Oxidative stability of purified canola oil triacylglycerols with altered fatty acid compositions as affected by triacylglycerol composition and structure View Full Text


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Article Info

DATE

1994-10

AUTHORS

W. E. Neff, T. L. Mounts, W. M. Rinsch, H. Konishi, M. A. El-Agaimy

ABSTRACT

Canola oil triacylglycerols from genetically modified canola lines (InterMountain Canola Co., Cinnaminson, NJ) have been evaluated for their photooxidative and autoxidative stabilities, as influenced by their fatty acid compositions and their triacylglycerol compositions and structures. Purified canola oil triacylglycerols were oxidized in duplicate in fluorescent light at 25°C and in the dark at 60°C under oxygen, and their oxidative deterioration with time was monitored by determining colorimetric peroxide values. Also monitored with time, oxidation products were determined by reversed-phase high-performance liquid chromatography with ultraviolet absorbance detection. Total volatiles, generated by thermal decomposition of the oxidized triacylglycerols, were quantitated by static-head-space gas chromatography. These experimental parameters were statistically correlated with predicted oxidizability, fatty acid composition, position of fatty acids on glycerol carbons and triacylglycerol composition. Oxidative deterioration of canola triacylglycerols correlated negatively with oleic acid composition, with oleic acid content at carbon 2 and with trioleoylglycerol content of the oil. Deterioration was positively correlated with the amount of linolenic acid on nonspecific locations on glycerol carbons 1,2 and 3, the amount of linoleic acid on glycerol carbon 2 and withsn-oleoyllinoleoyllinolenoyl glycerol content. Differences in character or quantity of volatile product and triacylglycerol hydroperoxides were low, whether generated during autoxidation or photooxidation of the canola triacylglycerols. More... »

PAGES

1101-1109

References to SciGraph publications

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  • 1987-02. Effects of β-carotene on light stability of soybean oil in JOURNAL OF THE AMERICAN OIL CHEMISTS' SOCIETY
  • 1991-06. Effect of heat treatments on canola press oils. II. Oxidative stability in JOURNAL OF THE AMERICAN OIL CHEMISTS' SOCIETY
  • 1992-06. Characterization of chlorophyll pigments present in canola seed, meal and oil in JOURNAL OF THE AMERICAN OIL CHEMISTS' SOCIETY
  • 1989-04. Flavor and oxidative stability of soybean, sunflower and low erucic acid rapeseed oils in JOURNAL OF THE AMERICAN OIL CHEMISTS' SOCIETY
  • 1992-06. Oxidative stability of soybean oils with altered fatty acid compositions in JOURNAL OF THE AMERICAN OIL CHEMISTS' SOCIETY
  • 1993-05. Comparison of oxidative stability of high- and normal-oleic peanut oils in JOURNAL OF THE AMERICAN OIL CHEMISTS' SOCIETY
  • 1988-04. Effect of altered fatty acid composition on soybean oil stability in JOURNAL OF THE AMERICAN OIL CHEMISTS' SOCIETY
  • 1990-03. A new variety of low-linolenic rapeseed oil; Characteristics and room-odor tests in JOURNAL OF THE AMERICAN OIL CHEMISTS' SOCIETY
  • 1977-12. Analysis of autoxidized fats by gas chromatography-mass spectrometry: III. Methyl linolenate in LIPIDS
  • 1992-02. Effect of triacylglycerol composition and structures on oxidative stability of oils from selected soybean germplasm in JOURNAL OF THE AMERICAN OIL CHEMISTS' SOCIETY
  • 1993-02. Photooxidation of soybean oils as affected by triacylglycerol composition and structure in JOURNAL OF THE AMERICAN OIL CHEMISTS' SOCIETY
  • 1989-08. Stability of low linolenic acid canola oil to frying temperatures in JOURNAL OF THE AMERICAN OIL CHEMISTS' SOCIETY
  • 1987-05. The kinetics of the autoxidation of polyunsaturated fatty acids in LIPIDS
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    http://scigraph.springernature.com/pub.10.1007/bf02675903

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    http://dx.doi.org/10.1007/bf02675903

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