Phase relations in the system V/Nb/O. V. Investigation of mixed crystals V1-xNbxO2 View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1999-01

AUTHORS

H. Oppermann, F. von Woedtke, T. Reich, M. A. Denecke, H. Nitsche, M. Doerr

ABSTRACT

Mixed crystals V1-xNbxO2 exist over the whole area of the quasibinary line VO2-NbO2. The existence of Nb5+ beside V3+ and V4+ on the V-rich side and V3+ beside Nb5+ and Nb4+ on the Nb-rich side of the mixed crystals is demonstrated by XANES-measurements. The compound VNbO4(V0.5Nb0.5O2) is described as a double oxide with vanadium only as V3+ and niobium only as Nb5+. At this point the electric resistivity of the solid solution shows a maximum. More... »

PAGES

202-205

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s002160051172

DOI

http://dx.doi.org/10.1007/s002160051172

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1022307748


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