15N CP/MAS NMR as an instrument in structure investigations of organosilicon polymers View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1999-01

AUTHORS

E. Brendler, E. Ebrecht, B. Thomas, G. Boden, T. Breuning

ABSTRACT

15N solid state NMR without enrichment is rarely used because of the low sensitivity and low natural abundance of this nucleus. As demonstrated on different nitrogen-containing polysilanes and polysilazanes, it can be shown that with the CP/MAS technique spectra can be obtained in good quality and within acceptable measuring time. Three main different nitrogen sites – NSi3, NSi2H and NSiH2– can be observed as well as changes in the intensities of these sites with reaction and tempering conditions. Thus the spectra give valuable additional information for a better understanding of the structures and their changes within the investigated systems. More... »

PAGES

185-188

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s002160051168

DOI

http://dx.doi.org/10.1007/s002160051168

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1003269240


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