Optical Properties of Noble Metal Clusters as a Function of the Size: Comparison between Experiments and a Semi-Quantal Theory View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2006-09

AUTHORS

E. Cottancin, G. Celep, J. Lermé, M. Pellarin, J. R. Huntzinger, J. L. Vialle, M. Broyer

ABSTRACT

The optical properties of noble metal clusters are measured and compared in the size range 1.4–7 nm in diameter. The clusters of copper, silver and gold are produced by the same experimental technique, the deposition of preformed clusters in a transparent matrix. The size dependence is found to be different for the three metals. As the size decreases, the surface plasmon resonance is only slightly blue-shifted for silver, more strongly blue-shifted and damped for gold while this peak resonance vanishes for copper. We show that these results cannot be interpreted by a simple classical theory. Since ab initio calculations are not possible in this size range, we obtain a complete theoretical description of these optical properties through the same semi-quantal model for the three metals. More... »

PAGES

514-523

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s00214-006-0089-1

DOI

http://dx.doi.org/10.1007/s00214-006-0089-1

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1034763596


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Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s00214-006-0089-1'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s00214-006-0089-1'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s00214-006-0089-1'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s00214-006-0089-1'


 

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