Thermodynamic considerations in the analysis of phase stability: The role of interfacial equilibrium in the determination of phase diagrams by ... View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1987-08

AUTHORS

A. D. Romig

ABSTRACT

Although the time required for full equilibration may be too long to attain experimentally, equilibrium tie lines between coexisting phases can be determined from unequilibrated alloys and multiphase diffusion couples if the compositions of the two phases coexisting at the interface can be resolved, assuming that the interface is in “local equilibrium”. The capability to examine elemental segregation on a fine spatial scale allows for more rigorous testing of the assumption of local equilibrium at phase interfaces and for the determination of phase equilibria at temperatures below those accessible with more conventional techniques. More... »

PAGES

308-322

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf02869262

DOI

http://dx.doi.org/10.1007/bf02869262

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1049480900


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