Synthesis, structural elucidation and X-ray analysis of triphenyltin(IV) [2-(2,3-dimethylanilino)nicotinate] View Full Text


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Article Info

DATE

2009-12

AUTHORS

M. Hussain, M. Zaman, M. Hanif, M. Altaf, S. Ali, H. Stoeckli-Evans

ABSTRACT

Triphenyltin(IV) [2-(2,3-dimethylanilino)nicotinate] was prepared by the interaction of triphenyltin(IV) hydroxide and 2-(2,3-dimethylanilino)nicotinic acid in 1:1 ratio. This compound was characterized by elemental analyses, IR, multinuclear NMR spectroscopy (1H and 13C) and mass spectrometry. The structure of title compound was confirmed by single crystal X-ray crystallography. The coordination around the tin atom was studied both in solution and solid state. The geometry around tin is trigonal bipyramidal in solid state while it is tetrahedral in solution. The compound belongs to Monoclinic system, having space group P 21/c with unit cell dimensions a = 17.002(8) Å, b = 9.0793(3) Å, c = 18.2616(9) Å, α = 90 (°) β = 107.381(4) (°), γ = 90 (°). More... »

PAGES

769-775

References to SciGraph publications

  • 2008-03. Structural chemistry of organotin(IV) complexes in JOURNAL OF THE IRANIAN CHEMICAL SOCIETY
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/bf03246168

    DOI

    http://dx.doi.org/10.1007/bf03246168

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