Solidification of undercooled Sn-Sb peritectic alloys: Part II. Heterogeneous nucleation View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1991-03

AUTHORS

W. P. Allen, J. H. Perepezko

ABSTRACT

The undercooling behavior of fine droplet samples of Sn-rich, Sn-Sb alloys was investigated using differential thermal analysis (DTA). Undercooling levels measured during cooling from the liquid state follow the trend of the intermetallic phase liquidus, suggesting that solidification of all droplet samples (even those which solidify to yield a supersaturatedβ-tin product) was probably initiated with formation of primary intermetallic phase. Heterogeneous nucleation thermal cycling treatments were then used to measure the relative catalytic potency of primary intermetallic phases in this system for nucleation ofβ-tin during cooling. Crystallization reactions below the equilibrium peritectic temperature of 250 °C, at 187 °C and 230 °C, have been interpreted as corresponding to nucleation ofβ on Sn3Sb2 and SnSb substrates, respectively. The behavior observed in the Sn-Sb system can be generalized to guide the interpretation of heterogeneous catalysis and the analysis of solidification pathways in other peritectic alloy systems. More... »

PAGES

765-773

References to SciGraph publications

  • 1971-02. Grain refinement in aluminum alloyed with titanium and boron in METALLURGICAL AND MATERIALS TRANSACTIONS B
  • 1981. Undercooling Behavior of Liquid Metals in MRS ADVANCES
  • 1991-03. Solidification of undercooled Sn-Sb peritectic alloys: Part I. Microstructural evolution in METALLURGICAL AND MATERIALS TRANSACTIONS A
  • 1971-03. Nucleation in undercooled Sn-Sb alloys in METALLURGICAL AND MATERIALS TRANSACTIONS B
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/bf02670299

    DOI

    http://dx.doi.org/10.1007/bf02670299

    DIMENSIONS

    https://app.dimensions.ai/details/publication/pub.1025550150


    Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
    Incoming Citations Browse incoming citations for this publication using opencitations.net

    JSON-LD is the canonical representation for SciGraph data.

    TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

    [
      {
        "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
        "about": [
          {
            "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/09", 
            "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
            "name": "Engineering", 
            "type": "DefinedTerm"
          }, 
          {
            "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0912", 
            "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
            "name": "Materials Engineering", 
            "type": "DefinedTerm"
          }
        ], 
        "author": [
          {
            "affiliation": {
              "alternateName": "United Technologies Research Center, 06108, East Hartford, CT", 
              "id": "http://www.grid.ac/institutes/grid.427377.2", 
              "name": [
                "United Technologies Research Center, 06108, East Hartford, CT"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Allen", 
            "givenName": "W. P.", 
            "id": "sg:person.012142101713.31", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012142101713.31"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Department of Materials Science and Engineering, University of Wisconsin-Madison, 53706, Madison, WI", 
              "id": "http://www.grid.ac/institutes/grid.14003.36", 
              "name": [
                "Department of Materials Science and Engineering, University of Wisconsin-Madison, 53706, Madison, WI"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Perepezko", 
            "givenName": "J. H.", 
            "id": "sg:person.01154535601.12", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01154535601.12"
            ], 
            "type": "Person"
          }
        ], 
        "citation": [
          {
            "id": "sg:pub.10.1007/bf02663335", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1037068499", 
              "https://doi.org/10.1007/bf02663335"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/bf02662761", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1017051303", 
              "https://doi.org/10.1007/bf02662761"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1557/proc-8-49", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1067957659", 
              "https://doi.org/10.1557/proc-8-49"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/bf02670298", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1043844887", 
              "https://doi.org/10.1007/bf02670298"
            ], 
            "type": "CreativeWork"
          }
        ], 
        "datePublished": "1991-03", 
        "datePublishedReg": "1991-03-01", 
        "description": "The undercooling behavior of fine droplet samples of Sn-rich, Sn-Sb alloys was investigated using differential thermal analysis (DTA). Undercooling levels measured during cooling from the liquid state follow the trend of the intermetallic phase liquidus, suggesting that solidification of all droplet samples (even those which solidify to yield a supersaturated\u03b2-tin product) was probably initiated with formation of primary intermetallic phase. Heterogeneous nucleation thermal cycling treatments were then used to measure the relative catalytic potency of primary intermetallic phases in this system for nucleation of\u03b2-tin during cooling. Crystallization reactions below the equilibrium peritectic temperature of 250 \u00b0C, at 187 \u00b0C and 230 \u00b0C, have been interpreted as corresponding to nucleation of\u03b2 on Sn3Sb2 and SnSb substrates, respectively. The behavior observed in the Sn-Sb system can be generalized to guide the interpretation of heterogeneous catalysis and the analysis of solidification pathways in other peritectic alloy systems.", 
        "genre": "article", 
        "id": "sg:pub.10.1007/bf02670299", 
        "inLanguage": "en", 
        "isAccessibleForFree": false, 
        "isPartOf": [
          {
            "id": "sg:journal.1136292", 
            "issn": [
              "1073-5623", 
              "1543-1940"
            ], 
            "name": "Metallurgical and Materials Transactions A", 
            "publisher": "Springer Nature", 
            "type": "Periodical"
          }, 
          {
            "issueNumber": "3", 
            "type": "PublicationIssue"
          }, 
          {
            "type": "PublicationVolume", 
            "volumeNumber": "22"
          }
        ], 
        "keywords": [
          "primary intermetallic phase", 
          "intermetallic phases", 
          "thermal cycling treatment", 
          "droplet samples", 
          "Sn-Sb alloy", 
          "differential thermal analysis", 
          "equilibrium peritectic temperature", 
          "solidification pathways", 
          "alloy system", 
          "peritectic alloys", 
          "cycling treatment", 
          "undercooling behavior", 
          "undercooling level", 
          "alloy", 
          "peritectic temperature", 
          "thermal analysis", 
          "solidification", 
          "heterogeneous nucleation", 
          "crystallization reaction", 
          "liquid state", 
          "Part II", 
          "cooling", 
          "Sn3Sb2", 
          "behavior", 
          "phase", 
          "nucleation", 
          "system", 
          "temperature", 
          "liquidus", 
          "substrate", 
          "Sn", 
          "catalytic potency", 
          "heterogeneous catalysis", 
          "of\u03b2", 
          "analysis", 
          "samples", 
          "formation", 
          "trends", 
          "reaction", 
          "state", 
          "catalysis", 
          "levels", 
          "treatment", 
          "interpretation", 
          "pathway", 
          "potency", 
          "Sn-Sb system", 
          "fine droplet samples", 
          "intermetallic phase liquidus", 
          "phase liquidus", 
          "Heterogeneous nucleation thermal cycling treatments", 
          "nucleation thermal cycling treatments", 
          "relative catalytic potency", 
          "nucleation of\u03b2-tin", 
          "of\u03b2-tin", 
          "nucleation of\u03b2", 
          "SnSb substrates", 
          "peritectic alloy systems", 
          "undercooled Sn-Sb peritectic alloys", 
          "Sn-Sb peritectic alloys"
        ], 
        "name": "Solidification of undercooled Sn-Sb peritectic alloys: Part II. Heterogeneous nucleation", 
        "pagination": "765-773", 
        "productId": [
          {
            "name": "dimensions_id", 
            "type": "PropertyValue", 
            "value": [
              "pub.1025550150"
            ]
          }, 
          {
            "name": "doi", 
            "type": "PropertyValue", 
            "value": [
              "10.1007/bf02670299"
            ]
          }
        ], 
        "sameAs": [
          "https://doi.org/10.1007/bf02670299", 
          "https://app.dimensions.ai/details/publication/pub.1025550150"
        ], 
        "sdDataset": "articles", 
        "sdDatePublished": "2022-01-01T18:06", 
        "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
        "sdPublisher": {
          "name": "Springer Nature - SN SciGraph project", 
          "type": "Organization"
        }, 
        "sdSource": "s3://com-springernature-scigraph/baseset/20220101/entities/gbq_results/article/article_248.jsonl", 
        "type": "ScholarlyArticle", 
        "url": "https://doi.org/10.1007/bf02670299"
      }
    ]
     

    Download the RDF metadata as:  json-ld nt turtle xml License info

    HOW TO GET THIS DATA PROGRAMMATICALLY:

    JSON-LD is a popular format for linked data which is fully compatible with JSON.

    curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf02670299'

    N-Triples is a line-based linked data format ideal for batch operations.

    curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf02670299'

    Turtle is a human-readable linked data format.

    curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf02670299'

    RDF/XML is a standard XML format for linked data.

    curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf02670299'


     

    This table displays all metadata directly associated to this object as RDF triples.

    144 TRIPLES      22 PREDICATES      90 URIs      78 LITERALS      6 BLANK NODES

    Subject Predicate Object
    1 sg:pub.10.1007/bf02670299 schema:about anzsrc-for:09
    2 anzsrc-for:0912
    3 schema:author N52edcb89869c4d59bac25d439df4e5bd
    4 schema:citation sg:pub.10.1007/bf02662761
    5 sg:pub.10.1007/bf02663335
    6 sg:pub.10.1007/bf02670298
    7 sg:pub.10.1557/proc-8-49
    8 schema:datePublished 1991-03
    9 schema:datePublishedReg 1991-03-01
    10 schema:description The undercooling behavior of fine droplet samples of Sn-rich, Sn-Sb alloys was investigated using differential thermal analysis (DTA). Undercooling levels measured during cooling from the liquid state follow the trend of the intermetallic phase liquidus, suggesting that solidification of all droplet samples (even those which solidify to yield a supersaturatedβ-tin product) was probably initiated with formation of primary intermetallic phase. Heterogeneous nucleation thermal cycling treatments were then used to measure the relative catalytic potency of primary intermetallic phases in this system for nucleation ofβ-tin during cooling. Crystallization reactions below the equilibrium peritectic temperature of 250 °C, at 187 °C and 230 °C, have been interpreted as corresponding to nucleation ofβ on Sn3Sb2 and SnSb substrates, respectively. The behavior observed in the Sn-Sb system can be generalized to guide the interpretation of heterogeneous catalysis and the analysis of solidification pathways in other peritectic alloy systems.
    11 schema:genre article
    12 schema:inLanguage en
    13 schema:isAccessibleForFree false
    14 schema:isPartOf Na97b71ff411543c4afef7deca29a2cc0
    15 Nb5e9a754f8b342b28c8fb5196c61cb2a
    16 sg:journal.1136292
    17 schema:keywords Heterogeneous nucleation thermal cycling treatments
    18 Part II
    19 Sn
    20 Sn-Sb alloy
    21 Sn-Sb peritectic alloys
    22 Sn-Sb system
    23 Sn3Sb2
    24 SnSb substrates
    25 alloy
    26 alloy system
    27 analysis
    28 behavior
    29 catalysis
    30 catalytic potency
    31 cooling
    32 crystallization reaction
    33 cycling treatment
    34 differential thermal analysis
    35 droplet samples
    36 equilibrium peritectic temperature
    37 fine droplet samples
    38 formation
    39 heterogeneous catalysis
    40 heterogeneous nucleation
    41 intermetallic phase liquidus
    42 intermetallic phases
    43 interpretation
    44 levels
    45 liquid state
    46 liquidus
    47 nucleation
    48 nucleation ofβ
    49 nucleation ofβ-tin
    50 nucleation thermal cycling treatments
    51 ofβ
    52 ofβ-tin
    53 pathway
    54 peritectic alloy systems
    55 peritectic alloys
    56 peritectic temperature
    57 phase
    58 phase liquidus
    59 potency
    60 primary intermetallic phase
    61 reaction
    62 relative catalytic potency
    63 samples
    64 solidification
    65 solidification pathways
    66 state
    67 substrate
    68 system
    69 temperature
    70 thermal analysis
    71 thermal cycling treatment
    72 treatment
    73 trends
    74 undercooled Sn-Sb peritectic alloys
    75 undercooling behavior
    76 undercooling level
    77 schema:name Solidification of undercooled Sn-Sb peritectic alloys: Part II. Heterogeneous nucleation
    78 schema:pagination 765-773
    79 schema:productId N054000de7c47480b9ee276f2c7ab436a
    80 N80a95f7f35dc4d77a8e3f72119d93563
    81 schema:sameAs https://app.dimensions.ai/details/publication/pub.1025550150
    82 https://doi.org/10.1007/bf02670299
    83 schema:sdDatePublished 2022-01-01T18:06
    84 schema:sdLicense https://scigraph.springernature.com/explorer/license/
    85 schema:sdPublisher N4ef8d327e088483e8c40f6560c950506
    86 schema:url https://doi.org/10.1007/bf02670299
    87 sgo:license sg:explorer/license/
    88 sgo:sdDataset articles
    89 rdf:type schema:ScholarlyArticle
    90 N054000de7c47480b9ee276f2c7ab436a schema:name dimensions_id
    91 schema:value pub.1025550150
    92 rdf:type schema:PropertyValue
    93 N4ef8d327e088483e8c40f6560c950506 schema:name Springer Nature - SN SciGraph project
    94 rdf:type schema:Organization
    95 N52edcb89869c4d59bac25d439df4e5bd rdf:first sg:person.012142101713.31
    96 rdf:rest Nfab8446406f948e2aa8418c25beb2cde
    97 N80a95f7f35dc4d77a8e3f72119d93563 schema:name doi
    98 schema:value 10.1007/bf02670299
    99 rdf:type schema:PropertyValue
    100 Na97b71ff411543c4afef7deca29a2cc0 schema:volumeNumber 22
    101 rdf:type schema:PublicationVolume
    102 Nb5e9a754f8b342b28c8fb5196c61cb2a schema:issueNumber 3
    103 rdf:type schema:PublicationIssue
    104 Nfab8446406f948e2aa8418c25beb2cde rdf:first sg:person.01154535601.12
    105 rdf:rest rdf:nil
    106 anzsrc-for:09 schema:inDefinedTermSet anzsrc-for:
    107 schema:name Engineering
    108 rdf:type schema:DefinedTerm
    109 anzsrc-for:0912 schema:inDefinedTermSet anzsrc-for:
    110 schema:name Materials Engineering
    111 rdf:type schema:DefinedTerm
    112 sg:journal.1136292 schema:issn 1073-5623
    113 1543-1940
    114 schema:name Metallurgical and Materials Transactions A
    115 schema:publisher Springer Nature
    116 rdf:type schema:Periodical
    117 sg:person.01154535601.12 schema:affiliation grid-institutes:grid.14003.36
    118 schema:familyName Perepezko
    119 schema:givenName J. H.
    120 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01154535601.12
    121 rdf:type schema:Person
    122 sg:person.012142101713.31 schema:affiliation grid-institutes:grid.427377.2
    123 schema:familyName Allen
    124 schema:givenName W. P.
    125 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012142101713.31
    126 rdf:type schema:Person
    127 sg:pub.10.1007/bf02662761 schema:sameAs https://app.dimensions.ai/details/publication/pub.1017051303
    128 https://doi.org/10.1007/bf02662761
    129 rdf:type schema:CreativeWork
    130 sg:pub.10.1007/bf02663335 schema:sameAs https://app.dimensions.ai/details/publication/pub.1037068499
    131 https://doi.org/10.1007/bf02663335
    132 rdf:type schema:CreativeWork
    133 sg:pub.10.1007/bf02670298 schema:sameAs https://app.dimensions.ai/details/publication/pub.1043844887
    134 https://doi.org/10.1007/bf02670298
    135 rdf:type schema:CreativeWork
    136 sg:pub.10.1557/proc-8-49 schema:sameAs https://app.dimensions.ai/details/publication/pub.1067957659
    137 https://doi.org/10.1557/proc-8-49
    138 rdf:type schema:CreativeWork
    139 grid-institutes:grid.14003.36 schema:alternateName Department of Materials Science and Engineering, University of Wisconsin-Madison, 53706, Madison, WI
    140 schema:name Department of Materials Science and Engineering, University of Wisconsin-Madison, 53706, Madison, WI
    141 rdf:type schema:Organization
    142 grid-institutes:grid.427377.2 schema:alternateName United Technologies Research Center, 06108, East Hartford, CT
    143 schema:name United Technologies Research Center, 06108, East Hartford, CT
    144 rdf:type schema:Organization
     




    Preview window. Press ESC to close (or click here)


    ...