A triad of rhenium-mediated transformations View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2003-10

AUTHORS

Jaydip Gangopadhyay, Samir Das, Suman Sengupta, Indranil Chakraborty, Animesh Chakravorty

ABSTRACT

The title transformations are oxygen atom transfer, twin isomerization and regiospecific imine oxidation.Bispyridyldiazole ligands have furnished new oxygen atom transfer reagents of coordination type ReVOCl3(NN) which undergo a slower transfer to PPh3 than the corresponding azole reagents. The rate of twin isomerization (linkage and geometrical) of meridional azole complexes of coordination type ReIII(OPnP)Cl3(NN) to facial ReIII(PnPO)Cl3(NN) decreases rapidly asn increases in the interval 1–4 (PnP is Ph2P(CH2)nPPh2). An α-diimine chelate of type ReV(NPh)Cl3(NN) is shown to undergo facile oxidation to the corresponding iminoamide complex ReVI(NPh)Cl3(NN) upon treating with dilute nitric acid. The reaction proceeds via regiospecific nucleophilic addition of waterto the more polarized imine function. More... »

PAGES

333-339

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf02708226

DOI

http://dx.doi.org/10.1007/bf02708226

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1026795284


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Department of Inorganic Chemistry, Indian Association for the Cultivation of Science, 700 032, Kolkata, India", 
          "id": "http://www.grid.ac/institutes/grid.417929.0", 
          "name": [
            "Department of Inorganic Chemistry, Indian Association for the Cultivation of Science, 700 032, Kolkata, India"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Gangopadhyay", 
        "givenName": "Jaydip", 
        "id": "sg:person.0653414265.52", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0653414265.52"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Department of Inorganic Chemistry, Indian Association for the Cultivation of Science, 700 032, Kolkata, India", 
          "id": "http://www.grid.ac/institutes/grid.417929.0", 
          "name": [
            "Department of Inorganic Chemistry, Indian Association for the Cultivation of Science, 700 032, Kolkata, India"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Das", 
        "givenName": "Samir", 
        "id": "sg:person.016220163636.48", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016220163636.48"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Department of Inorganic Chemistry, Indian Association for the Cultivation of Science, 700 032, Kolkata, India", 
          "id": "http://www.grid.ac/institutes/grid.417929.0", 
          "name": [
            "Department of Inorganic Chemistry, Indian Association for the Cultivation of Science, 700 032, Kolkata, India"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Sengupta", 
        "givenName": "Suman", 
        "id": "sg:person.0767642665.33", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0767642665.33"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Department of Inorganic Chemistry, Indian Association for the Cultivation of Science, 700 032, Kolkata, India", 
          "id": "http://www.grid.ac/institutes/grid.417929.0", 
          "name": [
            "Department of Inorganic Chemistry, Indian Association for the Cultivation of Science, 700 032, Kolkata, India"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Chakraborty", 
        "givenName": "Indranil", 
        "id": "sg:person.01066544241.16", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01066544241.16"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Jawaharlal Nehru Centre for Advanced Scientific Research, 560 064, Bangalore, India", 
          "id": "http://www.grid.ac/institutes/grid.419636.f", 
          "name": [
            "Department of Inorganic Chemistry, Indian Association for the Cultivation of Science, 700 032, Kolkata, India", 
            "Jawaharlal Nehru Centre for Advanced Scientific Research, 560 064, Bangalore, India"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Chakravorty", 
        "givenName": "Animesh", 
        "id": "sg:person.012503014436.35", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012503014436.35"
        ], 
        "type": "Person"
      }
    ], 
    "datePublished": "2003-10", 
    "datePublishedReg": "2003-10-01", 
    "description": "The title transformations are oxygen atom transfer, twin isomerization and regiospecific imine oxidation.Bispyridyldiazole ligands have furnished new oxygen atom transfer reagents of coordination type ReVOCl3(NN) which undergo a slower transfer to PPh3 than the corresponding azole reagents. The rate of twin isomerization (linkage and geometrical) of meridional azole complexes of coordination type ReIII(OPnP)Cl3(NN) to facial ReIII(PnPO)Cl3(NN) decreases rapidly asn increases in the interval 1\u20134 (PnP is Ph2P(CH2)nPPh2). An \u03b1-diimine chelate of type ReV(NPh)Cl3(NN) is shown to undergo facile oxidation to the corresponding iminoamide complex ReVI(NPh)Cl3(NN) upon treating with dilute nitric acid. The reaction proceeds via regiospecific nucleophilic addition of waterto the more polarized imine function.", 
    "genre": "article", 
    "id": "sg:pub.10.1007/bf02708226", 
    "inLanguage": "en", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1048512", 
        "issn": [
          "0253-4134", 
          "0973-7103"
        ], 
        "name": "Journal of Chemical Sciences", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "5-6", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "115"
      }
    ], 
    "keywords": [
      "coordination type", 
      "oxygen atom transfer reagents", 
      "atom transfer reagents", 
      "oxygen atom transfer", 
      "dilute nitric acid", 
      "diimine chelate", 
      "transfer reagent", 
      "facile oxidation", 
      "atom transfer", 
      "imine oxidation", 
      "azole complexes", 
      "nucleophilic addition", 
      "imine function", 
      "nitric acid", 
      "title transformation", 
      "isomerization", 
      "oxidation", 
      "reagents", 
      "slow transfer", 
      "PPh3", 
      "chelates", 
      "ligands", 
      "reaction", 
      "complexes", 
      "transfer", 
      "acid", 
      "transformation", 
      "asn increases", 
      "types", 
      "addition", 
      "triad", 
      "increase", 
      "rate", 
      "function", 
      "twin isomerization", 
      "regiospecific imine oxidation", 
      "Bispyridyldiazole ligands", 
      "new oxygen atom transfer reagents", 
      "corresponding azole reagents", 
      "azole reagents", 
      "meridional azole complexes", 
      "regiospecific nucleophilic addition", 
      "waterto", 
      "polarized imine function", 
      "rhenium-mediated transformations"
    ], 
    "name": "A triad of rhenium-mediated transformations", 
    "pagination": "333-339", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1026795284"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/bf02708226"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/bf02708226", 
      "https://app.dimensions.ai/details/publication/pub.1026795284"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2021-11-01T18:06", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20211101/entities/gbq_results/article/article_370.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1007/bf02708226"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf02708226'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf02708226'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf02708226'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf02708226'


 

This table displays all metadata directly associated to this object as RDF triples.

131 TRIPLES      21 PREDICATES      70 URIs      63 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/bf02708226 schema:about anzsrc-for:03
2 schema:author Nd69b20de87484a63ab49190588f54be9
3 schema:datePublished 2003-10
4 schema:datePublishedReg 2003-10-01
5 schema:description The title transformations are oxygen atom transfer, twin isomerization and regiospecific imine oxidation.Bispyridyldiazole ligands have furnished new oxygen atom transfer reagents of coordination type ReVOCl3(NN) which undergo a slower transfer to PPh3 than the corresponding azole reagents. The rate of twin isomerization (linkage and geometrical) of meridional azole complexes of coordination type ReIII(OPnP)Cl3(NN) to facial ReIII(PnPO)Cl3(NN) decreases rapidly asn increases in the interval 1–4 (PnP is Ph2P(CH2)nPPh2). An α-diimine chelate of type ReV(NPh)Cl3(NN) is shown to undergo facile oxidation to the corresponding iminoamide complex ReVI(NPh)Cl3(NN) upon treating with dilute nitric acid. The reaction proceeds via regiospecific nucleophilic addition of waterto the more polarized imine function.
6 schema:genre article
7 schema:inLanguage en
8 schema:isAccessibleForFree false
9 schema:isPartOf N9a6981d7eb7a43a3a5f5881d82ad0291
10 Nc245f31e08e443c19800dec52c444d2b
11 sg:journal.1048512
12 schema:keywords Bispyridyldiazole ligands
13 PPh3
14 acid
15 addition
16 asn increases
17 atom transfer
18 atom transfer reagents
19 azole complexes
20 azole reagents
21 chelates
22 complexes
23 coordination type
24 corresponding azole reagents
25 diimine chelate
26 dilute nitric acid
27 facile oxidation
28 function
29 imine function
30 imine oxidation
31 increase
32 isomerization
33 ligands
34 meridional azole complexes
35 new oxygen atom transfer reagents
36 nitric acid
37 nucleophilic addition
38 oxidation
39 oxygen atom transfer
40 oxygen atom transfer reagents
41 polarized imine function
42 rate
43 reaction
44 reagents
45 regiospecific imine oxidation
46 regiospecific nucleophilic addition
47 rhenium-mediated transformations
48 slow transfer
49 title transformation
50 transfer
51 transfer reagent
52 transformation
53 triad
54 twin isomerization
55 types
56 waterto
57 schema:name A triad of rhenium-mediated transformations
58 schema:pagination 333-339
59 schema:productId N2314f11270fe4bc9abfc264a242cfcaf
60 N787c0e8cce6f4f1da44511cf1db818b8
61 schema:sameAs https://app.dimensions.ai/details/publication/pub.1026795284
62 https://doi.org/10.1007/bf02708226
63 schema:sdDatePublished 2021-11-01T18:06
64 schema:sdLicense https://scigraph.springernature.com/explorer/license/
65 schema:sdPublisher Ne0b8a17a7c4f4e779bca9f9646a2066e
66 schema:url https://doi.org/10.1007/bf02708226
67 sgo:license sg:explorer/license/
68 sgo:sdDataset articles
69 rdf:type schema:ScholarlyArticle
70 N21c33be71ef744aa9989f925e313161b rdf:first sg:person.016220163636.48
71 rdf:rest N679a093b2bd640d3a765af8d099908bd
72 N2314f11270fe4bc9abfc264a242cfcaf schema:name dimensions_id
73 schema:value pub.1026795284
74 rdf:type schema:PropertyValue
75 N679a093b2bd640d3a765af8d099908bd rdf:first sg:person.0767642665.33
76 rdf:rest N89bebf4b58594be386cf958d80ab5813
77 N787c0e8cce6f4f1da44511cf1db818b8 schema:name doi
78 schema:value 10.1007/bf02708226
79 rdf:type schema:PropertyValue
80 N89bebf4b58594be386cf958d80ab5813 rdf:first sg:person.01066544241.16
81 rdf:rest Nd97b3b5e17e04e09a8b1365e69975b68
82 N9a6981d7eb7a43a3a5f5881d82ad0291 schema:volumeNumber 115
83 rdf:type schema:PublicationVolume
84 Nc245f31e08e443c19800dec52c444d2b schema:issueNumber 5-6
85 rdf:type schema:PublicationIssue
86 Nd69b20de87484a63ab49190588f54be9 rdf:first sg:person.0653414265.52
87 rdf:rest N21c33be71ef744aa9989f925e313161b
88 Nd97b3b5e17e04e09a8b1365e69975b68 rdf:first sg:person.012503014436.35
89 rdf:rest rdf:nil
90 Ne0b8a17a7c4f4e779bca9f9646a2066e schema:name Springer Nature - SN SciGraph project
91 rdf:type schema:Organization
92 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
93 schema:name Chemical Sciences
94 rdf:type schema:DefinedTerm
95 sg:journal.1048512 schema:issn 0253-4134
96 0973-7103
97 schema:name Journal of Chemical Sciences
98 schema:publisher Springer Nature
99 rdf:type schema:Periodical
100 sg:person.01066544241.16 schema:affiliation grid-institutes:grid.417929.0
101 schema:familyName Chakraborty
102 schema:givenName Indranil
103 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01066544241.16
104 rdf:type schema:Person
105 sg:person.012503014436.35 schema:affiliation grid-institutes:grid.419636.f
106 schema:familyName Chakravorty
107 schema:givenName Animesh
108 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012503014436.35
109 rdf:type schema:Person
110 sg:person.016220163636.48 schema:affiliation grid-institutes:grid.417929.0
111 schema:familyName Das
112 schema:givenName Samir
113 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016220163636.48
114 rdf:type schema:Person
115 sg:person.0653414265.52 schema:affiliation grid-institutes:grid.417929.0
116 schema:familyName Gangopadhyay
117 schema:givenName Jaydip
118 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0653414265.52
119 rdf:type schema:Person
120 sg:person.0767642665.33 schema:affiliation grid-institutes:grid.417929.0
121 schema:familyName Sengupta
122 schema:givenName Suman
123 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0767642665.33
124 rdf:type schema:Person
125 grid-institutes:grid.417929.0 schema:alternateName Department of Inorganic Chemistry, Indian Association for the Cultivation of Science, 700 032, Kolkata, India
126 schema:name Department of Inorganic Chemistry, Indian Association for the Cultivation of Science, 700 032, Kolkata, India
127 rdf:type schema:Organization
128 grid-institutes:grid.419636.f schema:alternateName Jawaharlal Nehru Centre for Advanced Scientific Research, 560 064, Bangalore, India
129 schema:name Department of Inorganic Chemistry, Indian Association for the Cultivation of Science, 700 032, Kolkata, India
130 Jawaharlal Nehru Centre for Advanced Scientific Research, 560 064, Bangalore, India
131 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...