Enhanced low-temperature sintering of tungsten View Full Text


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Article Info

DATE

1976-12

AUTHORS

R. M. German, Z. A. Munir

ABSTRACT

The effects of various transition metal additions on the sintering of a well-characterized, fine tungsten powder were analyzed using both isothermal and constant heating rate experiments in the temperature range 900 to 1400°C. Approximately four atomic mono-layers of palladium on the tungsten powder surface were found to be the optimal enhancer, followed by nickel, cobalt, platinum, and iron. The addition of Cu to the tungsten had no appreciable effect on the sintering kinetics. Sintering enhancement by these transition metals is related to their periodic chart position (i.e., electron structure). An overall non-Arrhenius shrinkage temperature dependence is attributed to grain growth in the activator-treated specimens. The activation energy for tungsten densification was determined to be 430 to 450 kJ/mol, which is in general agreement with a grain boundary diffusion process. More... »

PAGES

1873-1877

References to SciGraph publications

  • 1973-05. Effect of a solid-phase nickel coating on the sintering kinetics of tungsten wires in SOVIET POWDER METALLURGY AND METAL CERAMICS
  • 1967-07. Activated sintering of tungsten with palladium additions in SOVIET POWDER METALLURGY AND METAL CERAMICS
  • 1975-11. Diffusion in transition metals and alloys in METALLURGICAL AND MATERIALS TRANSACTIONS A
  • 1973. A Configurational Model of Matter in NONE
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/bf02659818

    DOI

    http://dx.doi.org/10.1007/bf02659818

    DIMENSIONS

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