1,2-Cycloaddition of Haloalkenes to Conjugated Fatty Esters View Full Text


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Article Info

DATE

1968-05

AUTHORS

E. W. Bell, J. P. Friedrich, L. E. Gast, J. C. Cowan

ABSTRACT

We have studied the reaction of 1,1-dichloro-2,2-difluoro-, chlorotrifluoro-, and tetrafluoro-ethylenes and also hexafluoropropylene withcis,trans andtrans,trans isomers of conjugated methyl octadecadienoate. Reactions gave 50-82% yields of cycloaddition products. The pre-ponderance of products with a cyclobutane struc-ture and a double bonda,β to the cyclobutane ring was shown by IR and NMR spectra. Reactions were carried out in diluent with hy-droquinone inhibitor at autogenous pressure and a temperature of 200C for 5 hr. The distilled adducts are colorless liquids with viscosities rang-ing from 11 to 19 centistokes at 100F. These products and their hydrogenated derivatives ex-hibit low pour points (down to -76F) and may be useful as low-temperature plasticizers or lubricant additives. More... »

PAGES

388-392

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf02667117

DOI

http://dx.doi.org/10.1007/bf02667117

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1033160935


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