Evidence for theπ-d interaction comparing magneto-resistance in (EDT-DSDTFVO)2X, X=FeCl4, GaCl4 View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2006-02

AUTHORS

Lin Li, Syuma Yasuzuka, Yufeng Weng, Keiichi Yokogawa, Tsutomu Fujimoto, Toyonari Sugimoto, Hideki Fujiwara, Toshiki Hayashi, Takashi Hiraoka, Keizo Murata

ABSTRACT

We have measured the electrical resistivities and magnetoresistances (MR) of (EDT-DSDTFVO)2X (X=FeCl4, GaCl4), where EDT-DSDTFVO stands for ethylenedithiodiselenadithiafulvalenothioquinone-1,3-dithiolemethide. These materials undergo gradual metal-insulator transitions at Tmin=52 K for FeCl4-salt and Tmin=30 K for GaCl4-salt, respectively. In spite of the similarity of the temperature dependence of the resistivity and its pressure effect, MR of both salts exhibit a clear contrast, i.e. FeCl4-salt shows negative and GaCl4, positive. Origin of the difference in the sign of MR between these salts are discussed in terms of the existence of π-d interaction. More... »

PAGES

469-472

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf02679547

DOI

http://dx.doi.org/10.1007/bf02679547

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1003307201


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141 rdf:type schema:Organization
142 https://www.grid.ac/institutes/grid.261455.1 schema:alternateName Osaka Prefecture University
143 schema:name Department of Chemistry, Graduate School of Science, Osaka Prefecture University, 599-8570, Osaka, Japan
144 rdf:type schema:Organization
145 https://www.grid.ac/institutes/grid.419082.6 schema:alternateName Japan Science and Technology Agency
146 schema:name CREST-JST, 332-0012, Saitama, Japan
147 Department of Chemistry, Graduate School of Science, Osaka Prefecture University, 599-8570, Osaka, Japan
148 rdf:type schema:Organization
 




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