A new crystal engineering approach for the synthesis of {[K.18-Crown-6]I3}n as a nanotube-Like and recyclable catalyst for the chemoselective silylation ... View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2011-06

AUTHORS

M. A. Zolfigol, E. Kolvari, N. Koukabi, S. Salehzadeh, G. Chehardoli, I. S. Tidmarsh, K. Niknam

ABSTRACT

Reaction of 18-crown-6 with KI in ethanol solution followed by addition of iodine (I2) afforded a unique triiodide salt with a nanotube-like structure ({[K.18-Crown-6]I3}n). It is shown that this reagent may be used for the chemoselective trimethylsilylation of alcohols. The synthesis of the crystalline reagent is a good example of crystal engineering. Reagent was recycled and reused. More... »

PAGES

484-494

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf03249082

DOI

http://dx.doi.org/10.1007/bf03249082

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1028086834


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157 schema:name Department of Chemistry, Faculty of Sciences, Persian Gulf University, 75169, Bushehr, Iran
158 rdf:type schema:Organization
 




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