Activity of carbon and solubility of carbides in the FCC Fe-Mo-C, Fe-Cr-C, and Fe-V-C alloys View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1972-11

AUTHORS

T. Wada, H. Wada, J. F. Elliott, J. Chipman

ABSTRACT

The activity of carbon in austenitic Fe-Mo-C, Fe-Cr-C, and Fe-V-C alloys has been studied by equilibration with controlled CH4-H2 atmospheres at temperatures in the range 850° to 1200°C. The observations included a number of compositions in the two-phase fields, γ + carbide. Equations are given for the activity coefficient of carbon as a function of temperature and composition in the austenite field and from these the other thermodynamic properties of the solution may be computed as desired. The phase boundaries γ/γ + carbide were determined by breaks in the isoactivity lines. This was supplemented in the case of Fe-Mo-C alloys by metallographic linear analysis of equilibrated samples. The results confirm certain published phase diagrams and discredit others. More... »

PAGES

2865-2872

References to SciGraph publications

  • 1971-08. Thermodynamics of the Fcc Fe−Ni−C and Ni−C alloys in METALLURGICAL AND MATERIALS TRANSACTIONS B
  • 1972-06. Thermodynamics of the fcc Fe-Mn-C and Fe-Si-C alloys in METALLURGICAL AND MATERIALS TRANSACTIONS B
  • 1970-05. Thermodynamics of austenitic Fe-C alloys in METALLURGICAL AND MATERIALS TRANSACTIONS B
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/bf02652854

    DOI

    http://dx.doi.org/10.1007/bf02652854

    DIMENSIONS

    https://app.dimensions.ai/details/publication/pub.1043449181


    Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
    Incoming Citations Browse incoming citations for this publication using opencitations.net

    JSON-LD is the canonical representation for SciGraph data.

    TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

    [
      {
        "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
        "about": [
          {
            "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/09", 
            "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
            "name": "Engineering", 
            "type": "DefinedTerm"
          }, 
          {
            "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0912", 
            "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
            "name": "Materials Engineering", 
            "type": "DefinedTerm"
          }
        ], 
        "author": [
          {
            "affiliation": {
              "alternateName": "Climax Molybdenum Company, Ann Arbor, Mich.", 
              "id": "http://www.grid.ac/institutes/None", 
              "name": [
                "Climax Molybdenum Company, Ann Arbor, Mich."
              ], 
              "type": "Organization"
            }, 
            "familyName": "Wada", 
            "givenName": "T.", 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "University of Michigan, Ann Arbor, Mich.", 
              "id": "http://www.grid.ac/institutes/grid.214458.e", 
              "name": [
                "University of Michigan, Ann Arbor, Mich."
              ], 
              "type": "Organization"
            }, 
            "familyName": "Wada", 
            "givenName": "H.", 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Department of Metallurgy and Materials Science, Massachusetts Institute of Technology, USA", 
              "id": "http://www.grid.ac/institutes/grid.116068.8", 
              "name": [
                "Department of Metallurgy and Materials Science, Massachusetts Institute of Technology, USA"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Elliott", 
            "givenName": "J. F.", 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Department of Metallurgy and Materials Science, Massachusetts Institute of Technology, USA", 
              "id": "http://www.grid.ac/institutes/grid.116068.8", 
              "name": [
                "Department of Metallurgy and Materials Science, Massachusetts Institute of Technology, USA"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Chipman", 
            "givenName": "J.", 
            "type": "Person"
          }
        ], 
        "citation": [
          {
            "id": "sg:pub.10.1007/bf02900248", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1085195729", 
              "https://doi.org/10.1007/bf02900248"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/bf02643059", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1005775822", 
              "https://doi.org/10.1007/bf02643059"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/bf02917551", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1050079849", 
              "https://doi.org/10.1007/bf02917551"
            ], 
            "type": "CreativeWork"
          }
        ], 
        "datePublished": "1972-11", 
        "datePublishedReg": "1972-11-01", 
        "description": "The activity of carbon in austenitic Fe-Mo-C, Fe-Cr-C, and Fe-V-C alloys has been studied by equilibration with controlled CH4-H2 atmospheres at temperatures in the range 850\u00b0 to 1200\u00b0C. The observations included a number of compositions in the two-phase fields, \u03b3 + carbide. Equations are given for the activity coefficient of carbon as a function of temperature and composition in the austenite field and from these the other thermodynamic properties of the solution may be computed as desired. The phase boundaries \u03b3/\u03b3 + carbide were determined by breaks in the isoactivity lines. This was supplemented in the case of Fe-Mo-C alloys by metallographic linear analysis of equilibrated samples. The results confirm certain published phase diagrams and discredit others.", 
        "genre": "article", 
        "id": "sg:pub.10.1007/bf02652854", 
        "isAccessibleForFree": false, 
        "isPartOf": [
          {
            "id": "sg:journal.1136775", 
            "issn": [
              "1073-5615", 
              "1543-1916"
            ], 
            "name": "Metallurgical and Materials Transactions B", 
            "publisher": "Springer Nature", 
            "type": "Periodical"
          }, 
          {
            "issueNumber": "11", 
            "type": "PublicationIssue"
          }, 
          {
            "type": "PublicationVolume", 
            "volumeNumber": "3"
          }
        ], 
        "keywords": [
          "linear analysis", 
          "phase diagram", 
          "thermodynamic properties", 
          "function of temperature", 
          "number of compositions", 
          "equations", 
          "field", 
          "solution", 
          "diagram", 
          "Fe-Mo", 
          "Fe-Cr", 
          "two-phase field", 
          "coefficient", 
          "properties", 
          "activity of carbon", 
          "temperature", 
          "function", 
          "activity coefficients", 
          "number", 
          "atmosphere", 
          "cases", 
          "observations", 
          "CH4-H2 atmospheres", 
          "results", 
          "solubility of carbides", 
          "carbide", 
          "austenite field", 
          "lines", 
          "C alloy", 
          "analysis", 
          "range 850", 
          "equilibration", 
          "alloy", 
          "equilibrated samples", 
          "carbon", 
          "samples", 
          "composition", 
          "isoactivity lines", 
          "solubility", 
          "breaks", 
          "activity"
        ], 
        "name": "Activity of carbon and solubility of carbides in the FCC Fe-Mo-C, Fe-Cr-C, and Fe-V-C alloys", 
        "pagination": "2865-2872", 
        "productId": [
          {
            "name": "dimensions_id", 
            "type": "PropertyValue", 
            "value": [
              "pub.1043449181"
            ]
          }, 
          {
            "name": "doi", 
            "type": "PropertyValue", 
            "value": [
              "10.1007/bf02652854"
            ]
          }
        ], 
        "sameAs": [
          "https://doi.org/10.1007/bf02652854", 
          "https://app.dimensions.ai/details/publication/pub.1043449181"
        ], 
        "sdDataset": "articles", 
        "sdDatePublished": "2022-10-01T06:26", 
        "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
        "sdPublisher": {
          "name": "Springer Nature - SN SciGraph project", 
          "type": "Organization"
        }, 
        "sdSource": "s3://com-springernature-scigraph/baseset/20221001/entities/gbq_results/article/article_128.jsonl", 
        "type": "ScholarlyArticle", 
        "url": "https://doi.org/10.1007/bf02652854"
      }
    ]
     

    Download the RDF metadata as:  json-ld nt turtle xml License info

    HOW TO GET THIS DATA PROGRAMMATICALLY:

    JSON-LD is a popular format for linked data which is fully compatible with JSON.

    curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf02652854'

    N-Triples is a line-based linked data format ideal for batch operations.

    curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf02652854'

    Turtle is a human-readable linked data format.

    curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf02652854'

    RDF/XML is a standard XML format for linked data.

    curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf02652854'


     

    This table displays all metadata directly associated to this object as RDF triples.

    133 TRIPLES      21 PREDICATES      69 URIs      58 LITERALS      6 BLANK NODES

    Subject Predicate Object
    1 sg:pub.10.1007/bf02652854 schema:about anzsrc-for:09
    2 anzsrc-for:0912
    3 schema:author Nd908705a088c46858e34de54da9435d2
    4 schema:citation sg:pub.10.1007/bf02643059
    5 sg:pub.10.1007/bf02900248
    6 sg:pub.10.1007/bf02917551
    7 schema:datePublished 1972-11
    8 schema:datePublishedReg 1972-11-01
    9 schema:description The activity of carbon in austenitic Fe-Mo-C, Fe-Cr-C, and Fe-V-C alloys has been studied by equilibration with controlled CH4-H2 atmospheres at temperatures in the range 850° to 1200°C. The observations included a number of compositions in the two-phase fields, γ + carbide. Equations are given for the activity coefficient of carbon as a function of temperature and composition in the austenite field and from these the other thermodynamic properties of the solution may be computed as desired. The phase boundaries γ/γ + carbide were determined by breaks in the isoactivity lines. This was supplemented in the case of Fe-Mo-C alloys by metallographic linear analysis of equilibrated samples. The results confirm certain published phase diagrams and discredit others.
    10 schema:genre article
    11 schema:isAccessibleForFree false
    12 schema:isPartOf N7626bedcffe74448bddf6335c503a3d2
    13 N7f673538ac37438b9b35142aefd223b6
    14 sg:journal.1136775
    15 schema:keywords C alloy
    16 CH4-H2 atmospheres
    17 Fe-Cr
    18 Fe-Mo
    19 activity
    20 activity coefficients
    21 activity of carbon
    22 alloy
    23 analysis
    24 atmosphere
    25 austenite field
    26 breaks
    27 carbide
    28 carbon
    29 cases
    30 coefficient
    31 composition
    32 diagram
    33 equations
    34 equilibrated samples
    35 equilibration
    36 field
    37 function
    38 function of temperature
    39 isoactivity lines
    40 linear analysis
    41 lines
    42 number
    43 number of compositions
    44 observations
    45 phase diagram
    46 properties
    47 range 850
    48 results
    49 samples
    50 solubility
    51 solubility of carbides
    52 solution
    53 temperature
    54 thermodynamic properties
    55 two-phase field
    56 schema:name Activity of carbon and solubility of carbides in the FCC Fe-Mo-C, Fe-Cr-C, and Fe-V-C alloys
    57 schema:pagination 2865-2872
    58 schema:productId N298d8d2f2fe74993abba3960a36a6583
    59 N48a5a40f9211444daebc6d57246772f1
    60 schema:sameAs https://app.dimensions.ai/details/publication/pub.1043449181
    61 https://doi.org/10.1007/bf02652854
    62 schema:sdDatePublished 2022-10-01T06:26
    63 schema:sdLicense https://scigraph.springernature.com/explorer/license/
    64 schema:sdPublisher N3f1fc845038940d8b44f50f25239574b
    65 schema:url https://doi.org/10.1007/bf02652854
    66 sgo:license sg:explorer/license/
    67 sgo:sdDataset articles
    68 rdf:type schema:ScholarlyArticle
    69 N1bb645d2f1b346c78fffb73b9a296ace schema:affiliation grid-institutes:None
    70 schema:familyName Wada
    71 schema:givenName T.
    72 rdf:type schema:Person
    73 N298d8d2f2fe74993abba3960a36a6583 schema:name doi
    74 schema:value 10.1007/bf02652854
    75 rdf:type schema:PropertyValue
    76 N3f1fc845038940d8b44f50f25239574b schema:name Springer Nature - SN SciGraph project
    77 rdf:type schema:Organization
    78 N42677e4de775466883270ee9fa4e9797 rdf:first N7636d29b3b5b41beb636638fa7855e0d
    79 rdf:rest rdf:nil
    80 N48a5a40f9211444daebc6d57246772f1 schema:name dimensions_id
    81 schema:value pub.1043449181
    82 rdf:type schema:PropertyValue
    83 N5684805fb608426f9d42ae882232a7b2 schema:affiliation grid-institutes:grid.116068.8
    84 schema:familyName Elliott
    85 schema:givenName J. F.
    86 rdf:type schema:Person
    87 N70330d27728244199b2b1e00b365464c rdf:first N5684805fb608426f9d42ae882232a7b2
    88 rdf:rest N42677e4de775466883270ee9fa4e9797
    89 N7626bedcffe74448bddf6335c503a3d2 schema:volumeNumber 3
    90 rdf:type schema:PublicationVolume
    91 N7636d29b3b5b41beb636638fa7855e0d schema:affiliation grid-institutes:grid.116068.8
    92 schema:familyName Chipman
    93 schema:givenName J.
    94 rdf:type schema:Person
    95 N7f673538ac37438b9b35142aefd223b6 schema:issueNumber 11
    96 rdf:type schema:PublicationIssue
    97 Nbf0f90665eba40f1a353228ea51ab9dd rdf:first Nd77e04ba825044efa4c99f2ed481b48a
    98 rdf:rest N70330d27728244199b2b1e00b365464c
    99 Nd77e04ba825044efa4c99f2ed481b48a schema:affiliation grid-institutes:grid.214458.e
    100 schema:familyName Wada
    101 schema:givenName H.
    102 rdf:type schema:Person
    103 Nd908705a088c46858e34de54da9435d2 rdf:first N1bb645d2f1b346c78fffb73b9a296ace
    104 rdf:rest Nbf0f90665eba40f1a353228ea51ab9dd
    105 anzsrc-for:09 schema:inDefinedTermSet anzsrc-for:
    106 schema:name Engineering
    107 rdf:type schema:DefinedTerm
    108 anzsrc-for:0912 schema:inDefinedTermSet anzsrc-for:
    109 schema:name Materials Engineering
    110 rdf:type schema:DefinedTerm
    111 sg:journal.1136775 schema:issn 1073-5615
    112 1543-1916
    113 schema:name Metallurgical and Materials Transactions B
    114 schema:publisher Springer Nature
    115 rdf:type schema:Periodical
    116 sg:pub.10.1007/bf02643059 schema:sameAs https://app.dimensions.ai/details/publication/pub.1005775822
    117 https://doi.org/10.1007/bf02643059
    118 rdf:type schema:CreativeWork
    119 sg:pub.10.1007/bf02900248 schema:sameAs https://app.dimensions.ai/details/publication/pub.1085195729
    120 https://doi.org/10.1007/bf02900248
    121 rdf:type schema:CreativeWork
    122 sg:pub.10.1007/bf02917551 schema:sameAs https://app.dimensions.ai/details/publication/pub.1050079849
    123 https://doi.org/10.1007/bf02917551
    124 rdf:type schema:CreativeWork
    125 grid-institutes:None schema:alternateName Climax Molybdenum Company, Ann Arbor, Mich.
    126 schema:name Climax Molybdenum Company, Ann Arbor, Mich.
    127 rdf:type schema:Organization
    128 grid-institutes:grid.116068.8 schema:alternateName Department of Metallurgy and Materials Science, Massachusetts Institute of Technology, USA
    129 schema:name Department of Metallurgy and Materials Science, Massachusetts Institute of Technology, USA
    130 rdf:type schema:Organization
    131 grid-institutes:grid.214458.e schema:alternateName University of Michigan, Ann Arbor, Mich.
    132 schema:name University of Michigan, Ann Arbor, Mich.
    133 rdf:type schema:Organization
     




    Preview window. Press ESC to close (or click here)


    ...