Surface acid sites of H3PW12O40 as studied by the adsorption of stable nitroxyl radicals View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2005-01

AUTHORS

M. N. Timofeeva, A. B. Ayupov, A. M. Volodin, Yu. R. Pak, G. G. Volkova, G. V. Echevskii

ABSTRACT

The surface acidity of H3PW12O40 and NaxH3-xPW12O40(x = 1-3) was studied using the adsorption of 2,2′,6,6′-tetramethyl-4-oxopiperidine-1-oxyl (TEMPON) and 2,2′,6,6′-tetramethyl-4-hydroxypiperidine-1-oxyl (TEMPOL) radicals. It was found that the amount of surface proton sites determined from the adsorption of TEMPON decreased with the degree of substitution of Na+ cations for protons. A correlation between amount of strong surface proton sites and catalytic activity of NaxH3-xPW12O40(x = 0-3) in the dealkylation reaction of 2,6-di-tert-butyl-4-methylphenol was found. More... »

PAGES

123-127

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/pl00021995

DOI

http://dx.doi.org/10.1007/pl00021995

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1085142819


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Boreskov Institute of Catalysis", 
          "id": "https://www.grid.ac/institutes/grid.418421.a", 
          "name": [
            "Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, 630090, Novosibirsk, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Timofeeva", 
        "givenName": "M. N.", 
        "id": "sg:person.016052471473.71", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016052471473.71"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Boreskov Institute of Catalysis", 
          "id": "https://www.grid.ac/institutes/grid.418421.a", 
          "name": [
            "Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, 630090, Novosibirsk, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Ayupov", 
        "givenName": "A. B.", 
        "id": "sg:person.013510657333.84", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013510657333.84"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Boreskov Institute of Catalysis", 
          "id": "https://www.grid.ac/institutes/grid.418421.a", 
          "name": [
            "Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, 630090, Novosibirsk, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Volodin", 
        "givenName": "A. M.", 
        "id": "sg:person.0727402755.46", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0727402755.46"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Novosibirsk State University", 
          "id": "https://www.grid.ac/institutes/grid.4605.7", 
          "name": [
            "Novosibirsk State University, 630090, Novosibirsk, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Pak", 
        "givenName": "Yu. R.", 
        "id": "sg:person.016456372203.41", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016456372203.41"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Boreskov Institute of Catalysis", 
          "id": "https://www.grid.ac/institutes/grid.418421.a", 
          "name": [
            "Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, 630090, Novosibirsk, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Volkova", 
        "givenName": "G. G.", 
        "id": "sg:person.012600646766.96", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012600646766.96"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Novosibirsk State University", 
          "id": "https://www.grid.ac/institutes/grid.4605.7", 
          "name": [
            "Novosibirsk State University, 630090, Novosibirsk, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Echevskii", 
        "givenName": "G. V.", 
        "id": "sg:person.07602127007.54", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07602127007.54"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1016/s0360-0564(08)60041-3", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1004880699"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0021-9517(86)90249-6", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1015800540"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0926-860x(99)00361-0", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1021833352"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0927-6513(95)00059-3", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1026929752"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0304-5102(90)85068-s", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1032441999"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02075437", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1034483864", 
          "https://doi.org/10.1007/bf02075437"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02075437", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1034483864", 
          "https://doi.org/10.1007/bf02075437"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0927-7757(96)03603-5", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1051457986"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja00800a041", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055748966"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jo01361a036", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056015645"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2005-01", 
    "datePublishedReg": "2005-01-01", 
    "description": "The surface acidity of H3PW12O40 and NaxH3-xPW12O40(x = 1-3) was studied using the adsorption of 2,2\u2032,6,6\u2032-tetramethyl-4-oxopiperidine-1-oxyl (TEMPON) and 2,2\u2032,6,6\u2032-tetramethyl-4-hydroxypiperidine-1-oxyl (TEMPOL) radicals. It was found that the amount of surface proton sites determined from the adsorption of TEMPON decreased with the degree of substitution of Na+ cations for protons. A correlation between amount of strong surface proton sites and catalytic activity of NaxH3-xPW12O40(x = 0-3) in the dealkylation reaction of 2,6-di-tert-butyl-4-methylphenol was found.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/pl00021995", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1136331", 
        "issn": [
          "0023-1584", 
          "0453-8811"
        ], 
        "name": "Kinetics and Catalysis", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "1", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "46"
      }
    ], 
    "name": "Surface acid sites of H3PW12O40 as studied by the adsorption of stable nitroxyl radicals", 
    "pagination": "123-127", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "3b33a081dd73058c178a9aaf22d79683a7268d73395fde206e35c1f513b39d45"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/pl00021995"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1085142819"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/pl00021995", 
      "https://app.dimensions.ai/details/publication/pub.1085142819"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T13:06", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8659_00000484.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1007/PL00021995"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/pl00021995'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/pl00021995'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/pl00021995'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/pl00021995'


 

This table displays all metadata directly associated to this object as RDF triples.

127 TRIPLES      21 PREDICATES      36 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/pl00021995 schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author N9d790a16957541ac9c351dea68fb45c2
4 schema:citation sg:pub.10.1007/bf02075437
5 https://doi.org/10.1016/0021-9517(86)90249-6
6 https://doi.org/10.1016/0304-5102(90)85068-s
7 https://doi.org/10.1016/0927-6513(95)00059-3
8 https://doi.org/10.1016/0927-7757(96)03603-5
9 https://doi.org/10.1016/s0360-0564(08)60041-3
10 https://doi.org/10.1016/s0926-860x(99)00361-0
11 https://doi.org/10.1021/ja00800a041
12 https://doi.org/10.1021/jo01361a036
13 schema:datePublished 2005-01
14 schema:datePublishedReg 2005-01-01
15 schema:description The surface acidity of H3PW12O40 and NaxH3-xPW12O40(x = 1-3) was studied using the adsorption of 2,2′,6,6′-tetramethyl-4-oxopiperidine-1-oxyl (TEMPON) and 2,2′,6,6′-tetramethyl-4-hydroxypiperidine-1-oxyl (TEMPOL) radicals. It was found that the amount of surface proton sites determined from the adsorption of TEMPON decreased with the degree of substitution of Na+ cations for protons. A correlation between amount of strong surface proton sites and catalytic activity of NaxH3-xPW12O40(x = 0-3) in the dealkylation reaction of 2,6-di-tert-butyl-4-methylphenol was found.
16 schema:genre research_article
17 schema:inLanguage en
18 schema:isAccessibleForFree false
19 schema:isPartOf N4e641526318c449db0452a0e5d2bb54b
20 Nca769e9319e748bf8b7554e2e238fd15
21 sg:journal.1136331
22 schema:name Surface acid sites of H3PW12O40 as studied by the adsorption of stable nitroxyl radicals
23 schema:pagination 123-127
24 schema:productId Nd1f4534b0cda4ee082919841e2ad9dd7
25 Ne169e719d0cc462dbf2c7dee7b64f953
26 Ne770dbdcba864d7b87a0de7bb5d7e20c
27 schema:sameAs https://app.dimensions.ai/details/publication/pub.1085142819
28 https://doi.org/10.1007/pl00021995
29 schema:sdDatePublished 2019-04-10T13:06
30 schema:sdLicense https://scigraph.springernature.com/explorer/license/
31 schema:sdPublisher N5012b6b6f12e428297f425f5c0d767a0
32 schema:url http://link.springer.com/10.1007/PL00021995
33 sgo:license sg:explorer/license/
34 sgo:sdDataset articles
35 rdf:type schema:ScholarlyArticle
36 N243ef0d11bd84393aa83c3b466481051 rdf:first sg:person.0727402755.46
37 rdf:rest Na5152b83c7b14d25847fda5c33c5587e
38 N4e641526318c449db0452a0e5d2bb54b schema:volumeNumber 46
39 rdf:type schema:PublicationVolume
40 N5012b6b6f12e428297f425f5c0d767a0 schema:name Springer Nature - SN SciGraph project
41 rdf:type schema:Organization
42 N9d790a16957541ac9c351dea68fb45c2 rdf:first sg:person.016052471473.71
43 rdf:rest Ncdba3e7aa80649578b414468c24d6a8d
44 Na5152b83c7b14d25847fda5c33c5587e rdf:first sg:person.016456372203.41
45 rdf:rest Nd5767457254f4f79b322889c2222f0bb
46 Nca769e9319e748bf8b7554e2e238fd15 schema:issueNumber 1
47 rdf:type schema:PublicationIssue
48 Ncdba3e7aa80649578b414468c24d6a8d rdf:first sg:person.013510657333.84
49 rdf:rest N243ef0d11bd84393aa83c3b466481051
50 Ncdc92a3426b4418f945a4eb1c365b738 rdf:first sg:person.07602127007.54
51 rdf:rest rdf:nil
52 Nd1f4534b0cda4ee082919841e2ad9dd7 schema:name readcube_id
53 schema:value 3b33a081dd73058c178a9aaf22d79683a7268d73395fde206e35c1f513b39d45
54 rdf:type schema:PropertyValue
55 Nd5767457254f4f79b322889c2222f0bb rdf:first sg:person.012600646766.96
56 rdf:rest Ncdc92a3426b4418f945a4eb1c365b738
57 Ne169e719d0cc462dbf2c7dee7b64f953 schema:name doi
58 schema:value 10.1007/pl00021995
59 rdf:type schema:PropertyValue
60 Ne770dbdcba864d7b87a0de7bb5d7e20c schema:name dimensions_id
61 schema:value pub.1085142819
62 rdf:type schema:PropertyValue
63 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
64 schema:name Chemical Sciences
65 rdf:type schema:DefinedTerm
66 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
67 schema:name Physical Chemistry (incl. Structural)
68 rdf:type schema:DefinedTerm
69 sg:journal.1136331 schema:issn 0023-1584
70 0453-8811
71 schema:name Kinetics and Catalysis
72 rdf:type schema:Periodical
73 sg:person.012600646766.96 schema:affiliation https://www.grid.ac/institutes/grid.418421.a
74 schema:familyName Volkova
75 schema:givenName G. G.
76 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012600646766.96
77 rdf:type schema:Person
78 sg:person.013510657333.84 schema:affiliation https://www.grid.ac/institutes/grid.418421.a
79 schema:familyName Ayupov
80 schema:givenName A. B.
81 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013510657333.84
82 rdf:type schema:Person
83 sg:person.016052471473.71 schema:affiliation https://www.grid.ac/institutes/grid.418421.a
84 schema:familyName Timofeeva
85 schema:givenName M. N.
86 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016052471473.71
87 rdf:type schema:Person
88 sg:person.016456372203.41 schema:affiliation https://www.grid.ac/institutes/grid.4605.7
89 schema:familyName Pak
90 schema:givenName Yu. R.
91 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016456372203.41
92 rdf:type schema:Person
93 sg:person.0727402755.46 schema:affiliation https://www.grid.ac/institutes/grid.418421.a
94 schema:familyName Volodin
95 schema:givenName A. M.
96 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0727402755.46
97 rdf:type schema:Person
98 sg:person.07602127007.54 schema:affiliation https://www.grid.ac/institutes/grid.4605.7
99 schema:familyName Echevskii
100 schema:givenName G. V.
101 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07602127007.54
102 rdf:type schema:Person
103 sg:pub.10.1007/bf02075437 schema:sameAs https://app.dimensions.ai/details/publication/pub.1034483864
104 https://doi.org/10.1007/bf02075437
105 rdf:type schema:CreativeWork
106 https://doi.org/10.1016/0021-9517(86)90249-6 schema:sameAs https://app.dimensions.ai/details/publication/pub.1015800540
107 rdf:type schema:CreativeWork
108 https://doi.org/10.1016/0304-5102(90)85068-s schema:sameAs https://app.dimensions.ai/details/publication/pub.1032441999
109 rdf:type schema:CreativeWork
110 https://doi.org/10.1016/0927-6513(95)00059-3 schema:sameAs https://app.dimensions.ai/details/publication/pub.1026929752
111 rdf:type schema:CreativeWork
112 https://doi.org/10.1016/0927-7757(96)03603-5 schema:sameAs https://app.dimensions.ai/details/publication/pub.1051457986
113 rdf:type schema:CreativeWork
114 https://doi.org/10.1016/s0360-0564(08)60041-3 schema:sameAs https://app.dimensions.ai/details/publication/pub.1004880699
115 rdf:type schema:CreativeWork
116 https://doi.org/10.1016/s0926-860x(99)00361-0 schema:sameAs https://app.dimensions.ai/details/publication/pub.1021833352
117 rdf:type schema:CreativeWork
118 https://doi.org/10.1021/ja00800a041 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055748966
119 rdf:type schema:CreativeWork
120 https://doi.org/10.1021/jo01361a036 schema:sameAs https://app.dimensions.ai/details/publication/pub.1056015645
121 rdf:type schema:CreativeWork
122 https://www.grid.ac/institutes/grid.418421.a schema:alternateName Boreskov Institute of Catalysis
123 schema:name Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, 630090, Novosibirsk, Russia
124 rdf:type schema:Organization
125 https://www.grid.ac/institutes/grid.4605.7 schema:alternateName Novosibirsk State University
126 schema:name Novosibirsk State University, 630090, Novosibirsk, Russia
127 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...