Electrochemical conversions of pentaphenyl(methoxycarbonyl)cyclopentadiene derivatives View Full Text


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Article Info

DATE

2000-05

AUTHORS

A. A. Bumber, G. A. Dushenko, I. A. Profatilova, A. A. Arutyunyants, I. E. Mikhailov

ABSTRACT

Redox processes of fluctuating pentaphenyl(methoxycarbonyl)cyclopentadiene derivatives on platinum electrode in acetonitrile are studied by cyclic voltammetry. The reduction of derivatives of pentaphenylcyclopentadiene C5Ph5M yields a radical anion which decomposes to anion M- and stable radical C5Ph5•; the latter reduces to C5Ph5. In the first stage of oxidation of these compounds, a stable radical cation forms, with substituent M intact. Reduction of derivatives of pentamethoxycarbonylcyclopentadiene [C5(CO2Me)5]M yields a dianion. Such electrochemical behavior of fluctuating cyclopentadiene compounds reveals additional information on the mechanism of displacement of the element-centered substituents M in them More... »

PAGES

553-556

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf02757421

DOI

http://dx.doi.org/10.1007/bf02757421

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1054504428


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