Influence of chain length of tertiary amines on extractability and chemical interactions in reactive extraction of succinic acid View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2004-03

AUTHORS

Yeon Ki Hong, Won Hi Hong

ABSTRACT

Reactive extraction of succinic acid from aqueous solutions with various tertiary amines dissolved in 1-octanol and in n-heptane has been studied as a function of the chain length of the tertiary amine. In the tertiary amine extractants in 1-octanol, the extractabilities of tertiary amines were proportional to their chain length. But, in n-heptane, the extractabilities of tertiary amines decreased with their chain length. In order to analyze chemical interactions involved in the complexation of succinic acid with amine extractants in 1-octanol and n-heptane, infrared (IR) spectroscopy was used. From IR spectroscopy, it was found that the difference of extractability in 1-octanol and in n-heptane was mainly due to the different degree of intramolecular hydrogen bonding of succinic acid with the polarity of diluents. And the possible stoichiometry of acid-amine-diluent complex was predicted as (1,1), (2,1), (1,1,1). More... »

PAGES

488-493

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf02705439

DOI

http://dx.doi.org/10.1007/bf02705439

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1042586688


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