Optical-limiting properties of neutral nickel dithiolenes View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2000-06

AUTHORS

W.L. Tan, W. Ji, J.L. Zuo, J.F. Bai, X.Z. You, J.H. Lim, S. Yang, D.J. Hagan, E.W. Van Stryland

ABSTRACT

We report the observation of optical-limiting effects in benzene solutions of two neutral nickel complexes with multi-sulfur 1,2 dithiolene ligands, [Ni(medt)2] 1 (medt = 5,6-dihydro-6-methyl-1,4-dithiin-2,3-dithiolate) and [Ni(phdt)2] 2 (phdt = 5,6-dihydro-5-phenyl-1,4-dithiin-2,3-dithiolate). The limiting effects were observed with nanosecond and picosecond laser pulses. The limiting thresholds of complexes 1 and 2 were ≈0.3 J/cm2, measured with the ps laser pulses at 532 nm. The linear absorption spectra of the two complexes indicated that their limiting response should cover the visible and near-infrared region (up to 900 nm). Both ps time-resolved pump-probe and Z-scan experiments revealed that the limiting effects should originate from excited-state absorption and refraction More... »

PAGES

809-812

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/pl00021139

DOI

http://dx.doi.org/10.1007/pl00021139

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1017532153


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0205", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Optical Physics", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/02", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "National University of Singapore", 
          "id": "https://www.grid.ac/institutes/grid.4280.e", 
          "name": [
            "Department of Physics, National University of Singapore, Singapore 119260, Singapore (Fax: +65-7776126, E-mail: phyjiwei@nus.edu.sg), SG"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Tan", 
        "givenName": "W.L.", 
        "id": "sg:person.07770563615.60", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07770563615.60"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "National University of Singapore", 
          "id": "https://www.grid.ac/institutes/grid.4280.e", 
          "name": [
            "Department of Physics, National University of Singapore, Singapore 119260, Singapore (Fax: +65-7776126, E-mail: phyjiwei@nus.edu.sg), SG"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Ji", 
        "givenName": "W.", 
        "id": "sg:person.016242043040.93", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016242043040.93"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Nanjing University", 
          "id": "https://www.grid.ac/institutes/grid.41156.37", 
          "name": [
            "Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, P.R. China, CN"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Zuo", 
        "givenName": "J.L.", 
        "id": "sg:person.0765367715.97", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0765367715.97"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Nanjing University", 
          "id": "https://www.grid.ac/institutes/grid.41156.37", 
          "name": [
            "Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, P.R. China, CN"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Bai", 
        "givenName": "J.F.", 
        "id": "sg:person.01365057030.23", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01365057030.23"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Nanjing University", 
          "id": "https://www.grid.ac/institutes/grid.41156.37", 
          "name": [
            "Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, P.R. China, CN"
          ], 
          "type": "Organization"
        }, 
        "familyName": "You", 
        "givenName": "X.Z.", 
        "id": "sg:person.01067561513.18", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01067561513.18"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "University of Central Florida", 
          "id": "https://www.grid.ac/institutes/grid.170430.1", 
          "name": [
            "School of Optics/CREOL, University of Central Florida, Orlando, FL 32816-2700, USA, US"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Lim", 
        "givenName": "J.H.", 
        "id": "sg:person.013102377605.78", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013102377605.78"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "University of Central Florida", 
          "id": "https://www.grid.ac/institutes/grid.170430.1", 
          "name": [
            "School of Optics/CREOL, University of Central Florida, Orlando, FL 32816-2700, USA, US"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Yang", 
        "givenName": "S.", 
        "id": "sg:person.016375000305.28", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016375000305.28"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "University of Central Florida", 
          "id": "https://www.grid.ac/institutes/grid.170430.1", 
          "name": [
            "School of Optics/CREOL, University of Central Florida, Orlando, FL 32816-2700, USA, US"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Hagan", 
        "givenName": "D.J.", 
        "id": "sg:person.0702507371.72", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0702507371.72"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "University of Central Florida", 
          "id": "https://www.grid.ac/institutes/grid.170430.1", 
          "name": [
            "School of Optics/CREOL, University of Central Florida, Orlando, FL 32816-2700, USA, US"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Van Stryland", 
        "givenName": "E.W.", 
        "id": "sg:person.0713016642.95", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0713016642.95"
        ], 
        "type": "Person"
      }
    ], 
    "datePublished": "2000-06", 
    "datePublishedReg": "2000-06-01", 
    "description": "We report the observation of optical-limiting effects in benzene solutions of two neutral nickel complexes with multi-sulfur 1,2 dithiolene ligands, [Ni(medt)2] 1 (medt = 5,6-dihydro-6-methyl-1,4-dithiin-2,3-dithiolate) and [Ni(phdt)2] 2 (phdt = 5,6-dihydro-5-phenyl-1,4-dithiin-2,3-dithiolate). The limiting effects were observed with nanosecond and picosecond laser pulses. The limiting thresholds of complexes 1 and 2 were \u22480.3 J/cm2, measured with the ps laser pulses at 532 nm. The linear absorption spectra of the two complexes indicated that their limiting response should cover the visible and near-infrared region (up to 900 nm). Both ps time-resolved pump-probe and Z-scan experiments revealed that the limiting effects should originate from excited-state absorption and refraction", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/pl00021139", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1312262", 
        "issn": [
          "0946-2171", 
          "1432-0649"
        ], 
        "name": "Applied Physics B", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "6", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "70"
      }
    ], 
    "name": "Optical-limiting properties of neutral nickel dithiolenes", 
    "pagination": "809-812", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "5387af50701f70ad0549ee959c16b3cf956f819f0dd2be12913c768b3c2042cf"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/pl00021139"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1017532153"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/pl00021139", 
      "https://app.dimensions.ai/details/publication/pub.1017532153"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T14:01", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8660_00000480.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1007/PL00021139"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/pl00021139'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/pl00021139'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/pl00021139'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/pl00021139'


 

This table displays all metadata directly associated to this object as RDF triples.

123 TRIPLES      20 PREDICATES      27 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/pl00021139 schema:about anzsrc-for:02
2 anzsrc-for:0205
3 schema:author N84666563cfcb43fc9d32d45a5ec82866
4 schema:datePublished 2000-06
5 schema:datePublishedReg 2000-06-01
6 schema:description We report the observation of optical-limiting effects in benzene solutions of two neutral nickel complexes with multi-sulfur 1,2 dithiolene ligands, [Ni(medt)2] 1 (medt = 5,6-dihydro-6-methyl-1,4-dithiin-2,3-dithiolate) and [Ni(phdt)2] 2 (phdt = 5,6-dihydro-5-phenyl-1,4-dithiin-2,3-dithiolate). The limiting effects were observed with nanosecond and picosecond laser pulses. The limiting thresholds of complexes 1 and 2 were ≈0.3 J/cm2, measured with the ps laser pulses at 532 nm. The linear absorption spectra of the two complexes indicated that their limiting response should cover the visible and near-infrared region (up to 900 nm). Both ps time-resolved pump-probe and Z-scan experiments revealed that the limiting effects should originate from excited-state absorption and refraction
7 schema:genre research_article
8 schema:inLanguage en
9 schema:isAccessibleForFree false
10 schema:isPartOf N0cccdad799c64e7fa5986a4a13969999
11 Nc5b88afa8e4848a0b66433d0b2ba06a2
12 sg:journal.1312262
13 schema:name Optical-limiting properties of neutral nickel dithiolenes
14 schema:pagination 809-812
15 schema:productId N287c417554a7434ab4b9d468ec593627
16 N347ad2f01f1e4ce3953040f4e82078f1
17 N5125b1a539514a2bb8830033318f02b3
18 schema:sameAs https://app.dimensions.ai/details/publication/pub.1017532153
19 https://doi.org/10.1007/pl00021139
20 schema:sdDatePublished 2019-04-10T14:01
21 schema:sdLicense https://scigraph.springernature.com/explorer/license/
22 schema:sdPublisher N5975819a3ce646a5a4f88cdcf2e55b71
23 schema:url http://link.springer.com/10.1007/PL00021139
24 sgo:license sg:explorer/license/
25 sgo:sdDataset articles
26 rdf:type schema:ScholarlyArticle
27 N0cccdad799c64e7fa5986a4a13969999 schema:issueNumber 6
28 rdf:type schema:PublicationIssue
29 N1e66b811d458430bb4cf8c123de9eff1 rdf:first sg:person.0713016642.95
30 rdf:rest rdf:nil
31 N287c417554a7434ab4b9d468ec593627 schema:name dimensions_id
32 schema:value pub.1017532153
33 rdf:type schema:PropertyValue
34 N2c57883135a24368a394ec48e5ea6274 rdf:first sg:person.013102377605.78
35 rdf:rest Nfd73bbedc3df48c1a191dc29fc57a7ba
36 N332be9e602e64772be4a9a13e507a54f rdf:first sg:person.01067561513.18
37 rdf:rest N2c57883135a24368a394ec48e5ea6274
38 N347ad2f01f1e4ce3953040f4e82078f1 schema:name readcube_id
39 schema:value 5387af50701f70ad0549ee959c16b3cf956f819f0dd2be12913c768b3c2042cf
40 rdf:type schema:PropertyValue
41 N38afe0f14ee34fff929a354b1d6ed757 rdf:first sg:person.016242043040.93
42 rdf:rest N65da6a5007454d91b463483b462f0cf8
43 N5125b1a539514a2bb8830033318f02b3 schema:name doi
44 schema:value 10.1007/pl00021139
45 rdf:type schema:PropertyValue
46 N5975819a3ce646a5a4f88cdcf2e55b71 schema:name Springer Nature - SN SciGraph project
47 rdf:type schema:Organization
48 N65da6a5007454d91b463483b462f0cf8 rdf:first sg:person.0765367715.97
49 rdf:rest Nef93bd63f0224decb7e9695848f79b3f
50 N84666563cfcb43fc9d32d45a5ec82866 rdf:first sg:person.07770563615.60
51 rdf:rest N38afe0f14ee34fff929a354b1d6ed757
52 Nc5b88afa8e4848a0b66433d0b2ba06a2 schema:volumeNumber 70
53 rdf:type schema:PublicationVolume
54 Nef93bd63f0224decb7e9695848f79b3f rdf:first sg:person.01365057030.23
55 rdf:rest N332be9e602e64772be4a9a13e507a54f
56 Nf40200bb7c2f4908aba4c1f0a498b91e rdf:first sg:person.0702507371.72
57 rdf:rest N1e66b811d458430bb4cf8c123de9eff1
58 Nfd73bbedc3df48c1a191dc29fc57a7ba rdf:first sg:person.016375000305.28
59 rdf:rest Nf40200bb7c2f4908aba4c1f0a498b91e
60 anzsrc-for:02 schema:inDefinedTermSet anzsrc-for:
61 schema:name Physical Sciences
62 rdf:type schema:DefinedTerm
63 anzsrc-for:0205 schema:inDefinedTermSet anzsrc-for:
64 schema:name Optical Physics
65 rdf:type schema:DefinedTerm
66 sg:journal.1312262 schema:issn 0946-2171
67 1432-0649
68 schema:name Applied Physics B
69 rdf:type schema:Periodical
70 sg:person.01067561513.18 schema:affiliation https://www.grid.ac/institutes/grid.41156.37
71 schema:familyName You
72 schema:givenName X.Z.
73 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01067561513.18
74 rdf:type schema:Person
75 sg:person.013102377605.78 schema:affiliation https://www.grid.ac/institutes/grid.170430.1
76 schema:familyName Lim
77 schema:givenName J.H.
78 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013102377605.78
79 rdf:type schema:Person
80 sg:person.01365057030.23 schema:affiliation https://www.grid.ac/institutes/grid.41156.37
81 schema:familyName Bai
82 schema:givenName J.F.
83 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01365057030.23
84 rdf:type schema:Person
85 sg:person.016242043040.93 schema:affiliation https://www.grid.ac/institutes/grid.4280.e
86 schema:familyName Ji
87 schema:givenName W.
88 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016242043040.93
89 rdf:type schema:Person
90 sg:person.016375000305.28 schema:affiliation https://www.grid.ac/institutes/grid.170430.1
91 schema:familyName Yang
92 schema:givenName S.
93 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016375000305.28
94 rdf:type schema:Person
95 sg:person.0702507371.72 schema:affiliation https://www.grid.ac/institutes/grid.170430.1
96 schema:familyName Hagan
97 schema:givenName D.J.
98 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0702507371.72
99 rdf:type schema:Person
100 sg:person.0713016642.95 schema:affiliation https://www.grid.ac/institutes/grid.170430.1
101 schema:familyName Van Stryland
102 schema:givenName E.W.
103 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0713016642.95
104 rdf:type schema:Person
105 sg:person.0765367715.97 schema:affiliation https://www.grid.ac/institutes/grid.41156.37
106 schema:familyName Zuo
107 schema:givenName J.L.
108 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0765367715.97
109 rdf:type schema:Person
110 sg:person.07770563615.60 schema:affiliation https://www.grid.ac/institutes/grid.4280.e
111 schema:familyName Tan
112 schema:givenName W.L.
113 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07770563615.60
114 rdf:type schema:Person
115 https://www.grid.ac/institutes/grid.170430.1 schema:alternateName University of Central Florida
116 schema:name School of Optics/CREOL, University of Central Florida, Orlando, FL 32816-2700, USA, US
117 rdf:type schema:Organization
118 https://www.grid.ac/institutes/grid.41156.37 schema:alternateName Nanjing University
119 schema:name Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, P.R. China, CN
120 rdf:type schema:Organization
121 https://www.grid.ac/institutes/grid.4280.e schema:alternateName National University of Singapore
122 schema:name Department of Physics, National University of Singapore, Singapore 119260, Singapore (Fax: +65-7776126, E-mail: phyjiwei@nus.edu.sg), SG
123 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...