The Preparation and Plasticizing Characteristics of the N,N-bis(2-Alkoxyethyl) Amides of Long Chain Fatty Acids View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1964-12

AUTHORS

R. R. Mod, F. C. Magne, E. L. Skau

ABSTRACT

A number of N-acyl derivatives of bis(2-alkoxyethyl) amines have been prepared, characterized and screened as plasticizers for poly (vinyl chloride-vinyl acetate) copolymer. Included were the N,N-bis (2-alkoxyethyl) amides of saturated (normal and branched), unsaturated, epoxy, dimer, terpenic and naphthenic acids as well as mixed acids from animal fats, rapeseed, Limnanthes douglasii seed, parsley seed and selectively hydrogenated cottonseed oils. With the exception of the linoleic acid derivative, all these amides, including the stearamide derivative, were compatible. Some exhibited low-temp properties comparable to the adipate plasticizers without the adverse volatility characteristics of the adipates. With the exception of the epoxystearamide derivative the N,N-bis(2-alkoxyethyl)amides were inferior to dioctyl phthalate in thermal stability. The N,N-bis(2-ethoxyethyl)stearamide is of special significance in that it seems to be the only carboxylic derivative of stearic acid known to be effective as a primary plasticizer. More... »

PAGES

781-782

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf03373656

DOI

http://dx.doi.org/10.1007/bf03373656

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1004212461


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/09", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Engineering", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0904", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Engineering", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Southern Regional Research Laboratory, New Orleans, Louisiana, USA", 
          "id": "http://www.grid.ac/institutes/grid.507314.4", 
          "name": [
            "Southern Regional Research Laboratory, New Orleans, Louisiana, USA"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Mod", 
        "givenName": "R. R.", 
        "id": "sg:person.011073123343.10", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011073123343.10"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Southern Regional Research Laboratory, New Orleans, Louisiana, USA", 
          "id": "http://www.grid.ac/institutes/grid.507314.4", 
          "name": [
            "Southern Regional Research Laboratory, New Orleans, Louisiana, USA"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Magne", 
        "givenName": "F. C.", 
        "id": "sg:person.012476571651.61", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012476571651.61"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Southern Regional Research Laboratory, New Orleans, Louisiana, USA", 
          "id": "http://www.grid.ac/institutes/grid.507314.4", 
          "name": [
            "Southern Regional Research Laboratory, New Orleans, Louisiana, USA"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Skau", 
        "givenName": "E. L.", 
        "id": "sg:person.014423631546.73", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014423631546.73"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1007/bf03024658", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1047420749", 
          "https://doi.org/10.1007/bf03024658"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02822461", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1033105712", 
          "https://doi.org/10.1007/bf02822461"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02638430", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1011137243", 
          "https://doi.org/10.1007/bf02638430"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02539918", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1010674973", 
          "https://doi.org/10.1007/bf02539918"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02640274", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1002911840", 
          "https://doi.org/10.1007/bf02640274"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "1964-12", 
    "datePublishedReg": "1964-12-01", 
    "description": "A number of N-acyl derivatives of bis(2-alkoxyethyl) amines have been prepared, characterized and screened as plasticizers for poly (vinyl chloride-vinyl acetate) copolymer. Included were the N,N-bis (2-alkoxyethyl) amides of saturated (normal and branched), unsaturated, epoxy, dimer, terpenic and naphthenic acids as well as mixed acids from animal fats, rapeseed, Limnanthes douglasii seed, parsley seed and selectively hydrogenated cottonseed oils. With the exception of the linoleic acid derivative, all these amides, including the stearamide derivative, were compatible. Some exhibited low-temp properties comparable to the adipate plasticizers without the adverse volatility characteristics of the adipates. With the exception of the epoxystearamide derivative the N,N-bis(2-alkoxyethyl)amides were inferior to dioctyl phthalate in thermal stability. The N,N-bis(2-ethoxyethyl)stearamide is of special significance in that it seems to be the only carboxylic derivative of stearic acid known to be effective as a primary plasticizer.", 
    "genre": "article", 
    "id": "sg:pub.10.1007/bf03373656", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1082739", 
        "issn": [
          "0003-021X", 
          "1558-9331"
        ], 
        "name": "Journal of the American Oil Chemists' Society", 
        "publisher": "Wiley", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "12", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "41"
      }
    ], 
    "keywords": [
      "linoleic acid derivatives", 
      "long-chain fatty acids", 
      "chain fatty acids", 
      "fatty acids", 
      "animal fat", 
      "fat", 
      "acid", 
      "acid derivatives", 
      "parsley seeds", 
      "stearic acid", 
      "N-acyl derivatives", 
      "exception", 
      "significance", 
      "cottonseed oil", 
      "characteristics", 
      "derivatives", 
      "number", 
      "preparation", 
      "special significance", 
      "amides", 
      "carboxylic derivatives", 
      "amines", 
      "oil", 
      "plasticizer", 
      "seeds", 
      "adipate plasticizers", 
      "properties", 
      "primary plasticizer", 
      "terpenic", 
      "dimers", 
      "stability", 
      "adipate", 
      "poly (ethylene-co-methacrylic acid) copolymer", 
      "rapeseed", 
      "mixed acid", 
      "dioctyl", 
      "Limnanthes", 
      "copolymers", 
      "epoxy", 
      "naphthenic acids", 
      "volatility characteristics", 
      "thermal stability"
    ], 
    "name": "The Preparation and Plasticizing Characteristics of the N,N-bis(2-Alkoxyethyl) Amides of Long Chain Fatty Acids", 
    "pagination": "781-782", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1004212461"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/bf03373656"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/bf03373656", 
      "https://app.dimensions.ai/details/publication/pub.1004212461"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-09-02T15:44", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20220902/entities/gbq_results/article/article_100.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1007/bf03373656"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf03373656'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf03373656'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf03373656'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf03373656'


 

This table displays all metadata directly associated to this object as RDF triples.

133 TRIPLES      21 PREDICATES      72 URIs      59 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/bf03373656 schema:about anzsrc-for:09
2 anzsrc-for:0904
3 schema:author Nb8e208eea7ea48b3b2844f6a2b83cc4a
4 schema:citation sg:pub.10.1007/bf02539918
5 sg:pub.10.1007/bf02638430
6 sg:pub.10.1007/bf02640274
7 sg:pub.10.1007/bf02822461
8 sg:pub.10.1007/bf03024658
9 schema:datePublished 1964-12
10 schema:datePublishedReg 1964-12-01
11 schema:description A number of N-acyl derivatives of bis(2-alkoxyethyl) amines have been prepared, characterized and screened as plasticizers for poly (vinyl chloride-vinyl acetate) copolymer. Included were the N,N-bis (2-alkoxyethyl) amides of saturated (normal and branched), unsaturated, epoxy, dimer, terpenic and naphthenic acids as well as mixed acids from animal fats, rapeseed, Limnanthes douglasii seed, parsley seed and selectively hydrogenated cottonseed oils. With the exception of the linoleic acid derivative, all these amides, including the stearamide derivative, were compatible. Some exhibited low-temp properties comparable to the adipate plasticizers without the adverse volatility characteristics of the adipates. With the exception of the epoxystearamide derivative the N,N-bis(2-alkoxyethyl)amides were inferior to dioctyl phthalate in thermal stability. The N,N-bis(2-ethoxyethyl)stearamide is of special significance in that it seems to be the only carboxylic derivative of stearic acid known to be effective as a primary plasticizer.
12 schema:genre article
13 schema:isAccessibleForFree false
14 schema:isPartOf N3ab990167c1f4934a33dd79ff7165fce
15 Nd69cb362291540e7a635e2e71b49ad40
16 sg:journal.1082739
17 schema:keywords Limnanthes
18 N-acyl derivatives
19 acid
20 acid derivatives
21 adipate
22 adipate plasticizers
23 amides
24 amines
25 animal fat
26 carboxylic derivatives
27 chain fatty acids
28 characteristics
29 copolymers
30 cottonseed oil
31 derivatives
32 dimers
33 dioctyl
34 epoxy
35 exception
36 fat
37 fatty acids
38 linoleic acid derivatives
39 long-chain fatty acids
40 mixed acid
41 naphthenic acids
42 number
43 oil
44 parsley seeds
45 plasticizer
46 poly (ethylene-co-methacrylic acid) copolymer
47 preparation
48 primary plasticizer
49 properties
50 rapeseed
51 seeds
52 significance
53 special significance
54 stability
55 stearic acid
56 terpenic
57 thermal stability
58 volatility characteristics
59 schema:name The Preparation and Plasticizing Characteristics of the N,N-bis(2-Alkoxyethyl) Amides of Long Chain Fatty Acids
60 schema:pagination 781-782
61 schema:productId N7cb2bc609f6a42179388227d423ec21b
62 Na603124a48c54ad7834f359d39f51caa
63 schema:sameAs https://app.dimensions.ai/details/publication/pub.1004212461
64 https://doi.org/10.1007/bf03373656
65 schema:sdDatePublished 2022-09-02T15:44
66 schema:sdLicense https://scigraph.springernature.com/explorer/license/
67 schema:sdPublisher Ndec59cc334d743c1b4d106fda863e5dd
68 schema:url https://doi.org/10.1007/bf03373656
69 sgo:license sg:explorer/license/
70 sgo:sdDataset articles
71 rdf:type schema:ScholarlyArticle
72 N3ab990167c1f4934a33dd79ff7165fce schema:volumeNumber 41
73 rdf:type schema:PublicationVolume
74 N7cb2bc609f6a42179388227d423ec21b schema:name doi
75 schema:value 10.1007/bf03373656
76 rdf:type schema:PropertyValue
77 Na603124a48c54ad7834f359d39f51caa schema:name dimensions_id
78 schema:value pub.1004212461
79 rdf:type schema:PropertyValue
80 Nb8e208eea7ea48b3b2844f6a2b83cc4a rdf:first sg:person.011073123343.10
81 rdf:rest Nd1fb49b501c842a58bf842a68235dc04
82 Nd1fb49b501c842a58bf842a68235dc04 rdf:first sg:person.012476571651.61
83 rdf:rest Nef6d1188ec19442db4ca0c0aecdae049
84 Nd69cb362291540e7a635e2e71b49ad40 schema:issueNumber 12
85 rdf:type schema:PublicationIssue
86 Ndec59cc334d743c1b4d106fda863e5dd schema:name Springer Nature - SN SciGraph project
87 rdf:type schema:Organization
88 Nef6d1188ec19442db4ca0c0aecdae049 rdf:first sg:person.014423631546.73
89 rdf:rest rdf:nil
90 anzsrc-for:09 schema:inDefinedTermSet anzsrc-for:
91 schema:name Engineering
92 rdf:type schema:DefinedTerm
93 anzsrc-for:0904 schema:inDefinedTermSet anzsrc-for:
94 schema:name Chemical Engineering
95 rdf:type schema:DefinedTerm
96 sg:journal.1082739 schema:issn 0003-021X
97 1558-9331
98 schema:name Journal of the American Oil Chemists' Society
99 schema:publisher Wiley
100 rdf:type schema:Periodical
101 sg:person.011073123343.10 schema:affiliation grid-institutes:grid.507314.4
102 schema:familyName Mod
103 schema:givenName R. R.
104 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011073123343.10
105 rdf:type schema:Person
106 sg:person.012476571651.61 schema:affiliation grid-institutes:grid.507314.4
107 schema:familyName Magne
108 schema:givenName F. C.
109 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012476571651.61
110 rdf:type schema:Person
111 sg:person.014423631546.73 schema:affiliation grid-institutes:grid.507314.4
112 schema:familyName Skau
113 schema:givenName E. L.
114 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014423631546.73
115 rdf:type schema:Person
116 sg:pub.10.1007/bf02539918 schema:sameAs https://app.dimensions.ai/details/publication/pub.1010674973
117 https://doi.org/10.1007/bf02539918
118 rdf:type schema:CreativeWork
119 sg:pub.10.1007/bf02638430 schema:sameAs https://app.dimensions.ai/details/publication/pub.1011137243
120 https://doi.org/10.1007/bf02638430
121 rdf:type schema:CreativeWork
122 sg:pub.10.1007/bf02640274 schema:sameAs https://app.dimensions.ai/details/publication/pub.1002911840
123 https://doi.org/10.1007/bf02640274
124 rdf:type schema:CreativeWork
125 sg:pub.10.1007/bf02822461 schema:sameAs https://app.dimensions.ai/details/publication/pub.1033105712
126 https://doi.org/10.1007/bf02822461
127 rdf:type schema:CreativeWork
128 sg:pub.10.1007/bf03024658 schema:sameAs https://app.dimensions.ai/details/publication/pub.1047420749
129 https://doi.org/10.1007/bf03024658
130 rdf:type schema:CreativeWork
131 grid-institutes:grid.507314.4 schema:alternateName Southern Regional Research Laboratory, New Orleans, Louisiana, USA
132 schema:name Southern Regional Research Laboratory, New Orleans, Louisiana, USA
133 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...