Complexation of uranium(VI) with protocatechuic acid—application of iterative transformation factor analysis to EXAFS spectroscopy View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2003-07

AUTHORS

A. Roßberg, T. Reich, G. Bernhard

ABSTRACT

The speciation of 1 mM uranium(VI) in carbonate-free aqueous solutions of 50 mM protocatechuic acid (PCA, 3,4-dihydroxybenzoic acid) was studied in the pH range of 4.0 to 6.8 using EXAFS spectroscopy. The uranium L(III)-edge EXAFS spectra were analyzed using a newly developed computer algorithm for iterative transformation factor analysis (FA). Two structural different uranium(VI) complexes were observed. The speciation in the pH range of 4.0 to 4.8 is dominated by a 1:2 or 1:3 uranium(VI)/PCA complex with bidentate coordination of the carboxyl group to the uranium(VI) moiety. Already at pH 4.6 significant amounts of a second species are formed. This uranium(VI) species contains two PCA ligands that are bound to the uranium via their neighboring phenolic hydroxyl groups under formation of five-member rings. More... »

PAGES

631-638

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s00216-003-1963-5

DOI

http://dx.doi.org/10.1007/s00216-003-1963-5

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1015060755

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/12811445


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0302", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Inorganic Chemistry", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Helmholtz-Zentrum Dresden-Rossendorf", 
          "id": "https://www.grid.ac/institutes/grid.40602.30", 
          "name": [
            "Forschungszentrum Rossendorf e.V., Institute of Radiochemistry, P.O. Box 510119, 01314, Dresden, Germany"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Ro\u00dfberg", 
        "givenName": "A.", 
        "id": "sg:person.01001375600.20", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01001375600.20"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Johannes Gutenberg University of Mainz", 
          "id": "https://www.grid.ac/institutes/grid.5802.f", 
          "name": [
            "Johannes Gutenberg-Universit\u00e4t Mainz, Institute of Nuclear Chemistry, Fritz-Strassmann-Weg 2, 55128, Mainz, Germany"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Reich", 
        "givenName": "T.", 
        "id": "sg:person.01250327770.60", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01250327770.60"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Helmholtz-Zentrum Dresden-Rossendorf", 
          "id": "https://www.grid.ac/institutes/grid.40602.30", 
          "name": [
            "Forschungszentrum Rossendorf e.V., Institute of Radiochemistry, P.O. Box 510119, 01314, Dresden, Germany"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Bernhard", 
        "givenName": "G.", 
        "id": "sg:person.01251577150.29", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01251577150.29"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1107/s0108270185008095", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1000324513"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0169-7439(86)80026-0", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1003861947"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1107/s0909049599010663", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1004778971"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02289233", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1018991466", 
          "https://doi.org/10.1007/bf02289233"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02289233", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1018991466", 
          "https://doi.org/10.1007/bf02289233"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0040-6090(99)00392-2", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1039129922"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0167-2738(98)00271-9", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1041156965"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf01242483", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1049328390", 
          "https://doi.org/10.1007/bf01242483"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02274608", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1053738136", 
          "https://doi.org/10.1007/bf02274608"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02274608", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1053738136", 
          "https://doi.org/10.1007/bf02274608"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ac00162a013", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1054977115"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ac50012a027", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055006690"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic970502m", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055587717"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic970502m", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055587717"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/j100033a032", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055650151"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1051/jp4/1997125", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056976919"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevb.52.2995", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060578073"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevb.52.2995", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060578073"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevb.54.156", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060581815"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevb.54.156", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060581815"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1524/ract.2000.88.9-11.593", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1067647219"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.2138/am-1997-5-607", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1069055582"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2003-07", 
    "datePublishedReg": "2003-07-01", 
    "description": "The speciation of 1 mM uranium(VI) in carbonate-free aqueous solutions of 50 mM protocatechuic acid (PCA, 3,4-dihydroxybenzoic acid) was studied in the pH range of 4.0 to 6.8 using EXAFS spectroscopy. The uranium L(III)-edge EXAFS spectra were analyzed using a newly developed computer algorithm for iterative transformation factor analysis (FA). Two structural different uranium(VI) complexes were observed. The speciation in the pH range of 4.0 to 4.8 is dominated by a 1:2 or 1:3 uranium(VI)/PCA complex with bidentate coordination of the carboxyl group to the uranium(VI) moiety. Already at pH 4.6 significant amounts of a second species are formed. This uranium(VI) species contains two PCA ligands that are bound to the uranium via their neighboring phenolic hydroxyl groups under formation of five-member rings.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/s00216-003-1963-5", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1357342", 
        "issn": [
          "1618-2642", 
          "1618-2650"
        ], 
        "name": "Analytical and Bioanalytical Chemistry", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "5", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "376"
      }
    ], 
    "name": "Complexation of uranium(VI) with protocatechuic acid\u2014application of iterative transformation factor analysis to EXAFS spectroscopy", 
    "pagination": "631-638", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "47c104ed1ff204281157d90ed9c0c21d6586092a05817d07d708b72fd19e19c7"
        ]
      }, 
      {
        "name": "pubmed_id", 
        "type": "PropertyValue", 
        "value": [
          "12811445"
        ]
      }, 
      {
        "name": "nlm_unique_id", 
        "type": "PropertyValue", 
        "value": [
          "101134327"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s00216-003-1963-5"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1015060755"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s00216-003-1963-5", 
      "https://app.dimensions.ai/details/publication/pub.1015060755"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-11T00:15", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8695_00000511.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1007%2Fs00216-003-1963-5"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s00216-003-1963-5'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s00216-003-1963-5'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s00216-003-1963-5'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s00216-003-1963-5'


 

This table displays all metadata directly associated to this object as RDF triples.

140 TRIPLES      21 PREDICATES      46 URIs      21 LITERALS      9 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s00216-003-1963-5 schema:about anzsrc-for:03
2 anzsrc-for:0302
3 schema:author N258378c676454f40be9e1d44c110464b
4 schema:citation sg:pub.10.1007/bf01242483
5 sg:pub.10.1007/bf02274608
6 sg:pub.10.1007/bf02289233
7 https://doi.org/10.1016/0169-7439(86)80026-0
8 https://doi.org/10.1016/s0040-6090(99)00392-2
9 https://doi.org/10.1016/s0167-2738(98)00271-9
10 https://doi.org/10.1021/ac00162a013
11 https://doi.org/10.1021/ac50012a027
12 https://doi.org/10.1021/ic970502m
13 https://doi.org/10.1021/j100033a032
14 https://doi.org/10.1051/jp4/1997125
15 https://doi.org/10.1103/physrevb.52.2995
16 https://doi.org/10.1103/physrevb.54.156
17 https://doi.org/10.1107/s0108270185008095
18 https://doi.org/10.1107/s0909049599010663
19 https://doi.org/10.1524/ract.2000.88.9-11.593
20 https://doi.org/10.2138/am-1997-5-607
21 schema:datePublished 2003-07
22 schema:datePublishedReg 2003-07-01
23 schema:description The speciation of 1 mM uranium(VI) in carbonate-free aqueous solutions of 50 mM protocatechuic acid (PCA, 3,4-dihydroxybenzoic acid) was studied in the pH range of 4.0 to 6.8 using EXAFS spectroscopy. The uranium L(III)-edge EXAFS spectra were analyzed using a newly developed computer algorithm for iterative transformation factor analysis (FA). Two structural different uranium(VI) complexes were observed. The speciation in the pH range of 4.0 to 4.8 is dominated by a 1:2 or 1:3 uranium(VI)/PCA complex with bidentate coordination of the carboxyl group to the uranium(VI) moiety. Already at pH 4.6 significant amounts of a second species are formed. This uranium(VI) species contains two PCA ligands that are bound to the uranium via their neighboring phenolic hydroxyl groups under formation of five-member rings.
24 schema:genre research_article
25 schema:inLanguage en
26 schema:isAccessibleForFree false
27 schema:isPartOf N990a57c6e05d4b6fb77a193427c50b8b
28 Nfd6895110ffd4d72ab6ea84d61f7fed7
29 sg:journal.1357342
30 schema:name Complexation of uranium(VI) with protocatechuic acid—application of iterative transformation factor analysis to EXAFS spectroscopy
31 schema:pagination 631-638
32 schema:productId N273f74dc039442e2b50c69e432e0f345
33 N5607c9d4d03b4c41a6795b051b543dfc
34 N59b36293185546fc8d562ac30908d2da
35 N99a8ea9b29b2438cb417c06bd5ea26a5
36 Nc021d573826b4be987b8298cb8523f7c
37 schema:sameAs https://app.dimensions.ai/details/publication/pub.1015060755
38 https://doi.org/10.1007/s00216-003-1963-5
39 schema:sdDatePublished 2019-04-11T00:15
40 schema:sdLicense https://scigraph.springernature.com/explorer/license/
41 schema:sdPublisher N9417cdcc5a1248f283a64a9645facb28
42 schema:url http://link.springer.com/10.1007%2Fs00216-003-1963-5
43 sgo:license sg:explorer/license/
44 sgo:sdDataset articles
45 rdf:type schema:ScholarlyArticle
46 N0721cbff98ab41b4b0df411b7c2cd665 rdf:first sg:person.01250327770.60
47 rdf:rest N076dcfdfac67488881504576e8d70b51
48 N076dcfdfac67488881504576e8d70b51 rdf:first sg:person.01251577150.29
49 rdf:rest rdf:nil
50 N258378c676454f40be9e1d44c110464b rdf:first sg:person.01001375600.20
51 rdf:rest N0721cbff98ab41b4b0df411b7c2cd665
52 N273f74dc039442e2b50c69e432e0f345 schema:name pubmed_id
53 schema:value 12811445
54 rdf:type schema:PropertyValue
55 N5607c9d4d03b4c41a6795b051b543dfc schema:name dimensions_id
56 schema:value pub.1015060755
57 rdf:type schema:PropertyValue
58 N59b36293185546fc8d562ac30908d2da schema:name readcube_id
59 schema:value 47c104ed1ff204281157d90ed9c0c21d6586092a05817d07d708b72fd19e19c7
60 rdf:type schema:PropertyValue
61 N9417cdcc5a1248f283a64a9645facb28 schema:name Springer Nature - SN SciGraph project
62 rdf:type schema:Organization
63 N990a57c6e05d4b6fb77a193427c50b8b schema:volumeNumber 376
64 rdf:type schema:PublicationVolume
65 N99a8ea9b29b2438cb417c06bd5ea26a5 schema:name doi
66 schema:value 10.1007/s00216-003-1963-5
67 rdf:type schema:PropertyValue
68 Nc021d573826b4be987b8298cb8523f7c schema:name nlm_unique_id
69 schema:value 101134327
70 rdf:type schema:PropertyValue
71 Nfd6895110ffd4d72ab6ea84d61f7fed7 schema:issueNumber 5
72 rdf:type schema:PublicationIssue
73 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
74 schema:name Chemical Sciences
75 rdf:type schema:DefinedTerm
76 anzsrc-for:0302 schema:inDefinedTermSet anzsrc-for:
77 schema:name Inorganic Chemistry
78 rdf:type schema:DefinedTerm
79 sg:journal.1357342 schema:issn 1618-2642
80 1618-2650
81 schema:name Analytical and Bioanalytical Chemistry
82 rdf:type schema:Periodical
83 sg:person.01001375600.20 schema:affiliation https://www.grid.ac/institutes/grid.40602.30
84 schema:familyName Roßberg
85 schema:givenName A.
86 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01001375600.20
87 rdf:type schema:Person
88 sg:person.01250327770.60 schema:affiliation https://www.grid.ac/institutes/grid.5802.f
89 schema:familyName Reich
90 schema:givenName T.
91 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01250327770.60
92 rdf:type schema:Person
93 sg:person.01251577150.29 schema:affiliation https://www.grid.ac/institutes/grid.40602.30
94 schema:familyName Bernhard
95 schema:givenName G.
96 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01251577150.29
97 rdf:type schema:Person
98 sg:pub.10.1007/bf01242483 schema:sameAs https://app.dimensions.ai/details/publication/pub.1049328390
99 https://doi.org/10.1007/bf01242483
100 rdf:type schema:CreativeWork
101 sg:pub.10.1007/bf02274608 schema:sameAs https://app.dimensions.ai/details/publication/pub.1053738136
102 https://doi.org/10.1007/bf02274608
103 rdf:type schema:CreativeWork
104 sg:pub.10.1007/bf02289233 schema:sameAs https://app.dimensions.ai/details/publication/pub.1018991466
105 https://doi.org/10.1007/bf02289233
106 rdf:type schema:CreativeWork
107 https://doi.org/10.1016/0169-7439(86)80026-0 schema:sameAs https://app.dimensions.ai/details/publication/pub.1003861947
108 rdf:type schema:CreativeWork
109 https://doi.org/10.1016/s0040-6090(99)00392-2 schema:sameAs https://app.dimensions.ai/details/publication/pub.1039129922
110 rdf:type schema:CreativeWork
111 https://doi.org/10.1016/s0167-2738(98)00271-9 schema:sameAs https://app.dimensions.ai/details/publication/pub.1041156965
112 rdf:type schema:CreativeWork
113 https://doi.org/10.1021/ac00162a013 schema:sameAs https://app.dimensions.ai/details/publication/pub.1054977115
114 rdf:type schema:CreativeWork
115 https://doi.org/10.1021/ac50012a027 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055006690
116 rdf:type schema:CreativeWork
117 https://doi.org/10.1021/ic970502m schema:sameAs https://app.dimensions.ai/details/publication/pub.1055587717
118 rdf:type schema:CreativeWork
119 https://doi.org/10.1021/j100033a032 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055650151
120 rdf:type schema:CreativeWork
121 https://doi.org/10.1051/jp4/1997125 schema:sameAs https://app.dimensions.ai/details/publication/pub.1056976919
122 rdf:type schema:CreativeWork
123 https://doi.org/10.1103/physrevb.52.2995 schema:sameAs https://app.dimensions.ai/details/publication/pub.1060578073
124 rdf:type schema:CreativeWork
125 https://doi.org/10.1103/physrevb.54.156 schema:sameAs https://app.dimensions.ai/details/publication/pub.1060581815
126 rdf:type schema:CreativeWork
127 https://doi.org/10.1107/s0108270185008095 schema:sameAs https://app.dimensions.ai/details/publication/pub.1000324513
128 rdf:type schema:CreativeWork
129 https://doi.org/10.1107/s0909049599010663 schema:sameAs https://app.dimensions.ai/details/publication/pub.1004778971
130 rdf:type schema:CreativeWork
131 https://doi.org/10.1524/ract.2000.88.9-11.593 schema:sameAs https://app.dimensions.ai/details/publication/pub.1067647219
132 rdf:type schema:CreativeWork
133 https://doi.org/10.2138/am-1997-5-607 schema:sameAs https://app.dimensions.ai/details/publication/pub.1069055582
134 rdf:type schema:CreativeWork
135 https://www.grid.ac/institutes/grid.40602.30 schema:alternateName Helmholtz-Zentrum Dresden-Rossendorf
136 schema:name Forschungszentrum Rossendorf e.V., Institute of Radiochemistry, P.O. Box 510119, 01314, Dresden, Germany
137 rdf:type schema:Organization
138 https://www.grid.ac/institutes/grid.5802.f schema:alternateName Johannes Gutenberg University of Mainz
139 schema:name Johannes Gutenberg-Universität Mainz, Institute of Nuclear Chemistry, Fritz-Strassmann-Weg 2, 55128, Mainz, Germany
140 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...