Kinetics, thermodynamics and mechanism of reactions of epoxy oligomers with amines View Full Text


Ontology type: schema:Chapter     


Chapter Info

DATE

1986

AUTHORS

B. A. Rozenberg

ABSTRACT

In this review, modern interpretations of the kinetics, thermodynamics and mechanisms of curing of epoxy oligomers with primary, secondary, and tertiary amines and their mixtures, as well as the structure of the resulting polymers are discussed. The effect of the structure of the reagents on their reactivity is analyzed. Kinetic peculiarities of the deep stages of the curing process are emphasized Problems to be solved in the future are formulated. More... »

PAGES

113-165

Book

TITLE

Epoxy Resins and Composites II

ISBN

3-540-15825-1

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bfb0017916

DOI

http://dx.doi.org/10.1007/bfb0017916

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1026487317


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0303", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Macromolecular and Materials Chemistry", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Semenov Institute of Chemical Physics", 
          "id": "https://www.grid.ac/institutes/grid.424930.8", 
          "name": [
            "Institute of Chemical Physics, Academy of Sciences of the U.S.S.R., 142432\u00a0Chernogolovka, Moscow Region, U.S.S.R."
          ], 
          "type": "Organization"
        }, 
        "familyName": "Rozenberg", 
        "givenName": "B. A.", 
        "id": "sg:person.015453043765.00", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015453043765.00"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1002/macp.1972.021540107", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1002542700"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/macp.1963.020680111", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1003375185"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0015-0568(83)90033-7", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1004618668"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0015-0568(83)90033-7", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1004618668"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/macp.1966.020910115", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1012619111"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1139/v51-068", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1013792671"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0032-3861(78)90200-8", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1015503390"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0032-3861(78)90200-8", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1015503390"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1139/v51-067", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1018356664"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf01045249", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1019585805", 
          "https://doi.org/10.1007/bf01045249"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0032-3861(78)90243-4", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1020845431"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0032-3861(78)90243-4", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1020845431"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0032-3861(61)90010-6", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1031159323"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0032-3861(61)90010-6", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1031159323"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/pen.760221807", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1035885014"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/app.1983.070280309", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1038163761"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/app.1961.070051313", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1043561812"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/macp.1960.020370101", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1047591089"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/macp.1981.021820117", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1049029700"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf00255704", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1053238174", 
          "https://doi.org/10.1007/bf00255704"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf00255704", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1053238174", 
          "https://doi.org/10.1007/bf00255704"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/macp.1968.021150110", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1053564809"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cr50028a006", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1053748765"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ie50553a028", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055636164"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/j100864a037", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055683236"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja01075a031", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055766168"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja01481a042", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055800714"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jo01282a057", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056010445"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1063/1.443328", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1058021353"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1063/1.443329", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1058021354"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "1986", 
    "datePublishedReg": "1986-01-01", 
    "description": "In this review, modern interpretations of the kinetics, thermodynamics and mechanisms of curing of epoxy oligomers with primary, secondary, and tertiary amines and their mixtures, as well as the structure of the resulting polymers are discussed. The effect of the structure of the reagents on their reactivity is analyzed. Kinetic peculiarities of the deep stages of the curing process are emphasized Problems to be solved in the future are formulated.", 
    "editor": [
      {
        "familyName": "Du\u0161ek", 
        "givenName": "K.", 
        "type": "Person"
      }
    ], 
    "genre": "chapter", 
    "id": "sg:pub.10.1007/bfb0017916", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": {
      "isbn": [
        "3-540-15825-1"
      ], 
      "name": "Epoxy Resins and Composites II", 
      "type": "Book"
    }, 
    "name": "Kinetics, thermodynamics and mechanism of reactions of epoxy oligomers with amines", 
    "pagination": "113-165", 
    "productId": [
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/bfb0017916"
        ]
      }, 
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "7e2fbdb786a649a86a4eae49961eb8bdbc89eb2f2a62e859531a9be0ee10d618"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1026487317"
        ]
      }
    ], 
    "publisher": {
      "location": "Berlin/Heidelberg", 
      "name": "Springer-Verlag", 
      "type": "Organisation"
    }, 
    "sameAs": [
      "https://doi.org/10.1007/bfb0017916", 
      "https://app.dimensions.ai/details/publication/pub.1026487317"
    ], 
    "sdDataset": "chapters", 
    "sdDatePublished": "2019-04-15T21:02", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8690_00000259.jsonl", 
    "type": "Chapter", 
    "url": "http://link.springer.com/10.1007/BFb0017916"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bfb0017916'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bfb0017916'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bfb0017916'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bfb0017916'


 

This table displays all metadata directly associated to this object as RDF triples.

141 TRIPLES      23 PREDICATES      52 URIs      20 LITERALS      8 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/bfb0017916 schema:about anzsrc-for:03
2 anzsrc-for:0303
3 schema:author Nc166d5360eda499e9b8e89266c17010c
4 schema:citation sg:pub.10.1007/bf00255704
5 sg:pub.10.1007/bf01045249
6 https://doi.org/10.1002/app.1961.070051313
7 https://doi.org/10.1002/app.1983.070280309
8 https://doi.org/10.1002/macp.1960.020370101
9 https://doi.org/10.1002/macp.1963.020680111
10 https://doi.org/10.1002/macp.1966.020910115
11 https://doi.org/10.1002/macp.1968.021150110
12 https://doi.org/10.1002/macp.1972.021540107
13 https://doi.org/10.1002/macp.1981.021820117
14 https://doi.org/10.1002/pen.760221807
15 https://doi.org/10.1016/0015-0568(83)90033-7
16 https://doi.org/10.1016/0032-3861(61)90010-6
17 https://doi.org/10.1016/0032-3861(78)90200-8
18 https://doi.org/10.1016/0032-3861(78)90243-4
19 https://doi.org/10.1021/cr50028a006
20 https://doi.org/10.1021/ie50553a028
21 https://doi.org/10.1021/j100864a037
22 https://doi.org/10.1021/ja01075a031
23 https://doi.org/10.1021/ja01481a042
24 https://doi.org/10.1021/jo01282a057
25 https://doi.org/10.1063/1.443328
26 https://doi.org/10.1063/1.443329
27 https://doi.org/10.1139/v51-067
28 https://doi.org/10.1139/v51-068
29 schema:datePublished 1986
30 schema:datePublishedReg 1986-01-01
31 schema:description In this review, modern interpretations of the kinetics, thermodynamics and mechanisms of curing of epoxy oligomers with primary, secondary, and tertiary amines and their mixtures, as well as the structure of the resulting polymers are discussed. The effect of the structure of the reagents on their reactivity is analyzed. Kinetic peculiarities of the deep stages of the curing process are emphasized Problems to be solved in the future are formulated.
32 schema:editor Ne11381a79b3e412ba364f1fcf8a6b164
33 schema:genre chapter
34 schema:inLanguage en
35 schema:isAccessibleForFree false
36 schema:isPartOf N78c7a92451e4485a91773525acef2e25
37 schema:name Kinetics, thermodynamics and mechanism of reactions of epoxy oligomers with amines
38 schema:pagination 113-165
39 schema:productId N11776854f4a34e60adc857f598e8c6a0
40 N633c8b7f53474d0ebf4652480ff486cb
41 N748d25daa5e3456cba030b3b915770c5
42 schema:publisher N50ca0bdc290a4f1c96e1fa4280af5473
43 schema:sameAs https://app.dimensions.ai/details/publication/pub.1026487317
44 https://doi.org/10.1007/bfb0017916
45 schema:sdDatePublished 2019-04-15T21:02
46 schema:sdLicense https://scigraph.springernature.com/explorer/license/
47 schema:sdPublisher N3aec9d47f0504f488ef1125987c5e9ff
48 schema:url http://link.springer.com/10.1007/BFb0017916
49 sgo:license sg:explorer/license/
50 sgo:sdDataset chapters
51 rdf:type schema:Chapter
52 N1131f1c7b42a415e966809d69f47f97f schema:familyName Dušek
53 schema:givenName K.
54 rdf:type schema:Person
55 N11776854f4a34e60adc857f598e8c6a0 schema:name dimensions_id
56 schema:value pub.1026487317
57 rdf:type schema:PropertyValue
58 N3aec9d47f0504f488ef1125987c5e9ff schema:name Springer Nature - SN SciGraph project
59 rdf:type schema:Organization
60 N50ca0bdc290a4f1c96e1fa4280af5473 schema:location Berlin/Heidelberg
61 schema:name Springer-Verlag
62 rdf:type schema:Organisation
63 N633c8b7f53474d0ebf4652480ff486cb schema:name readcube_id
64 schema:value 7e2fbdb786a649a86a4eae49961eb8bdbc89eb2f2a62e859531a9be0ee10d618
65 rdf:type schema:PropertyValue
66 N748d25daa5e3456cba030b3b915770c5 schema:name doi
67 schema:value 10.1007/bfb0017916
68 rdf:type schema:PropertyValue
69 N78c7a92451e4485a91773525acef2e25 schema:isbn 3-540-15825-1
70 schema:name Epoxy Resins and Composites II
71 rdf:type schema:Book
72 Nc166d5360eda499e9b8e89266c17010c rdf:first sg:person.015453043765.00
73 rdf:rest rdf:nil
74 Ne11381a79b3e412ba364f1fcf8a6b164 rdf:first N1131f1c7b42a415e966809d69f47f97f
75 rdf:rest rdf:nil
76 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
77 schema:name Chemical Sciences
78 rdf:type schema:DefinedTerm
79 anzsrc-for:0303 schema:inDefinedTermSet anzsrc-for:
80 schema:name Macromolecular and Materials Chemistry
81 rdf:type schema:DefinedTerm
82 sg:person.015453043765.00 schema:affiliation https://www.grid.ac/institutes/grid.424930.8
83 schema:familyName Rozenberg
84 schema:givenName B. A.
85 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015453043765.00
86 rdf:type schema:Person
87 sg:pub.10.1007/bf00255704 schema:sameAs https://app.dimensions.ai/details/publication/pub.1053238174
88 https://doi.org/10.1007/bf00255704
89 rdf:type schema:CreativeWork
90 sg:pub.10.1007/bf01045249 schema:sameAs https://app.dimensions.ai/details/publication/pub.1019585805
91 https://doi.org/10.1007/bf01045249
92 rdf:type schema:CreativeWork
93 https://doi.org/10.1002/app.1961.070051313 schema:sameAs https://app.dimensions.ai/details/publication/pub.1043561812
94 rdf:type schema:CreativeWork
95 https://doi.org/10.1002/app.1983.070280309 schema:sameAs https://app.dimensions.ai/details/publication/pub.1038163761
96 rdf:type schema:CreativeWork
97 https://doi.org/10.1002/macp.1960.020370101 schema:sameAs https://app.dimensions.ai/details/publication/pub.1047591089
98 rdf:type schema:CreativeWork
99 https://doi.org/10.1002/macp.1963.020680111 schema:sameAs https://app.dimensions.ai/details/publication/pub.1003375185
100 rdf:type schema:CreativeWork
101 https://doi.org/10.1002/macp.1966.020910115 schema:sameAs https://app.dimensions.ai/details/publication/pub.1012619111
102 rdf:type schema:CreativeWork
103 https://doi.org/10.1002/macp.1968.021150110 schema:sameAs https://app.dimensions.ai/details/publication/pub.1053564809
104 rdf:type schema:CreativeWork
105 https://doi.org/10.1002/macp.1972.021540107 schema:sameAs https://app.dimensions.ai/details/publication/pub.1002542700
106 rdf:type schema:CreativeWork
107 https://doi.org/10.1002/macp.1981.021820117 schema:sameAs https://app.dimensions.ai/details/publication/pub.1049029700
108 rdf:type schema:CreativeWork
109 https://doi.org/10.1002/pen.760221807 schema:sameAs https://app.dimensions.ai/details/publication/pub.1035885014
110 rdf:type schema:CreativeWork
111 https://doi.org/10.1016/0015-0568(83)90033-7 schema:sameAs https://app.dimensions.ai/details/publication/pub.1004618668
112 rdf:type schema:CreativeWork
113 https://doi.org/10.1016/0032-3861(61)90010-6 schema:sameAs https://app.dimensions.ai/details/publication/pub.1031159323
114 rdf:type schema:CreativeWork
115 https://doi.org/10.1016/0032-3861(78)90200-8 schema:sameAs https://app.dimensions.ai/details/publication/pub.1015503390
116 rdf:type schema:CreativeWork
117 https://doi.org/10.1016/0032-3861(78)90243-4 schema:sameAs https://app.dimensions.ai/details/publication/pub.1020845431
118 rdf:type schema:CreativeWork
119 https://doi.org/10.1021/cr50028a006 schema:sameAs https://app.dimensions.ai/details/publication/pub.1053748765
120 rdf:type schema:CreativeWork
121 https://doi.org/10.1021/ie50553a028 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055636164
122 rdf:type schema:CreativeWork
123 https://doi.org/10.1021/j100864a037 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055683236
124 rdf:type schema:CreativeWork
125 https://doi.org/10.1021/ja01075a031 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055766168
126 rdf:type schema:CreativeWork
127 https://doi.org/10.1021/ja01481a042 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055800714
128 rdf:type schema:CreativeWork
129 https://doi.org/10.1021/jo01282a057 schema:sameAs https://app.dimensions.ai/details/publication/pub.1056010445
130 rdf:type schema:CreativeWork
131 https://doi.org/10.1063/1.443328 schema:sameAs https://app.dimensions.ai/details/publication/pub.1058021353
132 rdf:type schema:CreativeWork
133 https://doi.org/10.1063/1.443329 schema:sameAs https://app.dimensions.ai/details/publication/pub.1058021354
134 rdf:type schema:CreativeWork
135 https://doi.org/10.1139/v51-067 schema:sameAs https://app.dimensions.ai/details/publication/pub.1018356664
136 rdf:type schema:CreativeWork
137 https://doi.org/10.1139/v51-068 schema:sameAs https://app.dimensions.ai/details/publication/pub.1013792671
138 rdf:type schema:CreativeWork
139 https://www.grid.ac/institutes/grid.424930.8 schema:alternateName Semenov Institute of Chemical Physics
140 schema:name Institute of Chemical Physics, Academy of Sciences of the U.S.S.R., 142432 Chernogolovka, Moscow Region, U.S.S.R.
141 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...