X-ray spectral study of the nature of electronic interactions in transition metal dithiocarbamates View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1998-11

AUTHORS

L. N. Mazalov, G. K. Parygina, É. S. Fomin, N. V. Bausk, S. B. Érenburg, S. M. Zemskova, S. V. Larionov

ABSTRACT

SKβ spectra are studied for a series of nickel(II), zinc(II), and cadmium(II) dithiocarbamate complexes. Model quantum chemical calculations of the electronic structure of planar chelate rings are reported. It is shown that the metal-ligand interaction forming a coordination bond between the dithiocarbamate ligand and the metal mainly involves the nonbonding n-electrons and the weakly bonding π-electrons localized on the sulfur atoms. More... »

PAGES

923-927

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf02903606

DOI

http://dx.doi.org/10.1007/bf02903606

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1039689890


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