquid- and solid-phase extraction in RUSSIAN JOURNAL OF APPLIED CHEMISTRY
  • 2015-11-20. One-step synthesis of triarm block copolymers by simultaneous atom transfer radical and ring-opening polymerization in POLYMER BULLETIN
  • 2002-01. Stability and thermosensitive properties of various poly (N-vinylcaprolactam) microgels in COLLOID AND POLYMER SCIENCE
  • 2004-01-01. Poly(Vinylformamide- co -Vinylamine)/Inorganic Oxide Hybrid Materials in POLYELECTROLYTES WITH DEFINED MOLECULAR ARCHITECTURE I
  • 2002-11-13. Amino Acid Production Processes in MICROBIAL PRODUCTION OF L-AMINO ACIDS
  • 2011-05-27. Characteristics of composite films based on methyl cellulose and poly(N-vinylformamide) prepared from solutions in water and dimethyl sulfoxide in POLYMER SCIENCE, SERIES A
  • 1987-02. Synthesis of vinylazole copolymers and their physiological activity in PHARMACEUTICAL CHEMISTRY JOURNAL
  • 2013-02. Extraction of biologically active compounds in two-phase aqueous systems based on poly-N-vinylpyrrolidone in DOKLADY CHEMISTRY
  • 2009-04. Radical copolymerization of N-vinylformamide with unsaturated carboxylic acids in RUSSIAN JOURNAL OF APPLIED CHEMISTRY
  • 2006-03. Immunomodulating properties of homo-and copolymers of N-vinylamides in PHARMACEUTICAL CHEMISTRY JOURNAL
  • 2016-02-16. Separation of Binary Mixtures of Histidine, Proline, and Methionine in Extraction Systems Based on Water-Soluble Polymers of Vinyl Series in JOURNAL OF ANALYTICAL CHEMISTRY
  • 1981. Bioorganic Chemistry, A Chemical Approach to Enzyme Action in NONE
  • 2014-03. Copolymerization of styrene with N-vinylformamide and ethylene glycol dimethacrylate and characteristics of the formed particles in POLYMER SCIENCE, SERIES B
  • 2015-01-21. Cross-linked poly(methyl methacrylate) particles with surface amino groups in COLLOID JOURNAL
  • 2003-05-06. N-Vinylformamide as a route to amine-containing latexes and microgels in COLLOID AND POLYMER SCIENCE
  • 2005-08. Synthesis of Copolymers of Vinylformamide with N-Methacryloylglucosamine in RUSSIAN JOURNAL OF APPLIED CHEMISTRY
  • 2007-05. Synthesis and hydrodynamic and molecular characteristics of N-methacryloylglucosamine N-vinylformamide copolymers in RUSSIAN JOURNAL OF APPLIED CHEMISTRY
  • 2008-11-21. Self-assembly of monodisperse nanoparticles of styrene copolymers with N-vinylformamide into periodic colloidal structures in HIGH ENERGY CHEMISTRY
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/s00289-017-2091-2

    DOI

    http://dx.doi.org/10.1007/s00289-017-2091-2

    DIMENSIONS

    https://app.dimensions.ai/details/publication/pub.1085981959


    Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
    Incoming Citations Browse incoming citations for this publication using opencitations.net

    JSON-LD is the canonical representation for SciGraph data.

    TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

    [
      {
        "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
        "about": [
          {
            "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
            "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
            "name": "Chemical Sciences", 
            "type": "DefinedTerm"
          }, 
          {
            "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0303", 
            "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
            "name": "Macromolecular and Materials Chemistry", 
            "type": "DefinedTerm"
          }
        ], 
        "author": [
          {
            "affiliation": {
              "alternateName": "Voronezh State University, Voronezh, Russia", 
              "id": "http://www.grid.ac/institutes/grid.20567.36", 
              "name": [
                "Voronezh State University, Voronezh, Russia"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Kuznetsov", 
            "givenName": "Vyacheslav A.", 
            "id": "sg:person.014675706571.50", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014675706571.50"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Voronezh State University, Voronezh, Russia", 
              "id": "http://www.grid.ac/institutes/grid.20567.36", 
              "name": [
                "Voronezh State University, Voronezh, Russia"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Lavlinskaya", 
            "givenName": "Maria S.", 
            "id": "sg:person.010363156771.42", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010363156771.42"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Voronezh State University, Voronezh, Russia", 
              "id": "http://www.grid.ac/institutes/grid.20567.36", 
              "name": [
                "Voronezh State University, Voronezh, Russia"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Ostankova", 
            "givenName": "Irina V.", 
            "id": "sg:person.013351060771.48", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013351060771.48"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Voronezh State University, Voronezh, Russia", 
              "id": "http://www.grid.ac/institutes/grid.20567.36", 
              "name": [
                "Voronezh State University, Voronezh, Russia"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Shatalov", 
            "givenName": "Gennadiy V.", 
            "id": "sg:person.016336762771.18", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016336762771.18"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Voronezh State University, Voronezh, Russia", 
              "id": "http://www.grid.ac/institutes/grid.20567.36", 
              "name": [
                "Voronezh State University, Voronezh, Russia"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Shikhaliev", 
            "givenName": "Khidmet S.", 
            "id": "sg:person.011360644453.24", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011360644453.24"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "People\u2019s Friendship University of Russia, Moscow, Russia", 
              "id": "http://www.grid.ac/institutes/grid.77642.30", 
              "name": [
                "People\u2019s Friendship University of Russia, Moscow, Russia"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Ryzhkova", 
            "givenName": "Elena A.", 
            "id": "sg:person.015012135171.00", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015012135171.00"
            ], 
            "type": "Person"
          }
        ], 
        "citation": [
          {
            "id": "sg:pub.10.1134/s1560090414020146", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1048525304", 
              "https://doi.org/10.1134/s1560090414020146"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1134/s1995078012020152", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1043247489", 
              "https://doi.org/10.1134/s1995078012020152"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1134/s1061933x15010020", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1021301254", 
              "https://doi.org/10.1134/s1061933x15010020"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/3-540-45989-8_1", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1034840699", 
              "https://doi.org/10.1007/3-540-45989-8_1"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1134/s1070427212090182", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1003813934", 
              "https://doi.org/10.1134/s1070427212090182"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1134/s1070427216010225", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1023829759", 
              "https://doi.org/10.1134/s1070427216010225"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/s00396-001-0596-5", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1025882981", 
              "https://doi.org/10.1007/s00396-001-0596-5"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1134/s1070427210090211", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1035662949", 
              "https://doi.org/10.1134/s1070427210090211"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/s11167-005-0506-6", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1013769972", 
              "https://doi.org/10.1007/s11167-005-0506-6"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1134/s1061934816020106", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1016518448", 
              "https://doi.org/10.1134/s1061934816020106"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/bf00765102", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1043964234", 
              "https://doi.org/10.1007/bf00765102"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1134/s0965545x11050026", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1035932792", 
              "https://doi.org/10.1134/s0965545x11050026"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/s11094-006-0078-7", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1049902115", 
              "https://doi.org/10.1007/s11094-006-0078-7"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/s00289-015-1558-2", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1006624872", 
              "https://doi.org/10.1007/s00289-015-1558-2"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/s00396-016-3922-7", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1021062592", 
              "https://doi.org/10.1007/s00396-016-3922-7"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1134/s1070427209040168", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1052609983", 
              "https://doi.org/10.1134/s1070427209040168"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1134/s0018143908070084", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1024770758", 
              "https://doi.org/10.1134/s0018143908070084"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/978-3-662-07757-3", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1019156820", 
              "https://doi.org/10.1007/978-3-662-07757-3"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/978-1-4684-0095-3", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1049291799", 
              "https://doi.org/10.1007/978-1-4684-0095-3"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/s00396-001-0613-8", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1052003848", 
              "https://doi.org/10.1007/s00396-001-0613-8"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/s003960200009", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1008997683", 
              "https://doi.org/10.1007/s003960200009"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/s00396-015-3792-4", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1029504758", 
              "https://doi.org/10.1007/s00396-015-3792-4"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1134/s1070427207050175", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1008156092", 
              "https://doi.org/10.1134/s1070427207050175"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1134/s1560090407030013", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1012954937", 
              "https://doi.org/10.1134/s1560090407030013"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1134/s1070427212080174", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1012626662", 
              "https://doi.org/10.1134/s1070427212080174"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/s00289-007-0885-3", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1007027377", 
              "https://doi.org/10.1007/s00289-007-0885-3"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/s00396-016-3843-5", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1039169272", 
              "https://doi.org/10.1007/s00396-016-3843-5"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1134/s0012500813020055", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1026992857", 
              "https://doi.org/10.1134/s0012500813020055"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/s00396-002-0828-3", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1028861208", 
              "https://doi.org/10.1007/s00396-002-0828-3"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/s00396-003-0901-6", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1051863991", 
              "https://doi.org/10.1007/s00396-003-0901-6"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1134/s1070427206100211", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1038455761", 
              "https://doi.org/10.1134/s1070427206100211"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/b11267", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1045350175", 
              "https://doi.org/10.1007/b11267"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1134/s1070427215020111", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1028827949", 
              "https://doi.org/10.1134/s1070427215020111"
            ], 
            "type": "CreativeWork"
          }
        ], 
        "datePublished": "2017-06-12", 
        "datePublishedReg": "2017-06-12", 
        "description": "Copolymers of N-vinylformamide (VF) with 1-vinyl-3,5-dimethylpyrazole (VDMP) and 1-methacryloyl-3,5-dimethylpyrazole (MDMP) are synthesized by free radical copolymerization in dioxane. The compositions of copolymers are determined by means of UV-spectroscopy and FTIR, and copolymerization constants r1 and r2 are calculated. N-vinylformamide demonstrates higher reactivity than pyrazole-containing monomers in both cases. Solubility of the synthesized copolymers in water was studied. VF\u2013VDMP copolymers are water soluble at VF content higher than 0.65 molar fractions, and VF\u2013MDMP copolymers\u2014at VF content over 0.8 molar fractions. The formation of complexes between water-soluble copolymers and essential \u03b1-amino acid histidine in aqueous solutions is confirmed by UV-spectroscopy, FTIR, dynamic light scattering (DLS), and transition electron microscopy. It is found via DLS that the interactions between the amino acid with copolymer macromolecules lead to conformation changes in macromolecular coils. It is shown that VF\u2013VDMP and VF\u2013MDMP copolymers are effective extragents for histidine. Extraction is carried out at different pH values. The highest extraction degree (98%) is achieved in an acidic medium.", 
        "genre": "article", 
        "id": "sg:pub.10.1007/s00289-017-2091-2", 
        "isAccessibleForFree": false, 
        "isPartOf": [
          {
            "id": "sg:journal.1123778", 
            "issn": [
              "0170-0839", 
              "1436-2449"
            ], 
            "name": "Polymer Bulletin", 
            "publisher": "Springer Nature", 
            "type": "Periodical"
          }, 
          {
            "issueNumber": "3", 
            "type": "PublicationIssue"
          }, 
          {
            "type": "PublicationVolume", 
            "volumeNumber": "75"
          }
        ], 
        "keywords": [
          "N-vinylformamide", 
          "water-soluble copolymers", 
          "water-salt media", 
          "free radical copolymerization", 
          "transition electron microscopy", 
          "composition of copolymers", 
          "molar fraction", 
          "higher extraction degree", 
          "formation of complexes", 
          "radical copolymerization", 
          "macromolecular coils", 
          "copolymerization constants r1", 
          "copolymer macromolecules", 
          "aqueous solution", 
          "dynamic light", 
          "acidic medium", 
          "copolymers", 
          "VF content", 
          "high reactivity", 
          "conformation change", 
          "electron microscopy", 
          "FTIR", 
          "extraction ability", 
          "extraction degree", 
          "histidine", 
          "copolymerization", 
          "DLS", 
          "monomers", 
          "water", 
          "dioxane", 
          "solubility", 
          "amino acids", 
          "macromolecules", 
          "synthesis", 
          "extragent", 
          "reactivity", 
          "complexes", 
          "microscopy", 
          "acid", 
          "formation", 
          "R1", 
          "solution", 
          "medium", 
          "fraction", 
          "composition", 
          "interaction", 
          "extraction", 
          "content", 
          "light", 
          "R2", 
          "means", 
          "ability", 
          "values", 
          "degree", 
          "coil", 
          "changes", 
          "cases", 
          "relation"
        ], 
        "name": "Synthesis of N-vinylformamide and 1-vinyl-(1-methacryloyl)-3,5-dimethylpyrazole copolymers and their extraction ability in relation to histidine in water-salt media", 
        "pagination": "1237-1251", 
        "productId": [
          {
            "name": "dimensions_id", 
            "type": "PropertyValue", 
            "value": [
              "pub.1085981959"
            ]
          }, 
          {
            "name": "doi", 
            "type": "PropertyValue", 
            "value": [
              "10.1007/s00289-017-2091-2"
            ]
          }
        ], 
        "sameAs": [
          "https://doi.org/10.1007/s00289-017-2091-2", 
          "https://app.dimensions.ai/details/publication/pub.1085981959"
        ], 
        "sdDataset": "articles", 
        "sdDatePublished": "2022-08-04T17:05", 
        "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
        "sdPublisher": {
          "name": "Springer Nature - SN SciGraph project", 
          "type": "Organization"
        }, 
        "sdSource": "s3://com-springernature-scigraph/baseset/20220804/entities/gbq_results/article/article_740.jsonl", 
        "type": "ScholarlyArticle", 
        "url": "https://doi.org/10.1007/s00289-017-2091-2"
      }
    ]
     

    Download the RDF metadata as:  json-ld nt turtle xml License info

    HOW TO GET THIS DATA PROGRAMMATICALLY:

    JSON-LD is a popular format for linked data which is fully compatible with JSON.

    curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s00289-017-2091-2'

    N-Triples is a line-based linked data format ideal for batch operations.

    curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s00289-017-2091-2'

    Turtle is a human-readable linked data format.

    curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s00289-017-2091-2'

    RDF/XML is a standard XML format for linked data.

    curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s00289-017-2091-2'


     

    This table displays all metadata directly associated to this object as RDF triples.

    285 TRIPLES      21 PREDICATES      115 URIs      74 LITERALS      6 BLANK NODES

    Subject Predicate Object
    1 sg:pub.10.1007/s00289-017-2091-2 schema:about anzsrc-for:03
    2 anzsrc-for:0303
    3 schema:author N164f922ae0ee4b0d8841f09dbc805530
    4 schema:citation sg:pub.10.1007/3-540-45989-8_1
    5 sg:pub.10.1007/978-1-4684-0095-3
    6 sg:pub.10.1007/978-3-662-07757-3
    7 sg:pub.10.1007/b11267
    8 sg:pub.10.1007/bf00765102
    9 sg:pub.10.1007/s00289-007-0885-3
    10 sg:pub.10.1007/s00289-015-1558-2
    11 sg:pub.10.1007/s00396-001-0596-5
    12 sg:pub.10.1007/s00396-001-0613-8
    13 sg:pub.10.1007/s00396-002-0828-3
    14 sg:pub.10.1007/s00396-003-0901-6
    15 sg:pub.10.1007/s00396-015-3792-4
    16 sg:pub.10.1007/s00396-016-3843-5
    17 sg:pub.10.1007/s00396-016-3922-7
    18 sg:pub.10.1007/s003960200009
    19 sg:pub.10.1007/s11094-006-0078-7
    20 sg:pub.10.1007/s11167-005-0506-6
    21 sg:pub.10.1134/s0012500813020055
    22 sg:pub.10.1134/s0018143908070084
    23 sg:pub.10.1134/s0965545x11050026
    24 sg:pub.10.1134/s1061933x15010020
    25 sg:pub.10.1134/s1061934816020106
    26 sg:pub.10.1134/s1070427206100211
    27 sg:pub.10.1134/s1070427207050175
    28 sg:pub.10.1134/s1070427209040168
    29 sg:pub.10.1134/s1070427210090211
    30 sg:pub.10.1134/s1070427212080174
    31 sg:pub.10.1134/s1070427212090182
    32 sg:pub.10.1134/s1070427215020111
    33 sg:pub.10.1134/s1070427216010225
    34 sg:pub.10.1134/s1560090407030013
    35 sg:pub.10.1134/s1560090414020146
    36 sg:pub.10.1134/s1995078012020152
    37 schema:datePublished 2017-06-12
    38 schema:datePublishedReg 2017-06-12
    39 schema:description Copolymers of N-vinylformamide (VF) with 1-vinyl-3,5-dimethylpyrazole (VDMP) and 1-methacryloyl-3,5-dimethylpyrazole (MDMP) are synthesized by free radical copolymerization in dioxane. The compositions of copolymers are determined by means of UV-spectroscopy and FTIR, and copolymerization constants r1 and r2 are calculated. N-vinylformamide demonstrates higher reactivity than pyrazole-containing monomers in both cases. Solubility of the synthesized copolymers in water was studied. VF–VDMP copolymers are water soluble at VF content higher than 0.65 molar fractions, and VF–MDMP copolymers—at VF content over 0.8 molar fractions. The formation of complexes between water-soluble copolymers and essential α-amino acid histidine in aqueous solutions is confirmed by UV-spectroscopy, FTIR, dynamic light scattering (DLS), and transition electron microscopy. It is found via DLS that the interactions between the amino acid with copolymer macromolecules lead to conformation changes in macromolecular coils. It is shown that VF–VDMP and VF–MDMP copolymers are effective extragents for histidine. Extraction is carried out at different pH values. The highest extraction degree (98%) is achieved in an acidic medium.
    40 schema:genre article
    41 schema:isAccessibleForFree false
    42 schema:isPartOf N9ddb93d3c3e649d08fcbf9cdfdc24750
    43 Nb98f9f8ee53f4c63baf4239b0b892d70
    44 sg:journal.1123778
    45 schema:keywords DLS
    46 FTIR
    47 N-vinylformamide
    48 R1
    49 R2
    50 VF content
    51 ability
    52 acid
    53 acidic medium
    54 amino acids
    55 aqueous solution
    56 cases
    57 changes
    58 coil
    59 complexes
    60 composition
    61 composition of copolymers
    62 conformation change
    63 content
    64 copolymer macromolecules
    65 copolymerization
    66 copolymerization constants r1
    67 copolymers
    68 degree
    69 dioxane
    70 dynamic light
    71 electron microscopy
    72 extraction
    73 extraction ability
    74 extraction degree
    75 extragent
    76 formation
    77 formation of complexes
    78 fraction
    79 free radical copolymerization
    80 high reactivity
    81 higher extraction degree
    82 histidine
    83 interaction
    84 light
    85 macromolecular coils
    86 macromolecules
    87 means
    88 medium
    89 microscopy
    90 molar fraction
    91 monomers
    92 radical copolymerization
    93 reactivity
    94 relation
    95 solubility
    96 solution
    97 synthesis
    98 transition electron microscopy
    99 values
    100 water
    101 water-salt media
    102 water-soluble copolymers
    103 schema:name Synthesis of N-vinylformamide and 1-vinyl-(1-methacryloyl)-3,5-dimethylpyrazole copolymers and their extraction ability in relation to histidine in water-salt media
    104 schema:pagination 1237-1251
    105 schema:productId N2d1e267de3e64d7094352d74d367b773
    106 Nd7355e339c8f48d6ac5b68ea0793b206
    107 schema:sameAs https://app.dimensions.ai/details/publication/pub.1085981959
    108 https://doi.org/10.1007/s00289-017-2091-2
    109 schema:sdDatePublished 2022-08-04T17:05
    110 schema:sdLicense https://scigraph.springernature.com/explorer/license/
    111 schema:sdPublisher Ndb7c1ad431b94694b8c9e24672303556
    112 schema:url https://doi.org/10.1007/s00289-017-2091-2
    113 sgo:license sg:explorer/license/
    114 sgo:sdDataset articles
    115 rdf:type schema:ScholarlyArticle
    116 N164f922ae0ee4b0d8841f09dbc805530 rdf:first sg:person.014675706571.50
    117 rdf:rest N8764d03985784a8f8723775ebf5db6a2
    118 N256bc8dd46144e2c931ef5fa15f50c5b rdf:first sg:person.015012135171.00
    119 rdf:rest rdf:nil
    120 N2d1e267de3e64d7094352d74d367b773 schema:name dimensions_id
    121 schema:value pub.1085981959
    122 rdf:type schema:PropertyValue
    123 N4ee27eb578694561bb816cf9c3fe41bf rdf:first sg:person.013351060771.48
    124 rdf:rest Naef7969709af476b8a69c57fb79092fd
    125 N58df90f5e92e4b92a5a807914091361f rdf:first sg:person.011360644453.24
    126 rdf:rest N256bc8dd46144e2c931ef5fa15f50c5b
    127 N8764d03985784a8f8723775ebf5db6a2 rdf:first sg:person.010363156771.42
    128 rdf:rest N4ee27eb578694561bb816cf9c3fe41bf
    129 N9ddb93d3c3e649d08fcbf9cdfdc24750 schema:issueNumber 3
    130 rdf:type schema:PublicationIssue
    131 Naef7969709af476b8a69c57fb79092fd rdf:first sg:person.016336762771.18
    132 rdf:rest N58df90f5e92e4b92a5a807914091361f
    133 Nb98f9f8ee53f4c63baf4239b0b892d70 schema:volumeNumber 75
    134 rdf:type schema:PublicationVolume
    135 Nd7355e339c8f48d6ac5b68ea0793b206 schema:name doi
    136 schema:value 10.1007/s00289-017-2091-2
    137 rdf:type schema:PropertyValue
    138 Ndb7c1ad431b94694b8c9e24672303556 schema:name Springer Nature - SN SciGraph project
    139 rdf:type schema:Organization
    140 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
    141 schema:name Chemical Sciences
    142 rdf:type schema:DefinedTerm
    143 anzsrc-for:0303 schema:inDefinedTermSet anzsrc-for:
    144 schema:name Macromolecular and Materials Chemistry
    145 rdf:type schema:DefinedTerm
    146 sg:journal.1123778 schema:issn 0170-0839
    147 1436-2449
    148 schema:name Polymer Bulletin
    149 schema:publisher Springer Nature
    150 rdf:type schema:Periodical
    151 sg:person.010363156771.42 schema:affiliation grid-institutes:grid.20567.36
    152 schema:familyName Lavlinskaya
    153 schema:givenName Maria S.
    154 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010363156771.42
    155 rdf:type schema:Person
    156 sg:person.011360644453.24 schema:affiliation grid-institutes:grid.20567.36
    157 schema:familyName Shikhaliev
    158 schema:givenName Khidmet S.
    159 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011360644453.24
    160 rdf:type schema:Person
    161 sg:person.013351060771.48 schema:affiliation grid-institutes:grid.20567.36
    162 schema:familyName Ostankova
    163 schema:givenName Irina V.
    164 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013351060771.48
    165 rdf:type schema:Person
    166 sg:person.014675706571.50 schema:affiliation grid-institutes:grid.20567.36
    167 schema:familyName Kuznetsov
    168 schema:givenName Vyacheslav A.
    169 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014675706571.50
    170 rdf:type schema:Person
    171 sg:person.015012135171.00 schema:affiliation grid-institutes:grid.77642.30
    172 schema:familyName Ryzhkova
    173 schema:givenName Elena A.
    174 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015012135171.00
    175 rdf:type schema:Person
    176 sg:person.016336762771.18 schema:affiliation grid-institutes:grid.20567.36
    177 schema:familyName Shatalov
    178 schema:givenName Gennadiy V.
    179 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016336762771.18
    180 rdf:type schema:Person
    181 sg:pub.10.1007/3-540-45989-8_1 schema:sameAs https://app.dimensions.ai/details/publication/pub.1034840699
    182 https://doi.org/10.1007/3-540-45989-8_1
    183 rdf:type schema:CreativeWork
    184 sg:pub.10.1007/978-1-4684-0095-3 schema:sameAs https://app.dimensions.ai/details/publication/pub.1049291799
    185 https://doi.org/10.1007/978-1-4684-0095-3
    186 rdf:type schema:CreativeWork
    187 sg:pub.10.1007/978-3-662-07757-3 schema:sameAs https://app.dimensions.ai/details/publication/pub.1019156820
    188 https://doi.org/10.1007/978-3-662-07757-3
    189 rdf:type schema:CreativeWork
    190 sg:pub.10.1007/b11267 schema:sameAs https://app.dimensions.ai/details/publication/pub.1045350175
    191 https://doi.org/10.1007/b11267
    192 rdf:type schema:CreativeWork
    193 sg:pub.10.1007/bf00765102 schema:sameAs https://app.dimensions.ai/details/publication/pub.1043964234
    194 https://doi.org/10.1007/bf00765102
    195 rdf:type schema:CreativeWork
    196 sg:pub.10.1007/s00289-007-0885-3 schema:sameAs https://app.dimensions.ai/details/publication/pub.1007027377
    197 https://doi.org/10.1007/s00289-007-0885-3
    198 rdf:type schema:CreativeWork
    199 sg:pub.10.1007/s00289-015-1558-2 schema:sameAs https://app.dimensions.ai/details/publication/pub.1006624872
    200 https://doi.org/10.1007/s00289-015-1558-2
    201 rdf:type schema:CreativeWork
    202 sg:pub.10.1007/s00396-001-0596-5 schema:sameAs https://app.dimensions.ai/details/publication/pub.1025882981
    203 https://doi.org/10.1007/s00396-001-0596-5
    204 rdf:type schema:CreativeWork
    205 sg:pub.10.1007/s00396-001-0613-8 schema:sameAs https://app.dimensions.ai/details/publication/pub.1052003848
    206 https://doi.org/10.1007/s00396-001-0613-8
    207 rdf:type schema:CreativeWork
    208 sg:pub.10.1007/s00396-002-0828-3 schema:sameAs https://app.dimensions.ai/details/publication/pub.1028861208
    209 https://doi.org/10.1007/s00396-002-0828-3
    210 rdf:type schema:CreativeWork
    211 sg:pub.10.1007/s00396-003-0901-6 schema:sameAs https://app.dimensions.ai/details/publication/pub.1051863991
    212 https://doi.org/10.1007/s00396-003-0901-6
    213 rdf:type schema:CreativeWork
    214 sg:pub.10.1007/s00396-015-3792-4 schema:sameAs https://app.dimensions.ai/details/publication/pub.1029504758
    215 https://doi.org/10.1007/s00396-015-3792-4
    216 rdf:type schema:CreativeWork
    217 sg:pub.10.1007/s00396-016-3843-5 schema:sameAs https://app.dimensions.ai/details/publication/pub.1039169272
    218 https://doi.org/10.1007/s00396-016-3843-5
    219 rdf:type schema:CreativeWork
    220 sg:pub.10.1007/s00396-016-3922-7 schema:sameAs https://app.dimensions.ai/details/publication/pub.1021062592
    221 https://doi.org/10.1007/s00396-016-3922-7
    222 rdf:type schema:CreativeWork
    223 sg:pub.10.1007/s003960200009 schema:sameAs https://app.dimensions.ai/details/publication/pub.1008997683
    224 https://doi.org/10.1007/s003960200009
    225 rdf:type schema:CreativeWork
    226 sg:pub.10.1007/s11094-006-0078-7 schema:sameAs https://app.dimensions.ai/details/publication/pub.1049902115
    227 https://doi.org/10.1007/s11094-006-0078-7
    228 rdf:type schema:CreativeWork
    229 sg:pub.10.1007/s11167-005-0506-6 schema:sameAs https://app.dimensions.ai/details/publication/pub.1013769972
    230 https://doi.org/10.1007/s11167-005-0506-6
    231 rdf:type schema:CreativeWork
    232 sg:pub.10.1134/s0012500813020055 schema:sameAs https://app.dimensions.ai/details/publication/pub.1026992857
    233 https://doi.org/10.1134/s0012500813020055
    234 rdf:type schema:CreativeWork
    235 sg:pub.10.1134/s0018143908070084 schema:sameAs https://app.dimensions.ai/details/publication/pub.1024770758
    236 https://doi.org/10.1134/s0018143908070084
    237 rdf:type schema:CreativeWork
    238 sg:pub.10.1134/s0965545x11050026 schema:sameAs https://app.dimensions.ai/details/publication/pub.1035932792
    239 https://doi.org/10.1134/s0965545x11050026
    240 rdf:type schema:CreativeWork
    241 sg:pub.10.1134/s1061933x15010020 schema:sameAs https://app.dimensions.ai/details/publication/pub.1021301254
    242 https://doi.org/10.1134/s1061933x15010020
    243 rdf:type schema:CreativeWork
    244 sg:pub.10.1134/s1061934816020106 schema:sameAs https://app.dimensions.ai/details/publication/pub.1016518448
    245 https://doi.org/10.1134/s1061934816020106
    246 rdf:type schema:CreativeWork
    247 sg:pub.10.1134/s1070427206100211 schema:sameAs https://app.dimensions.ai/details/publication/pub.1038455761
    248 https://doi.org/10.1134/s1070427206100211
    249 rdf:type schema:CreativeWork
    250 sg:pub.10.1134/s1070427207050175 schema:sameAs https://app.dimensions.ai/details/publication/pub.1008156092
    251 https://doi.org/10.1134/s1070427207050175
    252 rdf:type schema:CreativeWork
    253 sg:pub.10.1134/s1070427209040168 schema:sameAs https://app.dimensions.ai/details/publication/pub.1052609983
    254 https://doi.org/10.1134/s1070427209040168
    255 rdf:type schema:CreativeWork
    256 sg:pub.10.1134/s1070427210090211 schema:sameAs https://app.dimensions.ai/details/publication/pub.1035662949
    257 https://doi.org/10.1134/s1070427210090211
    258 rdf:type schema:CreativeWork
    259 sg:pub.10.1134/s1070427212080174 schema:sameAs https://app.dimensions.ai/details/publication/pub.1012626662
    260 https://doi.org/10.1134/s1070427212080174
    261 rdf:type schema:CreativeWork
    262 sg:pub.10.1134/s1070427212090182 schema:sameAs https://app.dimensions.ai/details/publication/pub.1003813934
    263 https://doi.org/10.1134/s1070427212090182
    264 rdf:type schema:CreativeWork
    265 sg:pub.10.1134/s1070427215020111 schema:sameAs https://app.dimensions.ai/details/publication/pub.1028827949
    266 https://doi.org/10.1134/s1070427215020111
    267 rdf:type schema:CreativeWork
    268 sg:pub.10.1134/s1070427216010225 schema:sameAs https://app.dimensions.ai/details/publication/pub.1023829759
    269 https://doi.org/10.1134/s1070427216010225
    270 rdf:type schema:CreativeWork
    271 sg:pub.10.1134/s1560090407030013 schema:sameAs https://app.dimensions.ai/details/publication/pub.1012954937
    272 https://doi.org/10.1134/s1560090407030013
    273 rdf:type schema:CreativeWork
    274 sg:pub.10.1134/s1560090414020146 schema:sameAs https://app.dimensions.ai/details/publication/pub.1048525304
    275 https://doi.org/10.1134/s1560090414020146
    276 rdf:type schema:CreativeWork
    277 sg:pub.10.1134/s1995078012020152 schema:sameAs https://app.dimensions.ai/details/publication/pub.1043247489
    278 https://doi.org/10.1134/s1995078012020152
    279 rdf:type schema:CreativeWork
    280 grid-institutes:grid.20567.36 schema:alternateName Voronezh State University, Voronezh, Russia
    281 schema:name Voronezh State University, Voronezh, Russia
    282 rdf:type schema:Organization
    283 grid-institutes:grid.77642.30 schema:alternateName People’s Friendship University of Russia, Moscow, Russia
    284 schema:name People’s Friendship University of Russia, Moscow, Russia
    285 rdf:type schema:Organization
     




    Preview window. Press ESC to close (or click here)


    ...