Sorption and thermodynamic properties of buried juvenile Pinus sylvestris L. wood aged 1,170 ± 40 BP View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2009-11

AUTHORS

Luis García Esteban, Paloma de Palacios, Francisco García Fernández, Juan Antonio Martín, Mar Génova, Juan Ignacio Fernández-Golfín

ABSTRACT

The hygroscopicity and thermodynamic properties of buried juvenile Pinus sylvestris L. wood with an age of 1,170 ± 40 BP were compared with the corresponding values of juvenile wood of the same species from recently cut trees. The 35 and 50°C isotherms were plotted following the saturated salts method and subsequently fitted in accordance with the GAB model. The isotherms were then compared by means of the hysteresis coefficients. X-ray diffractograms were used to analyse the crystal structure of the cellulose. The effect of time on the buried wood caused hemicelluloses degradation and a decrease in the crystallinity index and the crystallite length, resulting in an increase in the proportion of amorphous zones. Because of this, the equilibrium moisture contents of the buried wood are higher than of the recent wood, both in adsorption and desorption. In terms of the thermodynamic properties, the heat involved is greater in the buried wood than in the recent wood. More... »

PAGES

679-690

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s00226-009-0261-6

DOI

http://dx.doi.org/10.1007/s00226-009-0261-6

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1022111759


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