Optically Active Transition Metal Complexes CXX [1]. New Ruthenium(II) Complexes Containing Two Different Types of Optically Active Ligands View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1999-05

AUTHORS

Henri Brunner, Josef Spitzer

ABSTRACT

The synthesis of novel ruthenium(II) complexes containing two different chiral ligands is described. These ligands are on the one-hand (−)-diop and on the other hand optically active imines derived from the condensation of (S)-1-phenylethylamine with 2-pyrrolealdehyde or 2-salicylaldehyde. The synthesis includes the preparation of the precursors containing 1,5-cyclooctadiene (cod) and the corresponding imine ligands. Although for the octahedral (−)-diop-imine-ruthenium(II) complexes six diastereomers are possible, in highly stereoselective reactions only one diastereomer is formed. More... »

PAGES

605-612

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/pl00010241

DOI

http://dx.doi.org/10.1007/pl00010241

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1033736125


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0305", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Organic Chemistry", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "University of Regensburg", 
          "id": "https://www.grid.ac/institutes/grid.7727.5", 
          "name": [
            "Institut f\u00fcr Anorganische Chemie, Universit\u00e4t Regensburg, D-93040 Regensburg, Germany, DE"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Brunner", 
        "givenName": "Henri", 
        "id": "sg:person.013162531317.11", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013162531317.11"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "University of Regensburg", 
          "id": "https://www.grid.ac/institutes/grid.7727.5", 
          "name": [
            "Institut f\u00fcr Anorganische Chemie, Universit\u00e4t Regensburg, D-93040 Regensburg, Germany, DE"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Spitzer", 
        "givenName": "Josef", 
        "id": "sg:person.012532631403.35", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012532631403.35"
        ], 
        "type": "Person"
      }
    ], 
    "datePublished": "1999-05", 
    "datePublishedReg": "1999-05-01", 
    "description": "The synthesis of novel ruthenium(II) complexes containing two different chiral ligands is described. These ligands are on the one-hand (\u2212)-diop and on the other hand optically active imines derived from the condensation of (S)-1-phenylethylamine with 2-pyrrolealdehyde or 2-salicylaldehyde. The synthesis includes the preparation of the precursors containing 1,5-cyclooctadiene (cod) and the corresponding imine ligands. Although for the octahedral (\u2212)-diop-imine-ruthenium(II) complexes six diastereomers are possible, in highly stereoselective reactions only one diastereomer is formed.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/pl00010241", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1345587", 
        "issn": [
          "0343-7329", 
          "0026-9247"
        ], 
        "name": "Monatshefte f\u00fcr Chemie - Chemical Monthly", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "5", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "130"
      }
    ], 
    "name": "Optically Active Transition Metal Complexes CXX [1]. New Ruthenium(II) Complexes Containing Two Different Types of Optically Active Ligands", 
    "pagination": "605-612", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "a0b534c5e2771dc5fb44cb43522ab67556d83887edda908552e8870abb198b66"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/pl00010241"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1033736125"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/pl00010241", 
      "https://app.dimensions.ai/details/publication/pub.1033736125"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-11T01:54", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8700_00000489.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1007/PL00010241"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/pl00010241'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/pl00010241'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/pl00010241'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/pl00010241'


 

This table displays all metadata directly associated to this object as RDF triples.

68 TRIPLES      20 PREDICATES      27 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/pl00010241 schema:about anzsrc-for:03
2 anzsrc-for:0305
3 schema:author N8f12f19807b64b48b3646d1270ca7c3b
4 schema:datePublished 1999-05
5 schema:datePublishedReg 1999-05-01
6 schema:description The synthesis of novel ruthenium(II) complexes containing two different chiral ligands is described. These ligands are on the one-hand (−)-diop and on the other hand optically active imines derived from the condensation of (S)-1-phenylethylamine with 2-pyrrolealdehyde or 2-salicylaldehyde. The synthesis includes the preparation of the precursors containing 1,5-cyclooctadiene (cod) and the corresponding imine ligands. Although for the octahedral (−)-diop-imine-ruthenium(II) complexes six diastereomers are possible, in highly stereoselective reactions only one diastereomer is formed.
7 schema:genre research_article
8 schema:inLanguage en
9 schema:isAccessibleForFree false
10 schema:isPartOf N4153b452e0b2495b909e55b290f81ff3
11 N4a45b658a528457d9260aa504352eeff
12 sg:journal.1345587
13 schema:name Optically Active Transition Metal Complexes CXX [1]. New Ruthenium(II) Complexes Containing Two Different Types of Optically Active Ligands
14 schema:pagination 605-612
15 schema:productId N438d51818fdb44d998df3fe937497983
16 N96d172a259be4181bcdfa9022343243b
17 Ndd10bf293bd84524b8288d823dcd6008
18 schema:sameAs https://app.dimensions.ai/details/publication/pub.1033736125
19 https://doi.org/10.1007/pl00010241
20 schema:sdDatePublished 2019-04-11T01:54
21 schema:sdLicense https://scigraph.springernature.com/explorer/license/
22 schema:sdPublisher Nfd518c40dace4f74ad585ddd1d30149e
23 schema:url http://link.springer.com/10.1007/PL00010241
24 sgo:license sg:explorer/license/
25 sgo:sdDataset articles
26 rdf:type schema:ScholarlyArticle
27 N4153b452e0b2495b909e55b290f81ff3 schema:issueNumber 5
28 rdf:type schema:PublicationIssue
29 N438d51818fdb44d998df3fe937497983 schema:name readcube_id
30 schema:value a0b534c5e2771dc5fb44cb43522ab67556d83887edda908552e8870abb198b66
31 rdf:type schema:PropertyValue
32 N4a45b658a528457d9260aa504352eeff schema:volumeNumber 130
33 rdf:type schema:PublicationVolume
34 N8f12f19807b64b48b3646d1270ca7c3b rdf:first sg:person.013162531317.11
35 rdf:rest Na5105ede6ce84b848a0cb92e49d603ee
36 N96d172a259be4181bcdfa9022343243b schema:name dimensions_id
37 schema:value pub.1033736125
38 rdf:type schema:PropertyValue
39 Na5105ede6ce84b848a0cb92e49d603ee rdf:first sg:person.012532631403.35
40 rdf:rest rdf:nil
41 Ndd10bf293bd84524b8288d823dcd6008 schema:name doi
42 schema:value 10.1007/pl00010241
43 rdf:type schema:PropertyValue
44 Nfd518c40dace4f74ad585ddd1d30149e schema:name Springer Nature - SN SciGraph project
45 rdf:type schema:Organization
46 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
47 schema:name Chemical Sciences
48 rdf:type schema:DefinedTerm
49 anzsrc-for:0305 schema:inDefinedTermSet anzsrc-for:
50 schema:name Organic Chemistry
51 rdf:type schema:DefinedTerm
52 sg:journal.1345587 schema:issn 0026-9247
53 0343-7329
54 schema:name Monatshefte für Chemie - Chemical Monthly
55 rdf:type schema:Periodical
56 sg:person.012532631403.35 schema:affiliation https://www.grid.ac/institutes/grid.7727.5
57 schema:familyName Spitzer
58 schema:givenName Josef
59 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012532631403.35
60 rdf:type schema:Person
61 sg:person.013162531317.11 schema:affiliation https://www.grid.ac/institutes/grid.7727.5
62 schema:familyName Brunner
63 schema:givenName Henri
64 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013162531317.11
65 rdf:type schema:Person
66 https://www.grid.ac/institutes/grid.7727.5 schema:alternateName University of Regensburg
67 schema:name Institut für Anorganische Chemie, Universität Regensburg, D-93040 Regensburg, Germany, DE
68 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...