A host-guest optical sensor for aliphatic amines based on lipophilic cyclodextrin View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2000-06

AUTHORS

RH. Yang, KM. Wang, D. Xiao, XH. Yang

ABSTRACT

A host-guest optical sensor for the determination of aliphatic amines as exemplified by octylamine is proposed. It is based on the reversible fluorescence enhancement of heptakis(2,6-di-O-isobutyl)-β-cyclodextrin(DOB-β-CD) hosting tetraphenylporphyrin (TPP) immobilized in poly(vinyl chloride) (PVC) membrane by aliphatic amine extracted from aqueous phase into membrane phase. The optimum membrane contained 1.15 wt % TPP, 6.15 wt % DOB-β-CD as sensing reagent and other membrane materials. The fluorescence enhancement of the membrane resulted from the formation of a stable three-component complex among DOB-β-CD, TPP, and aliphatic amines. With the optimum conditions described, the fluorescence response of the sensor to octylamine shows a good correlation with the theoretically derived equation in the range 1.0 × 10–6 to 8.0 × 10–4 mol/L. The response characteristics including reversibility, response time, reproducibility and lifetime and selectivity of this optical device are also discussed in detail. This sensor has also been applied for the determination of octylamine in water samples containing interferents with satisfactory recovery. More... »

PAGES

429-435

Journal

TITLE

Journal of Analytical Chemistry

ISSUE

5

VOLUME

367

Author Affiliations

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s002160000353

DOI

http://dx.doi.org/10.1007/s002160000353

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1031307113


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