Probing some organic ukiyo-e Japanese pigments and mixtures using non-invasive and mobile infrared spectroscopies View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2018-11

AUTHORS

Carole Biron, Gwénaëlle Le Bourdon, Josefina Pérez-Arantegui, Laurent Servant, Rémy Chapoulie, Floréal Daniel

ABSTRACT

Non-invasive identification of organic colourants in paintings still remains a challenging issue, especially in the case of extremely thin layers of paint on printed paper such as Japanese ukiyo-e prints. Because prints are fragile artworks, various non-invasive analytical methods need to be employed. The present work focuses on results obtained by combining fibre optic reflectance spectroscopy in the near-infrared range (FORS NIR) with mid-infrared (MIR) spectroscopy. The first step consists of identifying spectroscopic marker bands typical of some organic pigments (indigo, gamboge, cochineal, turmeric, safflower, dragon's blood). Some reference printouts involving paper substrate, binder and pigments (seldom used or as mixtures) were then investigated in order to establish a straightforward way to extract the marker bands of the pigments. Some data post-treatments were applied to the spectra, such as spectral subtraction, in order to abstract the signal from overlapping bands originating from both substrate and binder, and second derivative calculation to emphasise the pigment marker bands' frequency positions. These data treatments turned out to be relevant to extract information on the organic pigments of interest, even within complex mixtures. More... »

PAGES

7043-7054

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s00216-018-1305-2

DOI

http://dx.doi.org/10.1007/s00216-018-1305-2

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1106083836

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/30094789


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