Equilibrium states and structure factor of concentrated colloidal dispersions in optimized random phase approximation View Full Text


Ontology type: schema:Chapter     


Chapter Info

DATE

2007-12-03

AUTHORS

Yu. V. Shulepov , S. Yu. Shulepov

ABSTRACT

In this work, the expression for correlation function of the concentrated dispersion of colloidal particles is calculated in optimized random phase approximation. We assume the time-averaged structure and thermodynamic states determined by the screened Coulomb pair potential and hard-sphere interaction between identical spherical colloidal particles immersed into electrolyte solution. The pair potential beyond the shortest separation of hard spheres obeys three models: a) equilibrium regime of charge regulation of particle, b) fixed potential on the surface of particle c) fixed charge of particle. Behavior of structure factor and corresponding correlation function shows increasing dispersion structure, eventually exhibiting solid-like state as we transfer from a) to the c) potential model. More... »

PAGES

148-150

References to SciGraph publications

Book

TITLE

Trends in Colloid and Interface Science X

ISBN

978-3-7985-1056-2

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bfb0115770

DOI

http://dx.doi.org/10.1007/bfb0115770

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1035301507


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