Reactivity of the C-H bond of organic molecules with various structures in hydrogen abstraction by peroxyl radicals View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1997-01

AUTHORS

I. A. Opeida, A. F. Dmitruk, O. M. Zarechnaya

ABSTRACT

A model of an early transition state with charge transfer is proposed for calculation of the activation parameters of the abstraction of a hydrogen atom by peroxyl radicals from the molecules of organic compounds. It was shown that the compensation effect in this reaction is due to the fact that the change in the preexponential factor is determined by change in the vibrational component of the entropy of activation. More... »

PAGES

5-10

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf02764735

DOI

http://dx.doi.org/10.1007/bf02764735

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1027322850


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