Theoretical study of lithium diffusion and fractionation in forsterite and its high-pressure phases View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2019-03-04

AUTHORS

Jiajun Jiang, Feiwu Zhang, Hua Yang, Tiancheng Yu

ABSTRACT

As a geochemical tracer in mantle studies, lithium isotopes play an important role in diffusion and fractionation in major mantle minerals. Olivine and its high-pressure phases, wadsleyite and ringwoodite, are considered to predominate in the upper mantle and transition zone on the earth. We carried out simulations of lithium isotopes’ diffusion and fractionation in Mg end member olivine and its high-pressure phases to learn the details of the signatures of lithium isotopes preserved in mantle materials. In this work, the diffusion and fractionation mechanisms between different lattice sites of lithium isotopes in forsterite (Mg2SiO4), wadsleyite (β-Mg2SiO4) and ringwoodite (γ-Mg2SiO4) at the atomic level are studied using empirical atomistic simulation techniques. It is found that Li can pass through the high-pressure phases (wadsleyite and ringwoodite) energetically much easier due to the low migration energy barriers via either substitutional or interstitial mechanism. The activation energy is high for Li diffusion along the interstitial path in the forsterite and decreases drastically with the assist of Mg vacancies. The temperature-dependent fractionation for two Li isotopes between two different lattice sites is calculated at the temperatures from 300 to 2500 K. This behavior generates the lighter Li storage in the near-surface mantle-derived rocks and provides insights into zoning and composition of lithium isotopes in olivine and its high-pressure phases. More... »

PAGES

1-11

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s00269-019-01029-x

DOI

http://dx.doi.org/10.1007/s00269-019-01029-x

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1112519636


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0403", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Geology", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/04", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Earth Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "University of Chinese Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.410726.6", 
          "name": [
            "State Key Laboratory of Ore Deposit Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, 550081, Guiyang, China", 
            "University of the Chinese Academy of Sciences, 100049, Beijing, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Jiang", 
        "givenName": "Jiajun", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Geology and Geophysics", 
          "id": "https://www.grid.ac/institutes/grid.458476.c", 
          "name": [
            "State Key Laboratory of Ore Deposit Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, 550081, Guiyang, China", 
            "Key Laboratory of Earth and Planetary Physics, Institute of Geology and Geophysics, Chinese Academy of Sciences, 100029, Beijing, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Zhang", 
        "givenName": "Feiwu", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "University of Chinese Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.410726.6", 
          "name": [
            "State Key Laboratory of Ore Deposit Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, 550081, Guiyang, China", 
            "University of the Chinese Academy of Sciences, 100049, Beijing, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Yang", 
        "givenName": "Hua", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Suzhou University of Science and Technology", 
          "id": "https://www.grid.ac/institutes/grid.440652.1", 
          "name": [
            "School of Mathematics and Physics, Suzhou University of Science and Technology, 215009, Suzhou, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Yu", 
        "givenName": "Tiancheng", 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1007/s004100000221", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1000678751", 
          "https://doi.org/10.1007/s004100000221"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.gca.2013.11.008", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1000923745"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.epsl.2005.09.020", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1001792206"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0097-8485(00)00060-7", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1002457115"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.gca.2010.01.015", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1003023975"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s00410-002-0407-0", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1004352460", 
          "https://doi.org/10.1007/s00410-002-0407-0"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1088/0953-8984/17/7/004", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1004623356"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0016-7037(98)00224-5", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1005731403"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0022-3697(77)90039-7", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1005779328"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0022-3697(77)90039-7", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1005779328"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.epsl.2008.12.009", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1007631292"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s00410-009-0376-7", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1009196293", 
          "https://doi.org/10.1007/s00410-009-0376-7"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s00410-009-0376-7", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1009196293", 
          "https://doi.org/10.1007/s00410-009-0376-7"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.chemgeo.2004.08.009", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1009328139"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/a606455h", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1011485596"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0016-7037(98)00131-8", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1011838709"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0016-7037(97)00198-1", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1012383251"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf00202991", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1012612714", 
          "https://doi.org/10.1007/bf00202991"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf00202991", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1012612714", 
          "https://doi.org/10.1007/bf00202991"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.gca.2015.04.029", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1012916848"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.2138/am.2012.3913", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1015082191"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s00410-009-0456-8", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1015964344", 
          "https://doi.org/10.1007/s00410-009-0456-8"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s00410-009-0456-8", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1015964344", 
          "https://doi.org/10.1007/s00410-009-0456-8"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s00410-009-0456-8", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1015964344", 
          "https://doi.org/10.1007/s00410-009-0456-8"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.gca.2009.10.016", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1017895443"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.pepi.2008.04.008", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1018081998"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s00410-016-1238-8", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1018557744", 
          "https://doi.org/10.1007/s00410-016-1238-8"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.gca.2012.05.034", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1019537024"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0009-2541(99)00184-9", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1019572853"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.gca.2012.03.039", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1019988490"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1180/0026461056910232", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1020711104"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.epsl.2007.11.020", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1022149779"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1029/1999gl008425", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1023183735"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.gca.2006.06.1611", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1025405713"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/371693a0", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1025936165", 
          "https://doi.org/10.1038/371693a0"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.pepi.2008.04.001", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1027678943"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.epsl.2007.08.005", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1028282911"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.2138/am.2014.4676", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1028449418"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0016-7037(03)00174-1", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1032680073"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0016-7037(03)00174-1", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1032680073"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0024-4937(00)00024-4", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1033197092"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1029/1999jb900145", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1034176404"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.gca.2010.07.019", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1034885321"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1086/375492", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1036806953"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.chemgeo.2003.08.001", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1037163616"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.chemgeo.2003.08.001", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1037163616"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0012-821x(01)00294-1", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1037552485"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s00269-005-0036-z", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1042203586", 
          "https://doi.org/10.1007/s00269-005-0036-z"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s00269-005-0036-z", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1042203586", 
          "https://doi.org/10.1007/s00269-005-0036-z"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s00269-005-0036-z", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1042203586", 
          "https://doi.org/10.1007/s00269-005-0036-z"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c39840001271", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1043919339"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.epsl.2012.01.035", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1044186094"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.epsl.2007.03.023", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1044336415"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf00308782", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1045304939", 
          "https://doi.org/10.1007/bf00308782"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.gca.2011.06.026", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1046410260"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.2138/am.2006.2083", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1047489348"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0012-821x(04)00096-2", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1050069736"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/j100247a015", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055660918"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp001303i", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056043037"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp001303i", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056043037"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1088/0022-3719/18/6/010", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1058962743"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1126/science.265.5176.1202", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1062548735"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1127/0935-1221/2003/0015-0893", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1062698181"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1127/0935-1221/2006/0018-0529", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1062698444"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1127/ejm/3/2/0387", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1062703529"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.2138/am-2000-0110", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1069056025"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.2138/am-2002-1025", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1069056490"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2019-03-04", 
    "datePublishedReg": "2019-03-04", 
    "description": "As a geochemical tracer in mantle studies, lithium isotopes play an important role in diffusion and fractionation in major mantle minerals. Olivine and its high-pressure phases, wadsleyite and ringwoodite, are considered to predominate in the upper mantle and transition zone on the earth. We carried out simulations of lithium isotopes\u2019 diffusion and fractionation in Mg end member olivine and its high-pressure phases to learn the details of the signatures of lithium isotopes preserved in mantle materials. In this work, the diffusion and fractionation mechanisms between different lattice sites of lithium isotopes in forsterite (Mg2SiO4), wadsleyite (\u03b2-Mg2SiO4) and ringwoodite (\u03b3-Mg2SiO4) at the atomic level are studied using empirical atomistic simulation techniques. It is found that Li can pass through the high-pressure phases (wadsleyite and ringwoodite) energetically much easier due to the low migration energy barriers via either substitutional or interstitial mechanism. The activation energy is high for Li diffusion along the interstitial path in the forsterite and decreases drastically with the assist of Mg vacancies. The temperature-dependent fractionation for two Li isotopes between two different lattice sites is calculated at the temperatures from 300 to 2500 K. This behavior generates the lighter Li storage in the near-surface mantle-derived rocks and provides insights into zoning and composition of lithium isotopes in olivine and its high-pressure phases.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/s00269-019-01029-x", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1052149", 
        "issn": [
          "0342-1791", 
          "1432-2021"
        ], 
        "name": "Physics and Chemistry of Minerals", 
        "type": "Periodical"
      }
    ], 
    "name": "Theoretical study of lithium diffusion and fractionation in forsterite and its high-pressure phases", 
    "pagination": "1-11", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "e7868be886d2969f902dd8eccbb4b77f7792c2ed63ac0d9cd2236ea8eb53aaeb"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s00269-019-01029-x"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1112519636"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s00269-019-01029-x", 
      "https://app.dimensions.ai/details/publication/pub.1112519636"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-11T11:05", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000352_0000000352/records_60367_00000004.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://link.springer.com/10.1007%2Fs00269-019-01029-x"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s00269-019-01029-x'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s00269-019-01029-x'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s00269-019-01029-x'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s00269-019-01029-x'


 

This table displays all metadata directly associated to this object as RDF triples.

260 TRIPLES      21 PREDICATES      81 URIs      16 LITERALS      5 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s00269-019-01029-x schema:about anzsrc-for:04
2 anzsrc-for:0403
3 schema:author N9148e8b7842143eba8bb313a6d54f887
4 schema:citation sg:pub.10.1007/bf00202991
5 sg:pub.10.1007/bf00308782
6 sg:pub.10.1007/s00269-005-0036-z
7 sg:pub.10.1007/s00410-002-0407-0
8 sg:pub.10.1007/s00410-009-0376-7
9 sg:pub.10.1007/s00410-009-0456-8
10 sg:pub.10.1007/s00410-016-1238-8
11 sg:pub.10.1007/s004100000221
12 sg:pub.10.1038/371693a0
13 https://doi.org/10.1016/0022-3697(77)90039-7
14 https://doi.org/10.1016/j.chemgeo.2003.08.001
15 https://doi.org/10.1016/j.chemgeo.2004.08.009
16 https://doi.org/10.1016/j.epsl.2005.09.020
17 https://doi.org/10.1016/j.epsl.2007.03.023
18 https://doi.org/10.1016/j.epsl.2007.08.005
19 https://doi.org/10.1016/j.epsl.2007.11.020
20 https://doi.org/10.1016/j.epsl.2008.12.009
21 https://doi.org/10.1016/j.epsl.2012.01.035
22 https://doi.org/10.1016/j.gca.2006.06.1611
23 https://doi.org/10.1016/j.gca.2009.10.016
24 https://doi.org/10.1016/j.gca.2010.01.015
25 https://doi.org/10.1016/j.gca.2010.07.019
26 https://doi.org/10.1016/j.gca.2011.06.026
27 https://doi.org/10.1016/j.gca.2012.03.039
28 https://doi.org/10.1016/j.gca.2012.05.034
29 https://doi.org/10.1016/j.gca.2013.11.008
30 https://doi.org/10.1016/j.gca.2015.04.029
31 https://doi.org/10.1016/j.pepi.2008.04.001
32 https://doi.org/10.1016/j.pepi.2008.04.008
33 https://doi.org/10.1016/s0009-2541(99)00184-9
34 https://doi.org/10.1016/s0012-821x(01)00294-1
35 https://doi.org/10.1016/s0012-821x(04)00096-2
36 https://doi.org/10.1016/s0016-7037(03)00174-1
37 https://doi.org/10.1016/s0016-7037(97)00198-1
38 https://doi.org/10.1016/s0016-7037(98)00131-8
39 https://doi.org/10.1016/s0016-7037(98)00224-5
40 https://doi.org/10.1016/s0024-4937(00)00024-4
41 https://doi.org/10.1016/s0097-8485(00)00060-7
42 https://doi.org/10.1021/j100247a015
43 https://doi.org/10.1021/jp001303i
44 https://doi.org/10.1029/1999gl008425
45 https://doi.org/10.1029/1999jb900145
46 https://doi.org/10.1039/a606455h
47 https://doi.org/10.1039/c39840001271
48 https://doi.org/10.1086/375492
49 https://doi.org/10.1088/0022-3719/18/6/010
50 https://doi.org/10.1088/0953-8984/17/7/004
51 https://doi.org/10.1126/science.265.5176.1202
52 https://doi.org/10.1127/0935-1221/2003/0015-0893
53 https://doi.org/10.1127/0935-1221/2006/0018-0529
54 https://doi.org/10.1127/ejm/3/2/0387
55 https://doi.org/10.1180/0026461056910232
56 https://doi.org/10.2138/am-2000-0110
57 https://doi.org/10.2138/am-2002-1025
58 https://doi.org/10.2138/am.2006.2083
59 https://doi.org/10.2138/am.2012.3913
60 https://doi.org/10.2138/am.2014.4676
61 schema:datePublished 2019-03-04
62 schema:datePublishedReg 2019-03-04
63 schema:description As a geochemical tracer in mantle studies, lithium isotopes play an important role in diffusion and fractionation in major mantle minerals. Olivine and its high-pressure phases, wadsleyite and ringwoodite, are considered to predominate in the upper mantle and transition zone on the earth. We carried out simulations of lithium isotopes’ diffusion and fractionation in Mg end member olivine and its high-pressure phases to learn the details of the signatures of lithium isotopes preserved in mantle materials. In this work, the diffusion and fractionation mechanisms between different lattice sites of lithium isotopes in forsterite (Mg2SiO4), wadsleyite (β-Mg2SiO4) and ringwoodite (γ-Mg2SiO4) at the atomic level are studied using empirical atomistic simulation techniques. It is found that Li can pass through the high-pressure phases (wadsleyite and ringwoodite) energetically much easier due to the low migration energy barriers via either substitutional or interstitial mechanism. The activation energy is high for Li diffusion along the interstitial path in the forsterite and decreases drastically with the assist of Mg vacancies. The temperature-dependent fractionation for two Li isotopes between two different lattice sites is calculated at the temperatures from 300 to 2500 K. This behavior generates the lighter Li storage in the near-surface mantle-derived rocks and provides insights into zoning and composition of lithium isotopes in olivine and its high-pressure phases.
64 schema:genre research_article
65 schema:inLanguage en
66 schema:isAccessibleForFree false
67 schema:isPartOf sg:journal.1052149
68 schema:name Theoretical study of lithium diffusion and fractionation in forsterite and its high-pressure phases
69 schema:pagination 1-11
70 schema:productId N4c9e98fa81a8454d99247f94f82dd80b
71 N754d828d0a5646039fff8239a3df08bf
72 N8a402f45662d4ad79ef80a5698ea9841
73 schema:sameAs https://app.dimensions.ai/details/publication/pub.1112519636
74 https://doi.org/10.1007/s00269-019-01029-x
75 schema:sdDatePublished 2019-04-11T11:05
76 schema:sdLicense https://scigraph.springernature.com/explorer/license/
77 schema:sdPublisher Nd4eb7512d7074f17b993f785e817e178
78 schema:url https://link.springer.com/10.1007%2Fs00269-019-01029-x
79 sgo:license sg:explorer/license/
80 sgo:sdDataset articles
81 rdf:type schema:ScholarlyArticle
82 N468739510261486e8f3a2c13a64879ec schema:affiliation https://www.grid.ac/institutes/grid.410726.6
83 schema:familyName Jiang
84 schema:givenName Jiajun
85 rdf:type schema:Person
86 N4c9e98fa81a8454d99247f94f82dd80b schema:name doi
87 schema:value 10.1007/s00269-019-01029-x
88 rdf:type schema:PropertyValue
89 N754d828d0a5646039fff8239a3df08bf schema:name readcube_id
90 schema:value e7868be886d2969f902dd8eccbb4b77f7792c2ed63ac0d9cd2236ea8eb53aaeb
91 rdf:type schema:PropertyValue
92 N82988b3858e448b8ac25bf4fcfcb46e1 schema:affiliation https://www.grid.ac/institutes/grid.410726.6
93 schema:familyName Yang
94 schema:givenName Hua
95 rdf:type schema:Person
96 N83e4b0679d4e445fbbc352cd361b7cb2 rdf:first N82988b3858e448b8ac25bf4fcfcb46e1
97 rdf:rest Nc6a8311e951d4fa3a4f2050e7e257a0b
98 N8a402f45662d4ad79ef80a5698ea9841 schema:name dimensions_id
99 schema:value pub.1112519636
100 rdf:type schema:PropertyValue
101 N9148e8b7842143eba8bb313a6d54f887 rdf:first N468739510261486e8f3a2c13a64879ec
102 rdf:rest Nf8af9f5d62c74a798c1c75eb4def2021
103 Nc101e948440141689f78c5671d3c2c9f schema:affiliation https://www.grid.ac/institutes/grid.440652.1
104 schema:familyName Yu
105 schema:givenName Tiancheng
106 rdf:type schema:Person
107 Nc573e965a554449b82947cdc3b6034d8 schema:affiliation https://www.grid.ac/institutes/grid.458476.c
108 schema:familyName Zhang
109 schema:givenName Feiwu
110 rdf:type schema:Person
111 Nc6a8311e951d4fa3a4f2050e7e257a0b rdf:first Nc101e948440141689f78c5671d3c2c9f
112 rdf:rest rdf:nil
113 Nd4eb7512d7074f17b993f785e817e178 schema:name Springer Nature - SN SciGraph project
114 rdf:type schema:Organization
115 Nf8af9f5d62c74a798c1c75eb4def2021 rdf:first Nc573e965a554449b82947cdc3b6034d8
116 rdf:rest N83e4b0679d4e445fbbc352cd361b7cb2
117 anzsrc-for:04 schema:inDefinedTermSet anzsrc-for:
118 schema:name Earth Sciences
119 rdf:type schema:DefinedTerm
120 anzsrc-for:0403 schema:inDefinedTermSet anzsrc-for:
121 schema:name Geology
122 rdf:type schema:DefinedTerm
123 sg:journal.1052149 schema:issn 0342-1791
124 1432-2021
125 schema:name Physics and Chemistry of Minerals
126 rdf:type schema:Periodical
127 sg:pub.10.1007/bf00202991 schema:sameAs https://app.dimensions.ai/details/publication/pub.1012612714
128 https://doi.org/10.1007/bf00202991
129 rdf:type schema:CreativeWork
130 sg:pub.10.1007/bf00308782 schema:sameAs https://app.dimensions.ai/details/publication/pub.1045304939
131 https://doi.org/10.1007/bf00308782
132 rdf:type schema:CreativeWork
133 sg:pub.10.1007/s00269-005-0036-z schema:sameAs https://app.dimensions.ai/details/publication/pub.1042203586
134 https://doi.org/10.1007/s00269-005-0036-z
135 rdf:type schema:CreativeWork
136 sg:pub.10.1007/s00410-002-0407-0 schema:sameAs https://app.dimensions.ai/details/publication/pub.1004352460
137 https://doi.org/10.1007/s00410-002-0407-0
138 rdf:type schema:CreativeWork
139 sg:pub.10.1007/s00410-009-0376-7 schema:sameAs https://app.dimensions.ai/details/publication/pub.1009196293
140 https://doi.org/10.1007/s00410-009-0376-7
141 rdf:type schema:CreativeWork
142 sg:pub.10.1007/s00410-009-0456-8 schema:sameAs https://app.dimensions.ai/details/publication/pub.1015964344
143 https://doi.org/10.1007/s00410-009-0456-8
144 rdf:type schema:CreativeWork
145 sg:pub.10.1007/s00410-016-1238-8 schema:sameAs https://app.dimensions.ai/details/publication/pub.1018557744
146 https://doi.org/10.1007/s00410-016-1238-8
147 rdf:type schema:CreativeWork
148 sg:pub.10.1007/s004100000221 schema:sameAs https://app.dimensions.ai/details/publication/pub.1000678751
149 https://doi.org/10.1007/s004100000221
150 rdf:type schema:CreativeWork
151 sg:pub.10.1038/371693a0 schema:sameAs https://app.dimensions.ai/details/publication/pub.1025936165
152 https://doi.org/10.1038/371693a0
153 rdf:type schema:CreativeWork
154 https://doi.org/10.1016/0022-3697(77)90039-7 schema:sameAs https://app.dimensions.ai/details/publication/pub.1005779328
155 rdf:type schema:CreativeWork
156 https://doi.org/10.1016/j.chemgeo.2003.08.001 schema:sameAs https://app.dimensions.ai/details/publication/pub.1037163616
157 rdf:type schema:CreativeWork
158 https://doi.org/10.1016/j.chemgeo.2004.08.009 schema:sameAs https://app.dimensions.ai/details/publication/pub.1009328139
159 rdf:type schema:CreativeWork
160 https://doi.org/10.1016/j.epsl.2005.09.020 schema:sameAs https://app.dimensions.ai/details/publication/pub.1001792206
161 rdf:type schema:CreativeWork
162 https://doi.org/10.1016/j.epsl.2007.03.023 schema:sameAs https://app.dimensions.ai/details/publication/pub.1044336415
163 rdf:type schema:CreativeWork
164 https://doi.org/10.1016/j.epsl.2007.08.005 schema:sameAs https://app.dimensions.ai/details/publication/pub.1028282911
165 rdf:type schema:CreativeWork
166 https://doi.org/10.1016/j.epsl.2007.11.020 schema:sameAs https://app.dimensions.ai/details/publication/pub.1022149779
167 rdf:type schema:CreativeWork
168 https://doi.org/10.1016/j.epsl.2008.12.009 schema:sameAs https://app.dimensions.ai/details/publication/pub.1007631292
169 rdf:type schema:CreativeWork
170 https://doi.org/10.1016/j.epsl.2012.01.035 schema:sameAs https://app.dimensions.ai/details/publication/pub.1044186094
171 rdf:type schema:CreativeWork
172 https://doi.org/10.1016/j.gca.2006.06.1611 schema:sameAs https://app.dimensions.ai/details/publication/pub.1025405713
173 rdf:type schema:CreativeWork
174 https://doi.org/10.1016/j.gca.2009.10.016 schema:sameAs https://app.dimensions.ai/details/publication/pub.1017895443
175 rdf:type schema:CreativeWork
176 https://doi.org/10.1016/j.gca.2010.01.015 schema:sameAs https://app.dimensions.ai/details/publication/pub.1003023975
177 rdf:type schema:CreativeWork
178 https://doi.org/10.1016/j.gca.2010.07.019 schema:sameAs https://app.dimensions.ai/details/publication/pub.1034885321
179 rdf:type schema:CreativeWork
180 https://doi.org/10.1016/j.gca.2011.06.026 schema:sameAs https://app.dimensions.ai/details/publication/pub.1046410260
181 rdf:type schema:CreativeWork
182 https://doi.org/10.1016/j.gca.2012.03.039 schema:sameAs https://app.dimensions.ai/details/publication/pub.1019988490
183 rdf:type schema:CreativeWork
184 https://doi.org/10.1016/j.gca.2012.05.034 schema:sameAs https://app.dimensions.ai/details/publication/pub.1019537024
185 rdf:type schema:CreativeWork
186 https://doi.org/10.1016/j.gca.2013.11.008 schema:sameAs https://app.dimensions.ai/details/publication/pub.1000923745
187 rdf:type schema:CreativeWork
188 https://doi.org/10.1016/j.gca.2015.04.029 schema:sameAs https://app.dimensions.ai/details/publication/pub.1012916848
189 rdf:type schema:CreativeWork
190 https://doi.org/10.1016/j.pepi.2008.04.001 schema:sameAs https://app.dimensions.ai/details/publication/pub.1027678943
191 rdf:type schema:CreativeWork
192 https://doi.org/10.1016/j.pepi.2008.04.008 schema:sameAs https://app.dimensions.ai/details/publication/pub.1018081998
193 rdf:type schema:CreativeWork
194 https://doi.org/10.1016/s0009-2541(99)00184-9 schema:sameAs https://app.dimensions.ai/details/publication/pub.1019572853
195 rdf:type schema:CreativeWork
196 https://doi.org/10.1016/s0012-821x(01)00294-1 schema:sameAs https://app.dimensions.ai/details/publication/pub.1037552485
197 rdf:type schema:CreativeWork
198 https://doi.org/10.1016/s0012-821x(04)00096-2 schema:sameAs https://app.dimensions.ai/details/publication/pub.1050069736
199 rdf:type schema:CreativeWork
200 https://doi.org/10.1016/s0016-7037(03)00174-1 schema:sameAs https://app.dimensions.ai/details/publication/pub.1032680073
201 rdf:type schema:CreativeWork
202 https://doi.org/10.1016/s0016-7037(97)00198-1 schema:sameAs https://app.dimensions.ai/details/publication/pub.1012383251
203 rdf:type schema:CreativeWork
204 https://doi.org/10.1016/s0016-7037(98)00131-8 schema:sameAs https://app.dimensions.ai/details/publication/pub.1011838709
205 rdf:type schema:CreativeWork
206 https://doi.org/10.1016/s0016-7037(98)00224-5 schema:sameAs https://app.dimensions.ai/details/publication/pub.1005731403
207 rdf:type schema:CreativeWork
208 https://doi.org/10.1016/s0024-4937(00)00024-4 schema:sameAs https://app.dimensions.ai/details/publication/pub.1033197092
209 rdf:type schema:CreativeWork
210 https://doi.org/10.1016/s0097-8485(00)00060-7 schema:sameAs https://app.dimensions.ai/details/publication/pub.1002457115
211 rdf:type schema:CreativeWork
212 https://doi.org/10.1021/j100247a015 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055660918
213 rdf:type schema:CreativeWork
214 https://doi.org/10.1021/jp001303i schema:sameAs https://app.dimensions.ai/details/publication/pub.1056043037
215 rdf:type schema:CreativeWork
216 https://doi.org/10.1029/1999gl008425 schema:sameAs https://app.dimensions.ai/details/publication/pub.1023183735
217 rdf:type schema:CreativeWork
218 https://doi.org/10.1029/1999jb900145 schema:sameAs https://app.dimensions.ai/details/publication/pub.1034176404
219 rdf:type schema:CreativeWork
220 https://doi.org/10.1039/a606455h schema:sameAs https://app.dimensions.ai/details/publication/pub.1011485596
221 rdf:type schema:CreativeWork
222 https://doi.org/10.1039/c39840001271 schema:sameAs https://app.dimensions.ai/details/publication/pub.1043919339
223 rdf:type schema:CreativeWork
224 https://doi.org/10.1086/375492 schema:sameAs https://app.dimensions.ai/details/publication/pub.1036806953
225 rdf:type schema:CreativeWork
226 https://doi.org/10.1088/0022-3719/18/6/010 schema:sameAs https://app.dimensions.ai/details/publication/pub.1058962743
227 rdf:type schema:CreativeWork
228 https://doi.org/10.1088/0953-8984/17/7/004 schema:sameAs https://app.dimensions.ai/details/publication/pub.1004623356
229 rdf:type schema:CreativeWork
230 https://doi.org/10.1126/science.265.5176.1202 schema:sameAs https://app.dimensions.ai/details/publication/pub.1062548735
231 rdf:type schema:CreativeWork
232 https://doi.org/10.1127/0935-1221/2003/0015-0893 schema:sameAs https://app.dimensions.ai/details/publication/pub.1062698181
233 rdf:type schema:CreativeWork
234 https://doi.org/10.1127/0935-1221/2006/0018-0529 schema:sameAs https://app.dimensions.ai/details/publication/pub.1062698444
235 rdf:type schema:CreativeWork
236 https://doi.org/10.1127/ejm/3/2/0387 schema:sameAs https://app.dimensions.ai/details/publication/pub.1062703529
237 rdf:type schema:CreativeWork
238 https://doi.org/10.1180/0026461056910232 schema:sameAs https://app.dimensions.ai/details/publication/pub.1020711104
239 rdf:type schema:CreativeWork
240 https://doi.org/10.2138/am-2000-0110 schema:sameAs https://app.dimensions.ai/details/publication/pub.1069056025
241 rdf:type schema:CreativeWork
242 https://doi.org/10.2138/am-2002-1025 schema:sameAs https://app.dimensions.ai/details/publication/pub.1069056490
243 rdf:type schema:CreativeWork
244 https://doi.org/10.2138/am.2006.2083 schema:sameAs https://app.dimensions.ai/details/publication/pub.1047489348
245 rdf:type schema:CreativeWork
246 https://doi.org/10.2138/am.2012.3913 schema:sameAs https://app.dimensions.ai/details/publication/pub.1015082191
247 rdf:type schema:CreativeWork
248 https://doi.org/10.2138/am.2014.4676 schema:sameAs https://app.dimensions.ai/details/publication/pub.1028449418
249 rdf:type schema:CreativeWork
250 https://www.grid.ac/institutes/grid.410726.6 schema:alternateName University of Chinese Academy of Sciences
251 schema:name State Key Laboratory of Ore Deposit Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, 550081, Guiyang, China
252 University of the Chinese Academy of Sciences, 100049, Beijing, China
253 rdf:type schema:Organization
254 https://www.grid.ac/institutes/grid.440652.1 schema:alternateName Suzhou University of Science and Technology
255 schema:name School of Mathematics and Physics, Suzhou University of Science and Technology, 215009, Suzhou, China
256 rdf:type schema:Organization
257 https://www.grid.ac/institutes/grid.458476.c schema:alternateName Institute of Geology and Geophysics
258 schema:name Key Laboratory of Earth and Planetary Physics, Institute of Geology and Geophysics, Chinese Academy of Sciences, 100029, Beijing, China
259 State Key Laboratory of Ore Deposit Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, 550081, Guiyang, China
260 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...