The peculiarities and nature of large-scale motion of highly crosslinked polymers View Full Text


Ontology type: schema:Chapter     


Chapter Info

DATE

2007-12-02

AUTHORS

B. A. Rozenberg , V. I. Irzhak

ABSTRACT

The peculiarities of highly crosslinked epoxy-amine polymer relaxation studied by pulse NMR method have been analyzed. A qualitative model of large-scale motion of highly crosslinked polymers based on the supposition of an anisotropic character of the interknot chain segmental motion and its dependence on the chain rigidity and connectivity of knots that adjoined to it has been developed. On the basis of this model the probable molecular and topological structure of epoxy-amine network fragments responsible for the α-relaxation has been given. The undissolved problems of highly crosslinked polymer α-relaxation have been discussed. More... »

PAGES

194-201

Book

TITLE

Physics of Polymer Networks

ISBN

978-3-7985-0914-6

Author Affiliations

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bfb0115500

DOI

http://dx.doi.org/10.1007/bfb0115500

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1025926489


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0303", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Macromolecular and Materials Chemistry", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Department of Polymer and Composite Materials of the Institute of Chemical Physics in Chernogolovka, Russian Academy of Sciences, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Rozenberg", 
        "givenName": "B. A.", 
        "id": "sg:person.015453043765.00", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015453043765.00"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Department of Polymer and Composite Materials of the Institute of Chemical Physics in Chernogolovka, Russian Academy of Sciences, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Irzhak", 
        "givenName": "V. I.", 
        "id": "sg:person.012414445231.76", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012414445231.76"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1007/3-540-16423-5_12", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1006471116", 
          "https://doi.org/10.1007/3-540-16423-5_12"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/masy.19870070106", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1019755421"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/pi.4980170218", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1033332614"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/pi.4980170218", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1033332614"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bfb0035356", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1034027589", 
          "https://doi.org/10.1007/bfb0035356"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2007-12-02", 
    "datePublishedReg": "2007-12-02", 
    "description": "The peculiarities of highly crosslinked epoxy-amine polymer relaxation studied by pulse NMR method have been analyzed. A qualitative model of large-scale motion of highly crosslinked polymers based on the supposition of an anisotropic character of the interknot chain segmental motion and its dependence on the chain rigidity and connectivity of knots that adjoined to it has been developed. On the basis of this model the probable molecular and topological structure of epoxy-amine network fragments responsible for the \u03b1-relaxation has been given. The undissolved problems of highly crosslinked polymer \u03b1-relaxation have been discussed.", 
    "genre": "chapter", 
    "id": "sg:pub.10.1007/bfb0115500", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": {
      "isbn": [
        "978-3-7985-0914-6"
      ], 
      "name": "Physics of Polymer Networks", 
      "type": "Book"
    }, 
    "name": "The peculiarities and nature of large-scale motion of highly crosslinked polymers", 
    "pagination": "194-201", 
    "productId": [
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/bfb0115500"
        ]
      }, 
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "7b83ba262b7d3edc2bf0115016b243c5108403ac366605634fc5a9203a30f01f"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1025926489"
        ]
      }
    ], 
    "publisher": {
      "location": "Darmstadt", 
      "name": "Steinkopff", 
      "type": "Organisation"
    }, 
    "sameAs": [
      "https://doi.org/10.1007/bfb0115500", 
      "https://app.dimensions.ai/details/publication/pub.1025926489"
    ], 
    "sdDataset": "chapters", 
    "sdDatePublished": "2019-04-16T05:47", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000347_0000000347/records_89816_00000001.jsonl", 
    "type": "Chapter", 
    "url": "https://link.springer.com/10.1007%2FBFb0115500"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bfb0115500'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bfb0115500'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bfb0115500'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bfb0115500'


 

This table displays all metadata directly associated to this object as RDF triples.

79 TRIPLES      22 PREDICATES      29 URIs      18 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/bfb0115500 schema:about anzsrc-for:03
2 anzsrc-for:0303
3 schema:author N8f9db98a28214ea89e671f236699abbf
4 schema:citation sg:pub.10.1007/3-540-16423-5_12
5 sg:pub.10.1007/bfb0035356
6 https://doi.org/10.1002/masy.19870070106
7 https://doi.org/10.1002/pi.4980170218
8 schema:datePublished 2007-12-02
9 schema:datePublishedReg 2007-12-02
10 schema:description The peculiarities of highly crosslinked epoxy-amine polymer relaxation studied by pulse NMR method have been analyzed. A qualitative model of large-scale motion of highly crosslinked polymers based on the supposition of an anisotropic character of the interknot chain segmental motion and its dependence on the chain rigidity and connectivity of knots that adjoined to it has been developed. On the basis of this model the probable molecular and topological structure of epoxy-amine network fragments responsible for the α-relaxation has been given. The undissolved problems of highly crosslinked polymer α-relaxation have been discussed.
11 schema:genre chapter
12 schema:inLanguage en
13 schema:isAccessibleForFree false
14 schema:isPartOf N3ccd36280b5d4de6a69edd2b70207808
15 schema:name The peculiarities and nature of large-scale motion of highly crosslinked polymers
16 schema:pagination 194-201
17 schema:productId N194185149e0b49acb63886da28729934
18 N23e8afb3de364b1980cd0686ed365820
19 N723b3635a045409ea978a319226a62af
20 schema:publisher Na9dcfc3847a443e2ab0d863e50a4d854
21 schema:sameAs https://app.dimensions.ai/details/publication/pub.1025926489
22 https://doi.org/10.1007/bfb0115500
23 schema:sdDatePublished 2019-04-16T05:47
24 schema:sdLicense https://scigraph.springernature.com/explorer/license/
25 schema:sdPublisher Ne8bca2053cf54ac99bea1f8e5ed89e92
26 schema:url https://link.springer.com/10.1007%2FBFb0115500
27 sgo:license sg:explorer/license/
28 sgo:sdDataset chapters
29 rdf:type schema:Chapter
30 N194185149e0b49acb63886da28729934 schema:name dimensions_id
31 schema:value pub.1025926489
32 rdf:type schema:PropertyValue
33 N23e8afb3de364b1980cd0686ed365820 schema:name readcube_id
34 schema:value 7b83ba262b7d3edc2bf0115016b243c5108403ac366605634fc5a9203a30f01f
35 rdf:type schema:PropertyValue
36 N3ccd36280b5d4de6a69edd2b70207808 schema:isbn 978-3-7985-0914-6
37 schema:name Physics of Polymer Networks
38 rdf:type schema:Book
39 N638009fb1f1a424984edbfce74581b95 rdf:first sg:person.012414445231.76
40 rdf:rest rdf:nil
41 N723b3635a045409ea978a319226a62af schema:name doi
42 schema:value 10.1007/bfb0115500
43 rdf:type schema:PropertyValue
44 N8f9db98a28214ea89e671f236699abbf rdf:first sg:person.015453043765.00
45 rdf:rest N638009fb1f1a424984edbfce74581b95
46 Na9dcfc3847a443e2ab0d863e50a4d854 schema:location Darmstadt
47 schema:name Steinkopff
48 rdf:type schema:Organisation
49 Ne8bca2053cf54ac99bea1f8e5ed89e92 schema:name Springer Nature - SN SciGraph project
50 rdf:type schema:Organization
51 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
52 schema:name Chemical Sciences
53 rdf:type schema:DefinedTerm
54 anzsrc-for:0303 schema:inDefinedTermSet anzsrc-for:
55 schema:name Macromolecular and Materials Chemistry
56 rdf:type schema:DefinedTerm
57 sg:person.012414445231.76 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
58 schema:familyName Irzhak
59 schema:givenName V. I.
60 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012414445231.76
61 rdf:type schema:Person
62 sg:person.015453043765.00 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
63 schema:familyName Rozenberg
64 schema:givenName B. A.
65 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015453043765.00
66 rdf:type schema:Person
67 sg:pub.10.1007/3-540-16423-5_12 schema:sameAs https://app.dimensions.ai/details/publication/pub.1006471116
68 https://doi.org/10.1007/3-540-16423-5_12
69 rdf:type schema:CreativeWork
70 sg:pub.10.1007/bfb0035356 schema:sameAs https://app.dimensions.ai/details/publication/pub.1034027589
71 https://doi.org/10.1007/bfb0035356
72 rdf:type schema:CreativeWork
73 https://doi.org/10.1002/masy.19870070106 schema:sameAs https://app.dimensions.ai/details/publication/pub.1019755421
74 rdf:type schema:CreativeWork
75 https://doi.org/10.1002/pi.4980170218 schema:sameAs https://app.dimensions.ai/details/publication/pub.1033332614
76 rdf:type schema:CreativeWork
77 https://www.grid.ac/institutes/grid.4886.2 schema:alternateName Russian Academy of Sciences
78 schema:name Department of Polymer and Composite Materials of the Institute of Chemical Physics in Chernogolovka, Russian Academy of Sciences, Moscow, Russia
79 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...