Kinetics of the graphite–diamond transformation in aqueous fluid determined by in-situ X-ray diffractions at high pressures and temperatures View Full Text


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Article Info

DATE

2004-05

AUTHORS

T. Okada, W. Utsumi, H. Kaneko, V. Turkevich, N. Hamaya, O. Shimomura

ABSTRACT

The graphite-diamond transformation was investigated by in situ time-resolved X-ray diffraction experiments using aqueous fluid containing dissolved MgO as the diamond-forming catalyst under conditions of 6.6–8.9 GPa and 1400–1835 °C. The transformed volume fractions of diamond as a function of time under various pressure-temperature conditions were obtained and analyzed using the JMAK rate equation. Variations in the nucleation and growth processes during diamond formation as a function of pressure and temperature were clarified. More... »

PAGES

261-268

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s00269-004-0386-y

DOI

http://dx.doi.org/10.1007/s00269-004-0386-y

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1043152749


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