Comprehensive physicochemical study of dioctahedral palygorskite-rich clay from Marrakech High Atlas (Morocco) View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2013-05

AUTHORS

Benaissa Rhouta, Ezzouhra Zatile, Lahcen Bouna, Omar Lakbita, Francis Maury, Lahcen Daoudi, Marie Christine Lafont, M’Barek Amjoud, François Senocq, Amane Jada, Ahmed Aït Aghzzaf

ABSTRACT

This study is devoted to the physicochemical and mineralogical characterizations of palygorskite from Marrakech High Atlas, Morocco. The raw clay and its Na+-saturated <2 μm fraction were characterized using chemical, structural, and thermal analytical techniques. Measurements of specific surface area and porous volume are reported. The clay fraction was found to be made up of 95 % of palygorskite and 5 % of sepiolite. An original feature of this palygorskite is its deficiency in zeolitic H2O. The half-cell structural formula of its dehydrated form was determined on the basis of 21 oxygens to be (Si7.92Al0.08)(Mg2.15Al1.4Fe0.4Ti0.05)(Ca0.03Na0.08K0.04)O21, while the hydrated form could be formulated as (Si7.97Al0.03)(Mg2.17Al1.46Fe0.40Ti0.05)(Ca0.03Na0.07K0,03)O20.18(OH)1.94(OH2)3.88·2.43 H2O. These formulas show that the (Al3++Fe3+)/Mg2+ ratio is around 0.84, revealing a pronounced dioctahedral character. Further, inside its octahedral sheet, it was determined that the inner M1 sites are occupied by vacancies, whereas the M2 sites are shared between 90 % of trivalent cations (78 % for Al3+ and 22 % for Fe3+), 7.5 % of Mg2+, and 2.5 % of Ti4+, all of them linked to 1.94 of structural hydroxyls. The two remaining Mg2+ by half-cell occupy edge M3 sites and are coordinated to 3.88 molecules of OH2. Channels of this palygorskite are deficient in zeolitic H2O since they contain only 2.43 H2O molecules. A correlation was found between these results and the observation of very intense and well-resolved FTIR bands arising from dioctahedral domains (mainly Al2OH, Fe2OH, and AlFeOH) along with very small responses from a trioctahedral domain (Mg3OH). Accordingly, a schematic representation of the composition of the octahedral sheet was proposed. The cation exchange capacity, specific surface area, and total pore volume were also assessed to be ca. 21.2 meq/100 g, 116 m2/g, and 0.458 cm3/g, respectively. More... »

PAGES

411-424

References to SciGraph publications

  • 2002-06. Infrared evidence of dioctahedral-trioctahedral site occupancy in palygorskite in CLAYS AND CLAY MINERALS
  • 2012-06. Mineralogical and Physico-Chemical Characterizations of Ferruginous Beidellite-Rich Clay from Agadir Basin (Morocco) in CLAYS AND CLAY MINERALS
  • 1999-11. Experimental and theoretical studies of palygorskite clays in JOURNAL OF MATERIALS SCIENCE
  • 2007-12. Crystallochemical characterization of the palygorskite and sepiolite from the Allou Kagne deposit, Senegal in CLAYS AND CLAY MINERALS
  • 1992-08. The Coordination of Aluminum Ions in the Palygorskite Structure in CLAYS AND CLAY MINERALS
  • 2007-02. Adsorption capacity and mineralogical and physico-chemical characteristics of Shuwaymiyah palygorskite (Oman) in ENVIRONMENTAL GEOLOGY
  • 2007-12. Combined near-infrared and X-ray diffraction investigation of the octahedral sheet composition of palygorskite in CLAYS AND CLAY MINERALS
  • 1988. Analyse minéralogique quantitative d'un échantillon de sol : utilisation des données concernant la composition chimique de l'échantillon in AGRONOMY FOR SUSTAINABLE DEVELOPMENT
  • 1991-04. Evolution of the Porous Structure and Surface Area of Palygorskite Under Vacuum Thermal Treatment in CLAYS AND CLAY MINERALS
  • 2010-02. On the Chemical Composition of Sepiolite and Palygorskite in CLAYS AND CLAY MINERALS
  • 1999-08. A New Approach to Compositional Limits for Sepiolite and Palygorskite in CLAYS AND CLAY MINERALS
  • 2001-10. Baseline studies of the clay minerals society source clays: Layer-charge determination and characteristics of those minerals containing 2:1 layers in CLAYS AND CLAY MINERALS
  • 1984-02. Estimation of Clay Proportions in Mixtures by X-Ray Diffraction and Computerized Chemical Mass Balance in CLAYS AND CLAY MINERALS
  • 1986-02. Detection of Nonequivalent Si Sites in Sepiolite and Palygorskite by Solid-State 29Si Magic Angle Spinning-Nuclear Magnetic Resonance in CLAYS AND CLAY MINERALS
  • 1976-04. A Mössbauer and I.R. Spectroscopic Study of the Structure of Nontronite in CLAYS AND CLAY MINERALS
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/s00269-013-0579-3

    DOI

    http://dx.doi.org/10.1007/s00269-013-0579-3

    DIMENSIONS

    https://app.dimensions.ai/details/publication/pub.1033421591


    Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
    Incoming Citations Browse incoming citations for this publication using opencitations.net

    JSON-LD is the canonical representation for SciGraph data.

    TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

    [
      {
        "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
        "about": [
          {
            "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0601", 
            "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
            "name": "Biochemistry and Cell Biology", 
            "type": "DefinedTerm"
          }, 
          {
            "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/06", 
            "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
            "name": "Biological Sciences", 
            "type": "DefinedTerm"
          }
        ], 
        "author": [
          {
            "affiliation": {
              "alternateName": "Cadi Ayyad University", 
              "id": "https://www.grid.ac/institutes/grid.411840.8", 
              "name": [
                "Laboratoire de Mati\u00e8re Condens\u00e9e et Nanostructures (LMCN), Facult\u00e9 des Sciences et Techniques Gu\u00e9liz, Universit\u00e9 Cadi Ayyad, BP 549, Marrakech, Morocco"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Rhouta", 
            "givenName": "Benaissa", 
            "id": "sg:person.014064177623.21", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014064177623.21"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Cadi Ayyad University", 
              "id": "https://www.grid.ac/institutes/grid.411840.8", 
              "name": [
                "Laboratoire de Mati\u00e8re Condens\u00e9e et Nanostructures (LMCN), Facult\u00e9 des Sciences et Techniques Gu\u00e9liz, Universit\u00e9 Cadi Ayyad, BP 549, Marrakech, Morocco"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Zatile", 
            "givenName": "Ezzouhra", 
            "id": "sg:person.0735056374.79", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0735056374.79"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Cadi Ayyad University", 
              "id": "https://www.grid.ac/institutes/grid.411840.8", 
              "name": [
                "Laboratoire de Mati\u00e8re Condens\u00e9e et Nanostructures (LMCN), Facult\u00e9 des Sciences et Techniques Gu\u00e9liz, Universit\u00e9 Cadi Ayyad, BP 549, Marrakech, Morocco"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Bouna", 
            "givenName": "Lahcen", 
            "id": "sg:person.015213205543.56", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015213205543.56"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Cadi Ayyad University", 
              "id": "https://www.grid.ac/institutes/grid.411840.8", 
              "name": [
                "Laboratoire de Mati\u00e8re Condens\u00e9e et Nanostructures (LMCN), Facult\u00e9 des Sciences et Techniques Gu\u00e9liz, Universit\u00e9 Cadi Ayyad, BP 549, Marrakech, Morocco"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Lakbita", 
            "givenName": "Omar", 
            "id": "sg:person.016010566143.43", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016010566143.43"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Inter university Material Research and Engineering Centre", 
              "id": "https://www.grid.ac/institutes/grid.464172.2", 
              "name": [
                "CIRIMAT, CNRS-UPS-INP, ENSIACET, 4 all\u00e9e Emile Monso, BP 44362, 31030, Toulouse Cedex 4, France"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Maury", 
            "givenName": "Francis", 
            "id": "sg:person.011121552621.19", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011121552621.19"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Cadi Ayyad University", 
              "id": "https://www.grid.ac/institutes/grid.411840.8", 
              "name": [
                "Laboratoire de G\u00e9osciences et G\u00e9oenvironnement, Facult\u00e9 des Sciences et Techniques Gu\u00e9liz, Universit\u00e9 Cadi Ayyad, BP 549, Marrakech, Morocco"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Daoudi", 
            "givenName": "Lahcen", 
            "id": "sg:person.012471236623.20", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012471236623.20"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Inter university Material Research and Engineering Centre", 
              "id": "https://www.grid.ac/institutes/grid.464172.2", 
              "name": [
                "CIRIMAT, CNRS-UPS-INP, ENSIACET, 4 all\u00e9e Emile Monso, BP 44362, 31030, Toulouse Cedex 4, France"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Lafont", 
            "givenName": "Marie Christine", 
            "id": "sg:person.016605006607.32", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016605006607.32"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Cadi Ayyad University", 
              "id": "https://www.grid.ac/institutes/grid.411840.8", 
              "name": [
                "Laboratoire de Mati\u00e8re Condens\u00e9e et Nanostructures (LMCN), Facult\u00e9 des Sciences et Techniques Gu\u00e9liz, Universit\u00e9 Cadi Ayyad, BP 549, Marrakech, Morocco"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Amjoud", 
            "givenName": "M\u2019Barek", 
            "id": "sg:person.014414767235.08", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014414767235.08"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Inter university Material Research and Engineering Centre", 
              "id": "https://www.grid.ac/institutes/grid.464172.2", 
              "name": [
                "CIRIMAT, CNRS-UPS-INP, ENSIACET, 4 all\u00e9e Emile Monso, BP 44362, 31030, Toulouse Cedex 4, France"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Senocq", 
            "givenName": "Fran\u00e7ois", 
            "id": "sg:person.014724657063.44", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014724657063.44"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "French National Centre for Scientific Research", 
              "id": "https://www.grid.ac/institutes/grid.4444.0", 
              "name": [
                "Institut de Sciences des Mat\u00e9riaux de Mulhouse IS2\u00a0M LRC 7228, CNRS, 15 rue jean Starcky BP 2488, 68057, Mulhouse Cedex, France"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Jada", 
            "givenName": "Amane", 
            "id": "sg:person.012476172412.48", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012476172412.48"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Cadi Ayyad University", 
              "id": "https://www.grid.ac/institutes/grid.411840.8", 
              "name": [
                "Laboratoire de Mati\u00e8re Condens\u00e9e et Nanostructures (LMCN), Facult\u00e9 des Sciences et Techniques Gu\u00e9liz, Universit\u00e9 Cadi Ayyad, BP 549, Marrakech, Morocco"
              ], 
              "type": "Organization"
            }, 
            "familyName": "A\u00eft Aghzzaf", 
            "givenName": "Ahmed", 
            "id": "sg:person.07612165271.72", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07612165271.72"
            ], 
            "type": "Person"
          }
        ], 
        "citation": [
          {
            "id": "https://doi.org/10.1016/j.jinorgbio.2007.07.009", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1000330154"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/j.clay.2012.04.025", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1000500551"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/j.clay.2012.04.025", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1000500551"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1351/pac198557040603", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1006669173"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/j.clay.2012.04.005", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1008114328"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/j.clay.2011.01.027", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1010274986"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/s00254-006-0430-y", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1011291297", 
              "https://doi.org/10.1007/s00254-006-0430-y"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/s00254-006-0430-y", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1011291297", 
              "https://doi.org/10.1007/s00254-006-0430-y"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/j.clay.2007.05.001", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1011868419"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1346/ccmn.2010.0580101", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1016732130"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1346/ccmn.2010.0580101", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1016732130", 
              "https://doi.org/10.1346/ccmn.2010.0580101"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1080/00387018908053926", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1017261739"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1051/agro:19880102", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1018508636", 
              "https://doi.org/10.1051/agro:19880102"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/s0040-6031(02)00228-9", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1019613058"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1346/ccmn.2007.0550608", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1021425627"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1346/ccmn.2007.0550608", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1021425627", 
              "https://doi.org/10.1346/ccmn.2007.0550608"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/0169-1317(94)90006-x", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1021433708"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/0169-1317(94)90006-x", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1021433708"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/b978-0-08-009235-5.50026-7", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1022852138"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.2138/am.2006.2023", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1024616623"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1111/j.1151-2916.1986.tb07433.x", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1024813195"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/j.jafrearsci.2004.07.033", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1025280560"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/j.msea.2006.06.001", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1027565040"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/s0022-3697(97)00166-2", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1028771449"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/j.clay.2011.09.012", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1033583827"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1023/a:1004724316051", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1033769087", 
              "https://doi.org/10.1023/a:1004724316051"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1346/ccmn.2012.0600305", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1034327334"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1346/ccmn.2012.0600305", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1034327334", 
              "https://doi.org/10.1346/ccmn.2012.0600305"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/0095-8522(66)90006-7", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1035819615"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/j.apcatb.2012.01.008", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1036908863"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/j.clay.2011.03.009", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1039289030"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/0899-5362(94)90025-6", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1042880810"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/0899-5362(94)90025-6", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1042880810"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1180/claymin.2008.043.3.05", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1045412550"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/j.clay.2005.10.005", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1045833207"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/j.clay.2005.10.005", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1045833207"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/j.clay.2012.04.017", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1045955220"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1346/ccmn.2007.0550601", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1046134148"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1346/ccmn.2007.0550601", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1046134148", 
              "https://doi.org/10.1346/ccmn.2007.0550601"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/s0169-1317(00)00016-8", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1047755427"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/j.nimb.2007.04.218", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1049827137"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1180/claymin.2011.046.3.371", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1050431801"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1039/b003197f", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1050785653"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/ja00535a008", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1055740136"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/ja01145a126", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1055773283"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/ja01269a023", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1055787826"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1126/science.154.3749.645", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1062489861"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1126/science.273.5272.223", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1062553590"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1127/0935-1221/2004/0016-0521", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1062698252"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1180/000985599545966", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1064111724"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1180/claymin.1978.013.4.02", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1064112741"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1180/claymin.1996.031.4.01", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1064113743"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1346/00098600260358067", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1065017344"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1346/00098600260358067", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1065017344", 
              "https://doi.org/10.1346/00098600260358067"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1346/ccmn.1976.0240201", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1065018564"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1346/ccmn.1976.0240201", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1065018564", 
              "https://doi.org/10.1346/ccmn.1976.0240201"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1346/ccmn.1984.0320103", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1065019137"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1346/ccmn.1984.0320103", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1065019137", 
              "https://doi.org/10.1346/ccmn.1984.0320103"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1346/ccmn.1986.0340113", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1065019312"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1346/ccmn.1986.0340113", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1065019312", 
              "https://doi.org/10.1346/ccmn.1986.0340113"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1346/ccmn.1991.0390211", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1065019763"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1346/ccmn.1991.0390211", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1065019763", 
              "https://doi.org/10.1346/ccmn.1991.0390211"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1346/ccmn.1992.0400410", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1065019884"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1346/ccmn.1992.0400410", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1065019884", 
              "https://doi.org/10.1346/ccmn.1992.0400410"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1346/ccmn.1999.0470402", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1065020507"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1346/ccmn.1999.0470402", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1065020507", 
              "https://doi.org/10.1346/ccmn.1999.0470402"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1346/ccmn.2001.0490506", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1065020684"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1346/ccmn.2001.0490506", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1065020684", 
              "https://doi.org/10.1346/ccmn.2001.0490506"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.4028/www.scientific.net/msf.166-169.647", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1072103277"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1180/mono-5.1", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1090269599"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.3406/argil.1960.974", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1100417897"
            ], 
            "type": "CreativeWork"
          }
        ], 
        "datePublished": "2013-05", 
        "datePublishedReg": "2013-05-01", 
        "description": "This study is devoted to the physicochemical and mineralogical characterizations of palygorskite from Marrakech High Atlas, Morocco. The raw clay and its Na+-saturated <2 \u03bcm fraction were characterized using chemical, structural, and thermal analytical techniques. Measurements of specific surface area and porous volume are reported. The clay fraction was found to be made up of 95 % of palygorskite and 5 % of sepiolite. An original feature of this palygorskite is its deficiency in zeolitic H2O. The half-cell structural formula of its dehydrated form was determined on the basis of 21 oxygens to be (Si7.92Al0.08)(Mg2.15Al1.4Fe0.4Ti0.05)(Ca0.03Na0.08K0.04)O21, while the hydrated form could be formulated as (Si7.97Al0.03)(Mg2.17Al1.46Fe0.40Ti0.05)(Ca0.03Na0.07K0,03)O20.18(OH)1.94(OH2)3.88\u00b72.43 H2O. These formulas show that the (Al3++Fe3+)/Mg2+ ratio is around 0.84, revealing a pronounced dioctahedral character. Further, inside its octahedral sheet, it was determined that the inner M1 sites are occupied by vacancies, whereas the M2 sites are shared between 90 % of trivalent cations (78 % for Al3+ and 22 % for Fe3+), 7.5 % of Mg2+, and 2.5 % of Ti4+, all of them linked to 1.94 of structural hydroxyls. The two remaining Mg2+ by half-cell occupy edge M3 sites and are coordinated to 3.88 molecules of OH2. Channels of this palygorskite are deficient in zeolitic H2O since they contain only 2.43 H2O molecules. A correlation was found between these results and the observation of very intense and well-resolved FTIR bands arising from dioctahedral domains (mainly Al2OH, Fe2OH, and AlFeOH) along with very small responses from a trioctahedral domain (Mg3OH). Accordingly, a schematic representation of the composition of the octahedral sheet was proposed. The cation exchange capacity, specific surface area, and total pore volume were also assessed to be ca. 21.2 meq/100 g, 116 m2/g, and 0.458 cm3/g, respectively.", 
        "genre": "research_article", 
        "id": "sg:pub.10.1007/s00269-013-0579-3", 
        "inLanguage": [
          "en"
        ], 
        "isAccessibleForFree": false, 
        "isPartOf": [
          {
            "id": "sg:journal.1052149", 
            "issn": [
              "0342-1791", 
              "1432-2021"
            ], 
            "name": "Physics and Chemistry of Minerals", 
            "type": "Periodical"
          }, 
          {
            "issueNumber": "5", 
            "type": "PublicationIssue"
          }, 
          {
            "type": "PublicationVolume", 
            "volumeNumber": "40"
          }
        ], 
        "name": "Comprehensive physicochemical study of dioctahedral palygorskite-rich clay from Marrakech High Atlas (Morocco)", 
        "pagination": "411-424", 
        "productId": [
          {
            "name": "readcube_id", 
            "type": "PropertyValue", 
            "value": [
              "9f3683a0ca8c8414e00b6975d2526c701876cdd7c02048f16441b68904e687a0"
            ]
          }, 
          {
            "name": "doi", 
            "type": "PropertyValue", 
            "value": [
              "10.1007/s00269-013-0579-3"
            ]
          }, 
          {
            "name": "dimensions_id", 
            "type": "PropertyValue", 
            "value": [
              "pub.1033421591"
            ]
          }
        ], 
        "sameAs": [
          "https://doi.org/10.1007/s00269-013-0579-3", 
          "https://app.dimensions.ai/details/publication/pub.1033421591"
        ], 
        "sdDataset": "articles", 
        "sdDatePublished": "2019-04-10T19:57", 
        "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
        "sdPublisher": {
          "name": "Springer Nature - SN SciGraph project", 
          "type": "Organization"
        }, 
        "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8681_00000514.jsonl", 
        "type": "ScholarlyArticle", 
        "url": "http://link.springer.com/10.1007%2Fs00269-013-0579-3"
      }
    ]
     

    Download the RDF metadata as:  json-ld nt turtle xml License info

    HOW TO GET THIS DATA PROGRAMMATICALLY:

    JSON-LD is a popular format for linked data which is fully compatible with JSON.

    curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s00269-013-0579-3'

    N-Triples is a line-based linked data format ideal for batch operations.

    curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s00269-013-0579-3'

    Turtle is a human-readable linked data format.

    curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s00269-013-0579-3'

    RDF/XML is a standard XML format for linked data.

    curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s00269-013-0579-3'


     

    This table displays all metadata directly associated to this object as RDF triples.

    351 TRIPLES      21 PREDICATES      93 URIs      19 LITERALS      7 BLANK NODES

    Subject Predicate Object
    1 sg:pub.10.1007/s00269-013-0579-3 schema:about anzsrc-for:06
    2 anzsrc-for:0601
    3 schema:author Nde21ef59a271445ea691b5fe01f774c9
    4 schema:citation sg:pub.10.1007/s00254-006-0430-y
    5 sg:pub.10.1023/a:1004724316051
    6 sg:pub.10.1051/agro:19880102
    7 sg:pub.10.1346/00098600260358067
    8 sg:pub.10.1346/ccmn.1976.0240201
    9 sg:pub.10.1346/ccmn.1984.0320103
    10 sg:pub.10.1346/ccmn.1986.0340113
    11 sg:pub.10.1346/ccmn.1991.0390211
    12 sg:pub.10.1346/ccmn.1992.0400410
    13 sg:pub.10.1346/ccmn.1999.0470402
    14 sg:pub.10.1346/ccmn.2001.0490506
    15 sg:pub.10.1346/ccmn.2007.0550601
    16 sg:pub.10.1346/ccmn.2007.0550608
    17 sg:pub.10.1346/ccmn.2010.0580101
    18 sg:pub.10.1346/ccmn.2012.0600305
    19 https://doi.org/10.1016/0095-8522(66)90006-7
    20 https://doi.org/10.1016/0169-1317(94)90006-x
    21 https://doi.org/10.1016/0899-5362(94)90025-6
    22 https://doi.org/10.1016/b978-0-08-009235-5.50026-7
    23 https://doi.org/10.1016/j.apcatb.2012.01.008
    24 https://doi.org/10.1016/j.clay.2005.10.005
    25 https://doi.org/10.1016/j.clay.2007.05.001
    26 https://doi.org/10.1016/j.clay.2011.01.027
    27 https://doi.org/10.1016/j.clay.2011.03.009
    28 https://doi.org/10.1016/j.clay.2011.09.012
    29 https://doi.org/10.1016/j.clay.2012.04.005
    30 https://doi.org/10.1016/j.clay.2012.04.017
    31 https://doi.org/10.1016/j.clay.2012.04.025
    32 https://doi.org/10.1016/j.jafrearsci.2004.07.033
    33 https://doi.org/10.1016/j.jinorgbio.2007.07.009
    34 https://doi.org/10.1016/j.msea.2006.06.001
    35 https://doi.org/10.1016/j.nimb.2007.04.218
    36 https://doi.org/10.1016/s0022-3697(97)00166-2
    37 https://doi.org/10.1016/s0040-6031(02)00228-9
    38 https://doi.org/10.1016/s0169-1317(00)00016-8
    39 https://doi.org/10.1021/ja00535a008
    40 https://doi.org/10.1021/ja01145a126
    41 https://doi.org/10.1021/ja01269a023
    42 https://doi.org/10.1039/b003197f
    43 https://doi.org/10.1080/00387018908053926
    44 https://doi.org/10.1111/j.1151-2916.1986.tb07433.x
    45 https://doi.org/10.1126/science.154.3749.645
    46 https://doi.org/10.1126/science.273.5272.223
    47 https://doi.org/10.1127/0935-1221/2004/0016-0521
    48 https://doi.org/10.1180/000985599545966
    49 https://doi.org/10.1180/claymin.1978.013.4.02
    50 https://doi.org/10.1180/claymin.1996.031.4.01
    51 https://doi.org/10.1180/claymin.2008.043.3.05
    52 https://doi.org/10.1180/claymin.2011.046.3.371
    53 https://doi.org/10.1180/mono-5.1
    54 https://doi.org/10.1346/00098600260358067
    55 https://doi.org/10.1346/ccmn.1976.0240201
    56 https://doi.org/10.1346/ccmn.1984.0320103
    57 https://doi.org/10.1346/ccmn.1986.0340113
    58 https://doi.org/10.1346/ccmn.1991.0390211
    59 https://doi.org/10.1346/ccmn.1992.0400410
    60 https://doi.org/10.1346/ccmn.1999.0470402
    61 https://doi.org/10.1346/ccmn.2001.0490506
    62 https://doi.org/10.1346/ccmn.2007.0550601
    63 https://doi.org/10.1346/ccmn.2007.0550608
    64 https://doi.org/10.1346/ccmn.2010.0580101
    65 https://doi.org/10.1346/ccmn.2012.0600305
    66 https://doi.org/10.1351/pac198557040603
    67 https://doi.org/10.2138/am.2006.2023
    68 https://doi.org/10.3406/argil.1960.974
    69 https://doi.org/10.4028/www.scientific.net/msf.166-169.647
    70 schema:datePublished 2013-05
    71 schema:datePublishedReg 2013-05-01
    72 schema:description This study is devoted to the physicochemical and mineralogical characterizations of palygorskite from Marrakech High Atlas, Morocco. The raw clay and its Na+-saturated <2 μm fraction were characterized using chemical, structural, and thermal analytical techniques. Measurements of specific surface area and porous volume are reported. The clay fraction was found to be made up of 95 % of palygorskite and 5 % of sepiolite. An original feature of this palygorskite is its deficiency in zeolitic H2O. The half-cell structural formula of its dehydrated form was determined on the basis of 21 oxygens to be (Si7.92Al0.08)(Mg2.15Al1.4Fe0.4Ti0.05)(Ca0.03Na0.08K0.04)O21, while the hydrated form could be formulated as (Si7.97Al0.03)(Mg2.17Al1.46Fe0.40Ti0.05)(Ca0.03Na0.07K0,03)O20.18(OH)1.94(OH2)3.88·2.43 H2O. These formulas show that the (Al3++Fe3+)/Mg2+ ratio is around 0.84, revealing a pronounced dioctahedral character. Further, inside its octahedral sheet, it was determined that the inner M1 sites are occupied by vacancies, whereas the M2 sites are shared between 90 % of trivalent cations (78 % for Al3+ and 22 % for Fe3+), 7.5 % of Mg2+, and 2.5 % of Ti4+, all of them linked to 1.94 of structural hydroxyls. The two remaining Mg2+ by half-cell occupy edge M3 sites and are coordinated to 3.88 molecules of OH2. Channels of this palygorskite are deficient in zeolitic H2O since they contain only 2.43 H2O molecules. A correlation was found between these results and the observation of very intense and well-resolved FTIR bands arising from dioctahedral domains (mainly Al2OH, Fe2OH, and AlFeOH) along with very small responses from a trioctahedral domain (Mg3OH). Accordingly, a schematic representation of the composition of the octahedral sheet was proposed. The cation exchange capacity, specific surface area, and total pore volume were also assessed to be ca. 21.2 meq/100 g, 116 m2/g, and 0.458 cm3/g, respectively.
    73 schema:genre research_article
    74 schema:inLanguage en
    75 schema:isAccessibleForFree false
    76 schema:isPartOf Nb3b6b3e35c0c45c3976a73363fddbc9c
    77 Nd27716bbc3e740038c12ac3d8198ef9f
    78 sg:journal.1052149
    79 schema:name Comprehensive physicochemical study of dioctahedral palygorskite-rich clay from Marrakech High Atlas (Morocco)
    80 schema:pagination 411-424
    81 schema:productId N599793f3c81c4b14bf600d983e49a25d
    82 N9742dde108704b408db3fc0a0ce1216f
    83 Nb6e95d9de73f48f2af8c4bdeeee7bee9
    84 schema:sameAs https://app.dimensions.ai/details/publication/pub.1033421591
    85 https://doi.org/10.1007/s00269-013-0579-3
    86 schema:sdDatePublished 2019-04-10T19:57
    87 schema:sdLicense https://scigraph.springernature.com/explorer/license/
    88 schema:sdPublisher N057818bb4eda4bc08a61251908e69d6a
    89 schema:url http://link.springer.com/10.1007%2Fs00269-013-0579-3
    90 sgo:license sg:explorer/license/
    91 sgo:sdDataset articles
    92 rdf:type schema:ScholarlyArticle
    93 N057818bb4eda4bc08a61251908e69d6a schema:name Springer Nature - SN SciGraph project
    94 rdf:type schema:Organization
    95 N0ce73be936bb478dbbb023522b87d07a rdf:first sg:person.012476172412.48
    96 rdf:rest Nd2cb1afbf45147538cc36c6e605e054f
    97 N0f38aa1d03be4f049b20c607e7a85c46 rdf:first sg:person.016010566143.43
    98 rdf:rest Nc96a28f27c8741928ce830aae370af54
    99 N1413708bfbe2410aa61122ff0928af77 rdf:first sg:person.012471236623.20
    100 rdf:rest Nd2b53b45c0954630a6eb5843f8076dc5
    101 N213b769bcf704b6a819540127b768cca rdf:first sg:person.015213205543.56
    102 rdf:rest N0f38aa1d03be4f049b20c607e7a85c46
    103 N332233c6b5714ef0b7b62c0fd5aa1e94 rdf:first sg:person.0735056374.79
    104 rdf:rest N213b769bcf704b6a819540127b768cca
    105 N47ddc17defad4db4a1c0591694e8cb3c rdf:first sg:person.014414767235.08
    106 rdf:rest Nf33596edde894b18aaff71119ce2bc56
    107 N599793f3c81c4b14bf600d983e49a25d schema:name doi
    108 schema:value 10.1007/s00269-013-0579-3
    109 rdf:type schema:PropertyValue
    110 N9742dde108704b408db3fc0a0ce1216f schema:name readcube_id
    111 schema:value 9f3683a0ca8c8414e00b6975d2526c701876cdd7c02048f16441b68904e687a0
    112 rdf:type schema:PropertyValue
    113 Nb3b6b3e35c0c45c3976a73363fddbc9c schema:issueNumber 5
    114 rdf:type schema:PublicationIssue
    115 Nb6e95d9de73f48f2af8c4bdeeee7bee9 schema:name dimensions_id
    116 schema:value pub.1033421591
    117 rdf:type schema:PropertyValue
    118 Nc96a28f27c8741928ce830aae370af54 rdf:first sg:person.011121552621.19
    119 rdf:rest N1413708bfbe2410aa61122ff0928af77
    120 Nd27716bbc3e740038c12ac3d8198ef9f schema:volumeNumber 40
    121 rdf:type schema:PublicationVolume
    122 Nd2b53b45c0954630a6eb5843f8076dc5 rdf:first sg:person.016605006607.32
    123 rdf:rest N47ddc17defad4db4a1c0591694e8cb3c
    124 Nd2cb1afbf45147538cc36c6e605e054f rdf:first sg:person.07612165271.72
    125 rdf:rest rdf:nil
    126 Nde21ef59a271445ea691b5fe01f774c9 rdf:first sg:person.014064177623.21
    127 rdf:rest N332233c6b5714ef0b7b62c0fd5aa1e94
    128 Nf33596edde894b18aaff71119ce2bc56 rdf:first sg:person.014724657063.44
    129 rdf:rest N0ce73be936bb478dbbb023522b87d07a
    130 anzsrc-for:06 schema:inDefinedTermSet anzsrc-for:
    131 schema:name Biological Sciences
    132 rdf:type schema:DefinedTerm
    133 anzsrc-for:0601 schema:inDefinedTermSet anzsrc-for:
    134 schema:name Biochemistry and Cell Biology
    135 rdf:type schema:DefinedTerm
    136 sg:journal.1052149 schema:issn 0342-1791
    137 1432-2021
    138 schema:name Physics and Chemistry of Minerals
    139 rdf:type schema:Periodical
    140 sg:person.011121552621.19 schema:affiliation https://www.grid.ac/institutes/grid.464172.2
    141 schema:familyName Maury
    142 schema:givenName Francis
    143 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011121552621.19
    144 rdf:type schema:Person
    145 sg:person.012471236623.20 schema:affiliation https://www.grid.ac/institutes/grid.411840.8
    146 schema:familyName Daoudi
    147 schema:givenName Lahcen
    148 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012471236623.20
    149 rdf:type schema:Person
    150 sg:person.012476172412.48 schema:affiliation https://www.grid.ac/institutes/grid.4444.0
    151 schema:familyName Jada
    152 schema:givenName Amane
    153 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012476172412.48
    154 rdf:type schema:Person
    155 sg:person.014064177623.21 schema:affiliation https://www.grid.ac/institutes/grid.411840.8
    156 schema:familyName Rhouta
    157 schema:givenName Benaissa
    158 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014064177623.21
    159 rdf:type schema:Person
    160 sg:person.014414767235.08 schema:affiliation https://www.grid.ac/institutes/grid.411840.8
    161 schema:familyName Amjoud
    162 schema:givenName M’Barek
    163 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014414767235.08
    164 rdf:type schema:Person
    165 sg:person.014724657063.44 schema:affiliation https://www.grid.ac/institutes/grid.464172.2
    166 schema:familyName Senocq
    167 schema:givenName François
    168 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014724657063.44
    169 rdf:type schema:Person
    170 sg:person.015213205543.56 schema:affiliation https://www.grid.ac/institutes/grid.411840.8
    171 schema:familyName Bouna
    172 schema:givenName Lahcen
    173 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015213205543.56
    174 rdf:type schema:Person
    175 sg:person.016010566143.43 schema:affiliation https://www.grid.ac/institutes/grid.411840.8
    176 schema:familyName Lakbita
    177 schema:givenName Omar
    178 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016010566143.43
    179 rdf:type schema:Person
    180 sg:person.016605006607.32 schema:affiliation https://www.grid.ac/institutes/grid.464172.2
    181 schema:familyName Lafont
    182 schema:givenName Marie Christine
    183 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016605006607.32
    184 rdf:type schema:Person
    185 sg:person.0735056374.79 schema:affiliation https://www.grid.ac/institutes/grid.411840.8
    186 schema:familyName Zatile
    187 schema:givenName Ezzouhra
    188 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0735056374.79
    189 rdf:type schema:Person
    190 sg:person.07612165271.72 schema:affiliation https://www.grid.ac/institutes/grid.411840.8
    191 schema:familyName Aït Aghzzaf
    192 schema:givenName Ahmed
    193 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07612165271.72
    194 rdf:type schema:Person
    195 sg:pub.10.1007/s00254-006-0430-y schema:sameAs https://app.dimensions.ai/details/publication/pub.1011291297
    196 https://doi.org/10.1007/s00254-006-0430-y
    197 rdf:type schema:CreativeWork
    198 sg:pub.10.1023/a:1004724316051 schema:sameAs https://app.dimensions.ai/details/publication/pub.1033769087
    199 https://doi.org/10.1023/a:1004724316051
    200 rdf:type schema:CreativeWork
    201 sg:pub.10.1051/agro:19880102 schema:sameAs https://app.dimensions.ai/details/publication/pub.1018508636
    202 https://doi.org/10.1051/agro:19880102
    203 rdf:type schema:CreativeWork
    204 sg:pub.10.1346/00098600260358067 schema:sameAs https://app.dimensions.ai/details/publication/pub.1065017344
    205 https://doi.org/10.1346/00098600260358067
    206 rdf:type schema:CreativeWork
    207 sg:pub.10.1346/ccmn.1976.0240201 schema:sameAs https://app.dimensions.ai/details/publication/pub.1065018564
    208 https://doi.org/10.1346/ccmn.1976.0240201
    209 rdf:type schema:CreativeWork
    210 sg:pub.10.1346/ccmn.1984.0320103 schema:sameAs https://app.dimensions.ai/details/publication/pub.1065019137
    211 https://doi.org/10.1346/ccmn.1984.0320103
    212 rdf:type schema:CreativeWork
    213 sg:pub.10.1346/ccmn.1986.0340113 schema:sameAs https://app.dimensions.ai/details/publication/pub.1065019312
    214 https://doi.org/10.1346/ccmn.1986.0340113
    215 rdf:type schema:CreativeWork
    216 sg:pub.10.1346/ccmn.1991.0390211 schema:sameAs https://app.dimensions.ai/details/publication/pub.1065019763
    217 https://doi.org/10.1346/ccmn.1991.0390211
    218 rdf:type schema:CreativeWork
    219 sg:pub.10.1346/ccmn.1992.0400410 schema:sameAs https://app.dimensions.ai/details/publication/pub.1065019884
    220 https://doi.org/10.1346/ccmn.1992.0400410
    221 rdf:type schema:CreativeWork
    222 sg:pub.10.1346/ccmn.1999.0470402 schema:sameAs https://app.dimensions.ai/details/publication/pub.1065020507
    223 https://doi.org/10.1346/ccmn.1999.0470402
    224 rdf:type schema:CreativeWork
    225 sg:pub.10.1346/ccmn.2001.0490506 schema:sameAs https://app.dimensions.ai/details/publication/pub.1065020684
    226 https://doi.org/10.1346/ccmn.2001.0490506
    227 rdf:type schema:CreativeWork
    228 sg:pub.10.1346/ccmn.2007.0550601 schema:sameAs https://app.dimensions.ai/details/publication/pub.1046134148
    229 https://doi.org/10.1346/ccmn.2007.0550601
    230 rdf:type schema:CreativeWork
    231 sg:pub.10.1346/ccmn.2007.0550608 schema:sameAs https://app.dimensions.ai/details/publication/pub.1021425627
    232 https://doi.org/10.1346/ccmn.2007.0550608
    233 rdf:type schema:CreativeWork
    234 sg:pub.10.1346/ccmn.2010.0580101 schema:sameAs https://app.dimensions.ai/details/publication/pub.1016732130
    235 https://doi.org/10.1346/ccmn.2010.0580101
    236 rdf:type schema:CreativeWork
    237 sg:pub.10.1346/ccmn.2012.0600305 schema:sameAs https://app.dimensions.ai/details/publication/pub.1034327334
    238 https://doi.org/10.1346/ccmn.2012.0600305
    239 rdf:type schema:CreativeWork
    240 https://doi.org/10.1016/0095-8522(66)90006-7 schema:sameAs https://app.dimensions.ai/details/publication/pub.1035819615
    241 rdf:type schema:CreativeWork
    242 https://doi.org/10.1016/0169-1317(94)90006-x schema:sameAs https://app.dimensions.ai/details/publication/pub.1021433708
    243 rdf:type schema:CreativeWork
    244 https://doi.org/10.1016/0899-5362(94)90025-6 schema:sameAs https://app.dimensions.ai/details/publication/pub.1042880810
    245 rdf:type schema:CreativeWork
    246 https://doi.org/10.1016/b978-0-08-009235-5.50026-7 schema:sameAs https://app.dimensions.ai/details/publication/pub.1022852138
    247 rdf:type schema:CreativeWork
    248 https://doi.org/10.1016/j.apcatb.2012.01.008 schema:sameAs https://app.dimensions.ai/details/publication/pub.1036908863
    249 rdf:type schema:CreativeWork
    250 https://doi.org/10.1016/j.clay.2005.10.005 schema:sameAs https://app.dimensions.ai/details/publication/pub.1045833207
    251 rdf:type schema:CreativeWork
    252 https://doi.org/10.1016/j.clay.2007.05.001 schema:sameAs https://app.dimensions.ai/details/publication/pub.1011868419
    253 rdf:type schema:CreativeWork
    254 https://doi.org/10.1016/j.clay.2011.01.027 schema:sameAs https://app.dimensions.ai/details/publication/pub.1010274986
    255 rdf:type schema:CreativeWork
    256 https://doi.org/10.1016/j.clay.2011.03.009 schema:sameAs https://app.dimensions.ai/details/publication/pub.1039289030
    257 rdf:type schema:CreativeWork
    258 https://doi.org/10.1016/j.clay.2011.09.012 schema:sameAs https://app.dimensions.ai/details/publication/pub.1033583827
    259 rdf:type schema:CreativeWork
    260 https://doi.org/10.1016/j.clay.2012.04.005 schema:sameAs https://app.dimensions.ai/details/publication/pub.1008114328
    261 rdf:type schema:CreativeWork
    262 https://doi.org/10.1016/j.clay.2012.04.017 schema:sameAs https://app.dimensions.ai/details/publication/pub.1045955220
    263 rdf:type schema:CreativeWork
    264 https://doi.org/10.1016/j.clay.2012.04.025 schema:sameAs https://app.dimensions.ai/details/publication/pub.1000500551
    265 rdf:type schema:CreativeWork
    266 https://doi.org/10.1016/j.jafrearsci.2004.07.033 schema:sameAs https://app.dimensions.ai/details/publication/pub.1025280560
    267 rdf:type schema:CreativeWork
    268 https://doi.org/10.1016/j.jinorgbio.2007.07.009 schema:sameAs https://app.dimensions.ai/details/publication/pub.1000330154
    269 rdf:type schema:CreativeWork
    270 https://doi.org/10.1016/j.msea.2006.06.001 schema:sameAs https://app.dimensions.ai/details/publication/pub.1027565040
    271 rdf:type schema:CreativeWork
    272 https://doi.org/10.1016/j.nimb.2007.04.218 schema:sameAs https://app.dimensions.ai/details/publication/pub.1049827137
    273 rdf:type schema:CreativeWork
    274 https://doi.org/10.1016/s0022-3697(97)00166-2 schema:sameAs https://app.dimensions.ai/details/publication/pub.1028771449
    275 rdf:type schema:CreativeWork
    276 https://doi.org/10.1016/s0040-6031(02)00228-9 schema:sameAs https://app.dimensions.ai/details/publication/pub.1019613058
    277 rdf:type schema:CreativeWork
    278 https://doi.org/10.1016/s0169-1317(00)00016-8 schema:sameAs https://app.dimensions.ai/details/publication/pub.1047755427
    279 rdf:type schema:CreativeWork
    280 https://doi.org/10.1021/ja00535a008 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055740136
    281 rdf:type schema:CreativeWork
    282 https://doi.org/10.1021/ja01145a126 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055773283
    283 rdf:type schema:CreativeWork
    284 https://doi.org/10.1021/ja01269a023 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055787826
    285 rdf:type schema:CreativeWork
    286 https://doi.org/10.1039/b003197f schema:sameAs https://app.dimensions.ai/details/publication/pub.1050785653
    287 rdf:type schema:CreativeWork
    288 https://doi.org/10.1080/00387018908053926 schema:sameAs https://app.dimensions.ai/details/publication/pub.1017261739
    289 rdf:type schema:CreativeWork
    290 https://doi.org/10.1111/j.1151-2916.1986.tb07433.x schema:sameAs https://app.dimensions.ai/details/publication/pub.1024813195
    291 rdf:type schema:CreativeWork
    292 https://doi.org/10.1126/science.154.3749.645 schema:sameAs https://app.dimensions.ai/details/publication/pub.1062489861
    293 rdf:type schema:CreativeWork
    294 https://doi.org/10.1126/science.273.5272.223 schema:sameAs https://app.dimensions.ai/details/publication/pub.1062553590
    295 rdf:type schema:CreativeWork
    296 https://doi.org/10.1127/0935-1221/2004/0016-0521 schema:sameAs https://app.dimensions.ai/details/publication/pub.1062698252
    297 rdf:type schema:CreativeWork
    298 https://doi.org/10.1180/000985599545966 schema:sameAs https://app.dimensions.ai/details/publication/pub.1064111724
    299 rdf:type schema:CreativeWork
    300 https://doi.org/10.1180/claymin.1978.013.4.02 schema:sameAs https://app.dimensions.ai/details/publication/pub.1064112741
    301 rdf:type schema:CreativeWork
    302 https://doi.org/10.1180/claymin.1996.031.4.01 schema:sameAs https://app.dimensions.ai/details/publication/pub.1064113743
    303 rdf:type schema:CreativeWork
    304 https://doi.org/10.1180/claymin.2008.043.3.05 schema:sameAs https://app.dimensions.ai/details/publication/pub.1045412550
    305 rdf:type schema:CreativeWork
    306 https://doi.org/10.1180/claymin.2011.046.3.371 schema:sameAs https://app.dimensions.ai/details/publication/pub.1050431801
    307 rdf:type schema:CreativeWork
    308 https://doi.org/10.1180/mono-5.1 schema:sameAs https://app.dimensions.ai/details/publication/pub.1090269599
    309 rdf:type schema:CreativeWork
    310 https://doi.org/10.1346/00098600260358067 schema:sameAs https://app.dimensions.ai/details/publication/pub.1065017344
    311 rdf:type schema:CreativeWork
    312 https://doi.org/10.1346/ccmn.1976.0240201 schema:sameAs https://app.dimensions.ai/details/publication/pub.1065018564
    313 rdf:type schema:CreativeWork
    314 https://doi.org/10.1346/ccmn.1984.0320103 schema:sameAs https://app.dimensions.ai/details/publication/pub.1065019137
    315 rdf:type schema:CreativeWork
    316 https://doi.org/10.1346/ccmn.1986.0340113 schema:sameAs https://app.dimensions.ai/details/publication/pub.1065019312
    317 rdf:type schema:CreativeWork
    318 https://doi.org/10.1346/ccmn.1991.0390211 schema:sameAs https://app.dimensions.ai/details/publication/pub.1065019763
    319 rdf:type schema:CreativeWork
    320 https://doi.org/10.1346/ccmn.1992.0400410 schema:sameAs https://app.dimensions.ai/details/publication/pub.1065019884
    321 rdf:type schema:CreativeWork
    322 https://doi.org/10.1346/ccmn.1999.0470402 schema:sameAs https://app.dimensions.ai/details/publication/pub.1065020507
    323 rdf:type schema:CreativeWork
    324 https://doi.org/10.1346/ccmn.2001.0490506 schema:sameAs https://app.dimensions.ai/details/publication/pub.1065020684
    325 rdf:type schema:CreativeWork
    326 https://doi.org/10.1346/ccmn.2007.0550601 schema:sameAs https://app.dimensions.ai/details/publication/pub.1046134148
    327 rdf:type schema:CreativeWork
    328 https://doi.org/10.1346/ccmn.2007.0550608 schema:sameAs https://app.dimensions.ai/details/publication/pub.1021425627
    329 rdf:type schema:CreativeWork
    330 https://doi.org/10.1346/ccmn.2010.0580101 schema:sameAs https://app.dimensions.ai/details/publication/pub.1016732130
    331 rdf:type schema:CreativeWork
    332 https://doi.org/10.1346/ccmn.2012.0600305 schema:sameAs https://app.dimensions.ai/details/publication/pub.1034327334
    333 rdf:type schema:CreativeWork
    334 https://doi.org/10.1351/pac198557040603 schema:sameAs https://app.dimensions.ai/details/publication/pub.1006669173
    335 rdf:type schema:CreativeWork
    336 https://doi.org/10.2138/am.2006.2023 schema:sameAs https://app.dimensions.ai/details/publication/pub.1024616623
    337 rdf:type schema:CreativeWork
    338 https://doi.org/10.3406/argil.1960.974 schema:sameAs https://app.dimensions.ai/details/publication/pub.1100417897
    339 rdf:type schema:CreativeWork
    340 https://doi.org/10.4028/www.scientific.net/msf.166-169.647 schema:sameAs https://app.dimensions.ai/details/publication/pub.1072103277
    341 rdf:type schema:CreativeWork
    342 https://www.grid.ac/institutes/grid.411840.8 schema:alternateName Cadi Ayyad University
    343 schema:name Laboratoire de Géosciences et Géoenvironnement, Faculté des Sciences et Techniques Guéliz, Université Cadi Ayyad, BP 549, Marrakech, Morocco
    344 Laboratoire de Matière Condensée et Nanostructures (LMCN), Faculté des Sciences et Techniques Guéliz, Université Cadi Ayyad, BP 549, Marrakech, Morocco
    345 rdf:type schema:Organization
    346 https://www.grid.ac/institutes/grid.4444.0 schema:alternateName French National Centre for Scientific Research
    347 schema:name Institut de Sciences des Matériaux de Mulhouse IS2 M LRC 7228, CNRS, 15 rue jean Starcky BP 2488, 68057, Mulhouse Cedex, France
    348 rdf:type schema:Organization
    349 https://www.grid.ac/institutes/grid.464172.2 schema:alternateName Inter university Material Research and Engineering Centre
    350 schema:name CIRIMAT, CNRS-UPS-INP, ENSIACET, 4 allée Emile Monso, BP 44362, 31030, Toulouse Cedex 4, France
    351 rdf:type schema:Organization
     




    Preview window. Press ESC to close (or click here)


    ...