Structure of the metastable modification of iron(III) oxide View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2000-05

AUTHORS

E. B. Burgina, G. N. Kustova, S. V. Tsybulya, G. N. Kryukova, G. S. Litvak, L. A. Isupova, V. A. Sadykov

ABSTRACT

A new metastable modification of iron(III) oxide — protohematite — has_been studied. According to the X-ray diffractogram, protohematite (R3c) is identified as hematite (R3c) but characterized by other selection rules for IR and Raman active vibrations. Protohematite does not possess mechanical stability. The protohematite-hematite phase transition is initiated by heating above 900°C, or by pressure application, or by mechanochemical activation. The higher catalytic activity of protohematite compared to hematite may be explained by its structural features, namely, by lowered symmetry of the oxygen sublattice and by the effective tetrahedral environment of some iron cations. More... »

PAGES

396-402

References to SciGraph publications

  • 1986-09. Nature of protohaematite and hydrohaematite in JOURNAL OF MATERIALS SCIENCE LETTERS
  • 1992-02. Vibrational spectroscopic investigation of the goethite thermal decomposition products in PHYSICS AND CHEMISTRY OF MINERALS
  • 1985-12. Structural and spectroscopic characteristics of synthetic hydrohaematite in JOURNAL OF MATERIALS SCIENCE
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/bf02741997

    DOI

    http://dx.doi.org/10.1007/bf02741997

    DIMENSIONS

    https://app.dimensions.ai/details/publication/pub.1011729884


    Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
    Incoming Citations Browse incoming citations for this publication using opencitations.net

    JSON-LD is the canonical representation for SciGraph data.

    TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

    [
      {
        "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
        "about": [
          {
            "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
            "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
            "name": "Chemical Sciences", 
            "type": "DefinedTerm"
          }, 
          {
            "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0302", 
            "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
            "name": "Inorganic Chemistry", 
            "type": "DefinedTerm"
          }
        ], 
        "author": [
          {
            "affiliation": {
              "alternateName": "G. K. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, USSR", 
              "id": "http://www.grid.ac/institutes/grid.4886.2", 
              "name": [
                "G. K. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, USSR"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Burgina", 
            "givenName": "E. B.", 
            "id": "sg:person.011163453051.19", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011163453051.19"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "G. K. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, USSR", 
              "id": "http://www.grid.ac/institutes/grid.4886.2", 
              "name": [
                "G. K. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, USSR"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Kustova", 
            "givenName": "G. N.", 
            "id": "sg:person.012630233547.03", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012630233547.03"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "G. K. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, USSR", 
              "id": "http://www.grid.ac/institutes/grid.4886.2", 
              "name": [
                "G. K. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, USSR"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Tsybulya", 
            "givenName": "S. V.", 
            "id": "sg:person.011252704043.40", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011252704043.40"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "G. K. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, USSR", 
              "id": "http://www.grid.ac/institutes/grid.4886.2", 
              "name": [
                "G. K. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, USSR"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Kryukova", 
            "givenName": "G. N.", 
            "id": "sg:person.016350770255.00", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016350770255.00"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "G. K. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, USSR", 
              "id": "http://www.grid.ac/institutes/grid.4886.2", 
              "name": [
                "G. K. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, USSR"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Litvak", 
            "givenName": "G. S.", 
            "id": "sg:person.07530237133.45", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07530237133.45"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "G. K. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, USSR", 
              "id": "http://www.grid.ac/institutes/grid.4886.2", 
              "name": [
                "G. K. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, USSR"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Isupova", 
            "givenName": "L. A.", 
            "id": "sg:person.013034675361.13", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013034675361.13"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "G. K. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, USSR", 
              "id": "http://www.grid.ac/institutes/grid.4886.2", 
              "name": [
                "G. K. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, USSR"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Sadykov", 
            "givenName": "V. A.", 
            "id": "sg:person.07571716351.55", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07571716351.55"
            ], 
            "type": "Person"
          }
        ], 
        "citation": [
          {
            "id": "sg:pub.10.1007/bf00199419", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1011506004", 
              "https://doi.org/10.1007/bf00199419"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/bf01729267", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1002425194", 
              "https://doi.org/10.1007/bf01729267"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/bf00559329", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1014333090", 
              "https://doi.org/10.1007/bf00559329"
            ], 
            "type": "CreativeWork"
          }
        ], 
        "datePublished": "2000-05", 
        "datePublishedReg": "2000-05-01", 
        "description": "A new metastable modification of iron(III) oxide \u2014 protohematite \u2014 has_been studied. According to the X-ray diffractogram, protohematite (R3c) is identified as hematite (R3c) but characterized by other selection rules for IR and Raman active vibrations. Protohematite does not possess mechanical stability. The protohematite-hematite phase transition is initiated by heating above 900\u00b0C, or by pressure application, or by mechanochemical activation. The higher catalytic activity of protohematite compared to hematite may be explained by its structural features, namely, by lowered symmetry of the oxygen sublattice and by the effective tetrahedral environment of some iron cations.", 
        "genre": "article", 
        "id": "sg:pub.10.1007/bf02741997", 
        "inLanguage": "en", 
        "isAccessibleForFree": false, 
        "isPartOf": [
          {
            "id": "sg:journal.1135923", 
            "issn": [
              "0022-4766", 
              "2542-0976"
            ], 
            "name": "Journal of Structural Chemistry", 
            "publisher": "Springer Nature", 
            "type": "Periodical"
          }, 
          {
            "issueNumber": "3", 
            "type": "PublicationIssue"
          }, 
          {
            "type": "PublicationVolume", 
            "volumeNumber": "41"
          }
        ], 
        "keywords": [
          "mechanical stability", 
          "mechanochemical activation", 
          "high catalytic activity", 
          "active vibrations", 
          "ray diffractograms", 
          "pressure application", 
          "iron cations", 
          "vibration", 
          "catalytic activity", 
          "oxygen sublattice", 
          "phase transition", 
          "oxide", 
          "Raman-active vibrations", 
          "diffractograms", 
          "stability", 
          "hematite", 
          "applications", 
          "modification", 
          "structure", 
          "new metastable modification", 
          "protohematite", 
          "structural features", 
          "metastable modification", 
          "environment", 
          "transition", 
          "features", 
          "sublattice", 
          "selection rules", 
          "rules", 
          "symmetry", 
          "cations", 
          "IR", 
          "tetrahedral environment", 
          "activity", 
          "activation"
        ], 
        "name": "Structure of the metastable modification of iron(III) oxide", 
        "pagination": "396-402", 
        "productId": [
          {
            "name": "dimensions_id", 
            "type": "PropertyValue", 
            "value": [
              "pub.1011729884"
            ]
          }, 
          {
            "name": "doi", 
            "type": "PropertyValue", 
            "value": [
              "10.1007/bf02741997"
            ]
          }
        ], 
        "sameAs": [
          "https://doi.org/10.1007/bf02741997", 
          "https://app.dimensions.ai/details/publication/pub.1011729884"
        ], 
        "sdDataset": "articles", 
        "sdDatePublished": "2022-05-20T07:21", 
        "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
        "sdPublisher": {
          "name": "Springer Nature - SN SciGraph project", 
          "type": "Organization"
        }, 
        "sdSource": "s3://com-springernature-scigraph/baseset/20220519/entities/gbq_results/article/article_331.jsonl", 
        "type": "ScholarlyArticle", 
        "url": "https://doi.org/10.1007/bf02741997"
      }
    ]
     

    Download the RDF metadata as:  json-ld nt turtle xml License info

    HOW TO GET THIS DATA PROGRAMMATICALLY:

    JSON-LD is a popular format for linked data which is fully compatible with JSON.

    curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf02741997'

    N-Triples is a line-based linked data format ideal for batch operations.

    curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf02741997'

    Turtle is a human-readable linked data format.

    curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf02741997'

    RDF/XML is a standard XML format for linked data.

    curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf02741997'


     

    This table displays all metadata directly associated to this object as RDF triples.

    147 TRIPLES      22 PREDICATES      64 URIs      53 LITERALS      6 BLANK NODES

    Subject Predicate Object
    1 sg:pub.10.1007/bf02741997 schema:about anzsrc-for:03
    2 anzsrc-for:0302
    3 schema:author Ne6e62d7d50a647e7ae7d2cae44f0a8d4
    4 schema:citation sg:pub.10.1007/bf00199419
    5 sg:pub.10.1007/bf00559329
    6 sg:pub.10.1007/bf01729267
    7 schema:datePublished 2000-05
    8 schema:datePublishedReg 2000-05-01
    9 schema:description A new metastable modification of iron(III) oxide — protohematite — has_been studied. According to the X-ray diffractogram, protohematite (R3c) is identified as hematite (R3c) but characterized by other selection rules for IR and Raman active vibrations. Protohematite does not possess mechanical stability. The protohematite-hematite phase transition is initiated by heating above 900°C, or by pressure application, or by mechanochemical activation. The higher catalytic activity of protohematite compared to hematite may be explained by its structural features, namely, by lowered symmetry of the oxygen sublattice and by the effective tetrahedral environment of some iron cations.
    10 schema:genre article
    11 schema:inLanguage en
    12 schema:isAccessibleForFree false
    13 schema:isPartOf N7a90d1aa217a437294ad923019346a7e
    14 Ne5d6930ecf91479ca66126a9dd95fc3b
    15 sg:journal.1135923
    16 schema:keywords IR
    17 Raman-active vibrations
    18 activation
    19 active vibrations
    20 activity
    21 applications
    22 catalytic activity
    23 cations
    24 diffractograms
    25 environment
    26 features
    27 hematite
    28 high catalytic activity
    29 iron cations
    30 mechanical stability
    31 mechanochemical activation
    32 metastable modification
    33 modification
    34 new metastable modification
    35 oxide
    36 oxygen sublattice
    37 phase transition
    38 pressure application
    39 protohematite
    40 ray diffractograms
    41 rules
    42 selection rules
    43 stability
    44 structural features
    45 structure
    46 sublattice
    47 symmetry
    48 tetrahedral environment
    49 transition
    50 vibration
    51 schema:name Structure of the metastable modification of iron(III) oxide
    52 schema:pagination 396-402
    53 schema:productId N4ab27049171e4e7a9be7d6268218c4af
    54 Na825ca6bb15c48739974aec9a0730b89
    55 schema:sameAs https://app.dimensions.ai/details/publication/pub.1011729884
    56 https://doi.org/10.1007/bf02741997
    57 schema:sdDatePublished 2022-05-20T07:21
    58 schema:sdLicense https://scigraph.springernature.com/explorer/license/
    59 schema:sdPublisher N9e7f677ec77f483c92d4b40a8f1da6c3
    60 schema:url https://doi.org/10.1007/bf02741997
    61 sgo:license sg:explorer/license/
    62 sgo:sdDataset articles
    63 rdf:type schema:ScholarlyArticle
    64 N13103ee8ac9646888fd7b482a7735f8c rdf:first sg:person.011252704043.40
    65 rdf:rest Na3c1043b8fda41e6a8878a088a746275
    66 N4ab27049171e4e7a9be7d6268218c4af schema:name doi
    67 schema:value 10.1007/bf02741997
    68 rdf:type schema:PropertyValue
    69 N60d7bd535b7842e1b5b0729ac3d6fae6 rdf:first sg:person.07571716351.55
    70 rdf:rest rdf:nil
    71 N7a90d1aa217a437294ad923019346a7e schema:volumeNumber 41
    72 rdf:type schema:PublicationVolume
    73 N9d0c8824396c483593e21378a021163b rdf:first sg:person.012630233547.03
    74 rdf:rest N13103ee8ac9646888fd7b482a7735f8c
    75 N9e7f677ec77f483c92d4b40a8f1da6c3 schema:name Springer Nature - SN SciGraph project
    76 rdf:type schema:Organization
    77 Na3c1043b8fda41e6a8878a088a746275 rdf:first sg:person.016350770255.00
    78 rdf:rest Ndbba12b8edab4b66a6cbc9f200814364
    79 Na825ca6bb15c48739974aec9a0730b89 schema:name dimensions_id
    80 schema:value pub.1011729884
    81 rdf:type schema:PropertyValue
    82 Ndbba12b8edab4b66a6cbc9f200814364 rdf:first sg:person.07530237133.45
    83 rdf:rest Nfd90808e436446318b7c9f29f252d272
    84 Ne5d6930ecf91479ca66126a9dd95fc3b schema:issueNumber 3
    85 rdf:type schema:PublicationIssue
    86 Ne6e62d7d50a647e7ae7d2cae44f0a8d4 rdf:first sg:person.011163453051.19
    87 rdf:rest N9d0c8824396c483593e21378a021163b
    88 Nfd90808e436446318b7c9f29f252d272 rdf:first sg:person.013034675361.13
    89 rdf:rest N60d7bd535b7842e1b5b0729ac3d6fae6
    90 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
    91 schema:name Chemical Sciences
    92 rdf:type schema:DefinedTerm
    93 anzsrc-for:0302 schema:inDefinedTermSet anzsrc-for:
    94 schema:name Inorganic Chemistry
    95 rdf:type schema:DefinedTerm
    96 sg:journal.1135923 schema:issn 0022-4766
    97 2542-0976
    98 schema:name Journal of Structural Chemistry
    99 schema:publisher Springer Nature
    100 rdf:type schema:Periodical
    101 sg:person.011163453051.19 schema:affiliation grid-institutes:grid.4886.2
    102 schema:familyName Burgina
    103 schema:givenName E. B.
    104 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011163453051.19
    105 rdf:type schema:Person
    106 sg:person.011252704043.40 schema:affiliation grid-institutes:grid.4886.2
    107 schema:familyName Tsybulya
    108 schema:givenName S. V.
    109 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011252704043.40
    110 rdf:type schema:Person
    111 sg:person.012630233547.03 schema:affiliation grid-institutes:grid.4886.2
    112 schema:familyName Kustova
    113 schema:givenName G. N.
    114 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012630233547.03
    115 rdf:type schema:Person
    116 sg:person.013034675361.13 schema:affiliation grid-institutes:grid.4886.2
    117 schema:familyName Isupova
    118 schema:givenName L. A.
    119 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013034675361.13
    120 rdf:type schema:Person
    121 sg:person.016350770255.00 schema:affiliation grid-institutes:grid.4886.2
    122 schema:familyName Kryukova
    123 schema:givenName G. N.
    124 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016350770255.00
    125 rdf:type schema:Person
    126 sg:person.07530237133.45 schema:affiliation grid-institutes:grid.4886.2
    127 schema:familyName Litvak
    128 schema:givenName G. S.
    129 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07530237133.45
    130 rdf:type schema:Person
    131 sg:person.07571716351.55 schema:affiliation grid-institutes:grid.4886.2
    132 schema:familyName Sadykov
    133 schema:givenName V. A.
    134 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07571716351.55
    135 rdf:type schema:Person
    136 sg:pub.10.1007/bf00199419 schema:sameAs https://app.dimensions.ai/details/publication/pub.1011506004
    137 https://doi.org/10.1007/bf00199419
    138 rdf:type schema:CreativeWork
    139 sg:pub.10.1007/bf00559329 schema:sameAs https://app.dimensions.ai/details/publication/pub.1014333090
    140 https://doi.org/10.1007/bf00559329
    141 rdf:type schema:CreativeWork
    142 sg:pub.10.1007/bf01729267 schema:sameAs https://app.dimensions.ai/details/publication/pub.1002425194
    143 https://doi.org/10.1007/bf01729267
    144 rdf:type schema:CreativeWork
    145 grid-institutes:grid.4886.2 schema:alternateName G. K. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, USSR
    146 schema:name G. K. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, USSR
    147 rdf:type schema:Organization
     




    Preview window. Press ESC to close (or click here)


    ...