JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0301", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Analytical Chemistry", 
        "type": "DefinedTerm"
      }, 
      {
        "inDefinedTermSet": "https://www.nlm.nih.gov/mesh/", 
        "name": "Bromides", 
        "type": "DefinedTerm"
      }, 
      {
        "inDefinedTermSet": "https://www.nlm.nih.gov/mesh/", 
        "name": "Fresh Water", 
        "type": "DefinedTerm"
      }, 
      {
        "inDefinedTermSet": "https://www.nlm.nih.gov/mesh/", 
        "name": "Geologic Sediments", 
        "type": "DefinedTerm"
      }, 
      {
        "inDefinedTermSet": "https://www.nlm.nih.gov/mesh/", 
        "name": "Hydrochloric Acid", 
        "type": "DefinedTerm"
      }, 
      {
        "inDefinedTermSet": "https://www.nlm.nih.gov/mesh/", 
        "name": "Mercury Radioisotopes", 
        "type": "DefinedTerm"
      }, 
      {
        "inDefinedTermSet": "https://www.nlm.nih.gov/mesh/", 
        "name": "Methylmercury Compounds", 
        "type": "DefinedTerm"
      }, 
      {
        "inDefinedTermSet": "https://www.nlm.nih.gov/mesh/", 
        "name": "Oxidation-Reduction", 
        "type": "DefinedTerm"
      }, 
      {
        "inDefinedTermSet": "https://www.nlm.nih.gov/mesh/", 
        "name": "Potassium Compounds", 
        "type": "DefinedTerm"
      }, 
      {
        "inDefinedTermSet": "https://www.nlm.nih.gov/mesh/", 
        "name": "Reproducibility of Results", 
        "type": "DefinedTerm"
      }, 
      {
        "inDefinedTermSet": "https://www.nlm.nih.gov/mesh/", 
        "name": "Sensitivity and Specificity", 
        "type": "DefinedTerm"
      }, 
      {
        "inDefinedTermSet": "https://www.nlm.nih.gov/mesh/", 
        "name": "Sulfonic Acids", 
        "type": "DefinedTerm"
      }, 
      {
        "inDefinedTermSet": "https://www.nlm.nih.gov/mesh/", 
        "name": "Water Pollutants, Chemical", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Laboratorio de An\u00e1lisis por Activaci\u00f3n Neutr\u00f3nica, Centro At\u00f3mico Bariloche, Av. Bustillo Km 9.5, 8400, Bariloche, Argentina", 
          "id": "http://www.grid.ac/institutes/grid.418211.f", 
          "name": [
            "Laboratorio de An\u00e1lisis por Activaci\u00f3n Neutr\u00f3nica, Centro At\u00f3mico Bariloche, Av. Bustillo Km 9.5, 8400, Bariloche, Argentina"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Ribeiro Guevara", 
        "givenName": "Sergio", 
        "id": "sg:person.01345756563.92", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01345756563.92"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Department of Environmental Sciences, Jo\u017eef Stefan Institute, Jamova 39, 1000, Ljubljana, Slovenia", 
          "id": "http://www.grid.ac/institutes/grid.11375.31", 
          "name": [
            "Department of Environmental Sciences, Jo\u017eef Stefan Institute, Jamova 39, 1000, Ljubljana, Slovenia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "\u017di\u017eek", 
        "givenName": "Suzana", 
        "id": "sg:person.0764220601.21", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0764220601.21"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Department of Environmental Sciences, Jo\u017eef Stefan Institute, Jamova 39, 1000, Ljubljana, Slovenia", 
          "id": "http://www.grid.ac/institutes/grid.11375.31", 
          "name": [
            "Department of Environmental Sciences, Jo\u017eef Stefan Institute, Jamova 39, 1000, Ljubljana, Slovenia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Repinc", 
        "givenName": "Ur\u0161ka", 
        "id": "sg:person.01262035114.28", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01262035114.28"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Laboratorio de An\u00e1lisis por Activaci\u00f3n Neutr\u00f3nica, Centro At\u00f3mico Bariloche, Av. Bustillo Km 9.5, 8400, Bariloche, Argentina", 
          "id": "http://www.grid.ac/institutes/grid.418211.f", 
          "name": [
            "Laboratorio de An\u00e1lisis por Activaci\u00f3n Neutr\u00f3nica, Centro At\u00f3mico Bariloche, Av. Bustillo Km 9.5, 8400, Bariloche, Argentina"
          ], 
          "type": "Organization"
        }, 
        "familyName": "P\u00e9rez Cat\u00e1n", 
        "givenName": "Soledad", 
        "id": "sg:person.07657625777.93", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07657625777.93"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Department of Environmental Sciences, Jo\u017eef Stefan Institute, Jamova 39, 1000, Ljubljana, Slovenia", 
          "id": "http://www.grid.ac/institutes/grid.11375.31", 
          "name": [
            "Department of Environmental Sciences, Jo\u017eef Stefan Institute, Jamova 39, 1000, Ljubljana, Slovenia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Ja\u0107imovi\u0107", 
        "givenName": "Radojko", 
        "id": "sg:person.015030044321.46", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015030044321.46"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Department of Environmental Sciences, Jo\u017eef Stefan Institute, Jamova 39, 1000, Ljubljana, Slovenia", 
          "id": "http://www.grid.ac/institutes/grid.11375.31", 
          "name": [
            "Department of Environmental Sciences, Jo\u017eef Stefan Institute, Jamova 39, 1000, Ljubljana, Slovenia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Horvat", 
        "givenName": "Milena", 
        "id": "sg:person.01067035034.55", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01067035034.55"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1007/s00254-002-0623-y", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1086167620", 
          "https://doi.org/10.1007/s00254-002-0623-y"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s00216-002-1534-1", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1005382794", 
          "https://doi.org/10.1007/s00216-002-1534-1"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf01189726", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1004540140", 
          "https://doi.org/10.1007/bf01189726"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf01189724", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1041289392", 
          "https://doi.org/10.1007/bf01189724"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/978-94-009-1780-4_11", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1006217828", 
          "https://doi.org/10.1007/978-94-009-1780-4_11"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/978-94-009-1780-4", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1036336793", 
          "https://doi.org/10.1007/978-94-009-1780-4"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/978-94-009-1780-4_15", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1028476489", 
          "https://doi.org/10.1007/978-94-009-1780-4_15"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/978-94-009-1780-4_14", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1003584884", 
          "https://doi.org/10.1007/978-94-009-1780-4_14"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2007-01-05", 
    "datePublishedReg": "2007-01-05", 
    "description": "Mercury tracers are powerful tools that can be used to study mercury transformations in environmental systems, particularly mercury methylation, demethylation and reduction in sediments and water. However, mercury transformation studies using tracers can be subject to error, especially when used to assess methylation potential. The organic mercury extracted can be as low as 0.01% of the endogenous labeled mercury, and artefacts and contamination present during methylmercury (MeHg) extraction processes can cause interference. Solvent extraction methods based on the use of either KBr/H2SO4 or HCl were evaluated in freshwater sediments using 197Hg radiotracer. Values obtained for the 197Hg tracer in the organic phase were up to 25-fold higher when HCl was used, which is due to the coextraction of 197Hg2+ into the organic phase during MeHg extraction. Evaluations of the production of MeHg gave similar results with both MeHg extraction procedures, but due to the higher Hg2+ contamination of the controls, the uncertainty in the determination was higher when HCl was used. The Hg2+ contamination of controls in the HCl extraction method showed a nonlinear correlation with the humic acid content of sediment pore water. Therefore, use of the KBr/H2SO4 method is recommended, since it is free from these interferences. 197Hg radiotracer (T1/2\u2009=\u20092.673\u00a0d) has a production rate that is about 50 times higher than that of 203Hg (T1/2\u2009=\u200946.595\u00a0d), the most frequently used mercury radiotracer. Hence it is possible to obtain a similar level of performance to 203Hg when it is used it in short-term experiments and produced by the irradiation of 196Hg with thermal neutrons, using mercury targets with the natural isotopic composition. However, if the 0.15% natural abundance of the 196Hg isotope is increased, the specific activity of the 197Hg tracer can be significantly improved. In the present work, 197Hg tracer was produced from mercury 51.58% enriched in the 196Hg isotope, and a 340-fold increase in specific activity with respect to natural mercury targets was obtained. When this high specific activity tracer is employed, mercury methylation and reduction experiments with minimum mercury additions are feasible. Tracer recovery in methylation experiments (associated with Me197Hg production from 197Hg2+ spike, but also with Hg2+ contamination and Me197Hg artefacts) with marine sediments was about 0.005% g\u22121 WS (WS: wet sediment) after 20\u00a0h incubation with mercury additions of 0.05\u00a0ng\u00a0g\u22121 WS, which is far below natural mercury levels. In this case, the amount of Hg2+ reduced to Hg0 (expressed as the percent 197Hg0 recovered with respect to the 197Hg2+ added) varied from 0.13 to 1.6% g\u22121 WS. Me197Hg production from 197Hg2+ spike after 20\u00a0h of incubation of freshwater sediment ranged from 0.02 to 0.13% g\u22121 WS with mercury additions of 2.5\u00a0ng g\u22121 WS, which is also far below natural levels. 197Hg0 recoveries were low, 0.0058\u2009\u00b1\u20090.0013% g\u22121 WS, but showed good reproducibility in five replicates. Me197Hg production from 197Hg2+ spiked in freshwater samples ranged from 0.1 to 0.3% over a period of three days with mercury additions of 10\u00a0ng L\u22121. A detection limit of 0.05% for Me197Hg production from 197Hg2+ spike was obtained in seawater in a 25\u00a0h incubation experiment with mercury additions of 12\u00a0ng L\u22121.", 
    "genre": "article", 
    "id": "sg:pub.10.1007/s00216-006-1040-y", 
    "inLanguage": "en", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1358693", 
        "issn": [
          "1618-2642", 
          "1618-2650"
        ], 
        "name": "Analytical and Bioanalytical Chemistry", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "6", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "387"
      }
    ], 
    "keywords": [
      "freshwater sediments", 
      "mercury methylation", 
      "mercury target", 
      "sediment pore water", 
      "production of MeHg", 
      "natural mercury levels", 
      "organic phase", 
      "HCl extraction method", 
      "isotopic composition", 
      "marine sediments", 
      "pore water", 
      "natural isotopic composition", 
      "freshwater samples", 
      "high specific activity tracer", 
      "sediments", 
      "solvent extraction method", 
      "mercury addition", 
      "extraction method", 
      "tracer recovery", 
      "mercury transformation", 
      "methylation potential", 
      "extraction process", 
      "tracer", 
      "natural levels", 
      "incubation experiment", 
      "reduction experiments", 
      "humic acid content", 
      "isotopes", 
      "environmental systems", 
      "MeHg extraction", 
      "high Hg2", 
      "water", 
      "present work", 
      "thermal neutrons", 
      "production rate", 
      "contamination", 
      "H2SO4 method", 
      "mercury levels", 
      "natural abundance", 
      "novel methodology", 
      "mercury", 
      "amount of Hg2", 
      "good reproducibility", 
      "seawater", 
      "extraction procedure", 
      "detection limit", 
      "MeHg", 
      "experiments", 
      "Hg0", 
      "phase", 
      "short-term experiments", 
      "HCl", 
      "organic mercury", 
      "method", 
      "nonlinear correlation", 
      "abundance", 
      "coextraction", 
      "H2SO4", 
      "WS", 
      "composition", 
      "performance", 
      "uncertainty", 
      "interference", 
      "activity tracers", 
      "reduction", 
      "powerful tool", 
      "addition", 
      "error", 
      "extraction", 
      "recovery", 
      "production", 
      "Hg2", 
      "methylation experiments", 
      "period", 
      "control", 
      "process", 
      "irradiation", 
      "methodology", 
      "transformation studies", 
      "system", 
      "work", 
      "specific activity", 
      "limit", 
      "use", 
      "content", 
      "correlation", 
      "amount", 
      "neutrons", 
      "reproducibility", 
      "results", 
      "samples", 
      "artifacts", 
      "values", 
      "respect", 
      "determination", 
      "transformation", 
      "potential", 
      "time", 
      "increase", 
      "rate", 
      "activity", 
      "levels", 
      "tool", 
      "study", 
      "procedure", 
      "similar results", 
      "radiotracer", 
      "evaluation", 
      "spikes", 
      "target", 
      "cases", 
      "days", 
      "acid content", 
      "similar levels", 
      "demethylation", 
      "methylation", 
      "incubation", 
      "replicates"
    ], 
    "name": "Novel methodology for the study of mercury methylation and reduction in sediments and water using 197Hg radiotracer", 
    "pagination": "2185-2197", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1045810402"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s00216-006-1040-y"
        ]
      }, 
      {
        "name": "pubmed_id", 
        "type": "PropertyValue", 
        "value": [
          "17205268"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s00216-006-1040-y", 
      "https://app.dimensions.ai/details/publication/pub.1045810402"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-05-20T07:24", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20220519/entities/gbq_results/article/article_442.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1007/s00216-006-1040-y"
  }
]

Download the RDF metadata as:  json-ld nt turtle xml License info

This table displays all metadata directly associated to this object as RDF triples.

298 TRIPLES      22 PREDICATES      164 URIs      148 LITERALS      19 BLANK NODES