Influence of Tacticity on the Retardation Mode Associated with Tg in PMMA View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1998-03

AUTHORS

S. Doulut, P. Demont, C. Lacabanne

ABSTRACT

The anelastic properties of PMMA in the temperature range of the main retardation mode are strongly dependent upon tacticity. The thermally stimulated creep (TSCr) technique was used to analyse the distribution function of retardation times. A series of PMMA, with various tacticities, synthesized by living polymerization, were investigated. One of the most important findings was the observation of a sub-mode, at 150°C, with a magnitude increasing with syndiotactic triads. The existence of physical interactions might explain this behaviour. On the low-temperature tail of the a retardation mode, a sub-mode was observed at 60°C: it was associated with remaining isotactic triads. More... »

PAGES

805-814

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf03341457

DOI

http://dx.doi.org/10.1007/bf03341457

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1053312136


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