Acetalization of aldehyde oils by catalysis with cation-exchange resins View Full Text


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Article Info

DATE

1967-01

AUTHORS

R. E. Beal, D. E. Anders, L. T. Black

ABSTRACT

Aldehyde oils produced on a pilot-plant scale gradually polymerized at room temperature and became extremely viscous or solidified in a few weeks. Initial viscosity level was maintained by converting the oils to acetals by use of a strong cation resin catalyst which, it was found, does not cause appreciable transesterification. Aldehyde conversion was determined by infrared absorbance at 2720 cm−1. The effects of amount of alcohol and resin on degree of conversion were studied. Storage studies indicate that the acetal oils must be protected from oxidation. More... »

PAGES

55-58

References to SciGraph publications

  • 1966-05. Infrared spectrophotometric procedure for determining azelaaldehydic acid derivatives in JOURNAL OF THE AMERICAN OIL CHEMISTS' SOCIETY
  • 1966-03. Removal of metal catalysts from aldehyde oils in JOURNAL OF THE AMERICAN OIL CHEMISTS' SOCIETY
  • 1965-03. Omega-formylalkanoates by ozonization of unsaturated fatty esters in JOURNAL OF THE AMERICAN OIL CHEMISTS' SOCIETY
  • 1966-03. Quantitative determination of unsaturation in oils by using an automatic-titrating hydrogenator in LIPIDS
  • 1962-11. Aldehydic materials by the ozonization of vegetable oils in JOURNAL OF THE AMERICAN OIL CHEMISTS' SOCIETY
  • 1961-07. Ozonization of soybean oil. The preparation and some properties of aldehyde oils in JOURNAL OF THE AMERICAN OIL CHEMISTS' SOCIETY
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    http://scigraph.springernature.com/pub.10.1007/bf02908374

    DOI

    http://dx.doi.org/10.1007/bf02908374

    DIMENSIONS

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