Crystal and molecular structure of dicopper bis-(3-amino-5-methylisoxazole)tetraacetate [Cu2(μ-OCOCH3)2L2] View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2000-05

AUTHORS

D. A. Garnovskii, A. S. Antsyshkina, G. G. Sadikov, V. P. Kurbatov, A. Yu. Eliseeva, I. S. Vasilchenko, A. D. Garnovskii

ABSTRACT

It was established by X-ray diffraction analysis that in the dimer complex of 3-amino-5-methylisoxazole (L) [ Cu2(μ-OCOCH3)4L2 ] the coordination bond is localized at the endocyclic pyridine type N atom. Arguments are given against other possible types of coordination in aminoisoxazole complexes conjectured from IR spectroscopy data in a number of publications. The dimer structure of the complex agrees with antiferromagnetic data (2J = -280 cm-1 ). More... »

PAGES

468-475

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf02742007

DOI

http://dx.doi.org/10.1007/bf02742007

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1010252115


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