Donor ligand, basal ligand and solvent effects on the equilibrium constants of triphenylphosphinecobalt(III) Schiff base complexes with phosphite ligands View Full Text


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Article Info

DATE

2006-09

AUTHORS

M. Asadi, K. Mohammadi, A. H. Kiyanfar

ABSTRACT

The equilibrium constants and the thermodynamic parameters were spectrophotometrically measured for the 1:1 adduct formation of [Co(Salen)(PPh3)]ClO4.H2O, and [Co(7,7′-Me2Salen)(PPh3)]ClO4.H2O as acceptors, with P(OR)3 (R = methyl, ethyl, and i-propyl) as donors, in acetonitrile (CH3CN) and dimethylformamide (DMF) as solvents at constant ionic strength (I = 0.1 M NaClO4), and various temperatures (t = 10–50 °C). Our results revealed the following trends: stability of the cobalt(III) Schiff base complexes toward a given phosphite donor, [Co(7,7′-Me2Salen)(PPh3)]+ < [Co(Salen)(PPh3)]+; binding of the donors (phosphites) toward a given cobalt(III) Schiff base complex, P(OEt)3 > P(OMe)3 > P(O-iPr)3; influence of solvent on the stability of a given cobalt(III) Schiff base complex toward a given phosphite donor, CH3CN < DMF. More... »

PAGES

247-252

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf03247215

DOI

http://dx.doi.org/10.1007/bf03247215

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1036634326


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