Macrokinetics of thermal explosion in a niobium-aluminum system. II. Phase-formation dynamics View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2000-03

AUTHORS

E. B. Pis’menskaya, A. S. Rogachev, V. I. Ponomarev

ABSTRACT

The thermal explosion in a gas-free mixture of metal powders has been studied for the first time using the method of dynamic x-ray structural analysis. The dynamics of formation of new crystalline phases at all stages of the process is determined. It is shown that melting of aluminum is followed by dissolution of niobium in the melt and crystallization of the intermediate product NbAl3, and the melt does not wet niobium particles. A dramatic improvement in wetting is observed at a temperature of ≈ 1040 K (apparently, due to the destruction of oxide films). This results in a thermal explosion, and the Nb2Al phase is formed. The reaction during the thermal explosion also follows the dissolution-crystallization mechanism. More... »

PAGES

198-203

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf02699360

DOI

http://dx.doi.org/10.1007/bf02699360

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1051868581


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