Surface composition of ternary cu-ag-au alloys: part i. experimental results View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1991-08

AUTHORS

M. A. Hoffmann, P. Wynblatt

ABSTRACT

The enthalpies and entropies of segregation for silver and gold, along with equilibrium surface composition measurements on three Cu-Ag-Au ternary specimens, are reported and discussed. The experimentally studied compositions were Cu-0.3 at. pct Ag-2.1 at. pct Au, Cu-0.55 at. pct Ag-6.5 at. pct Au, and Cu-1.09 at. pct Ag-6.9 at. pct Au. The experimental enthalpies of segregation, entropies of segregation, and surface compositions are compared with those of binary alloys having nearly identical bulk solute contents in order to isolate ternary effects on surface segregation. The results indicate that the equilibrium surface composition of the ternary alloys is dominated by site competition with respect to the more weakly segregating species (gold). The surface composition of the more strongly surface-active species (silver) is largely unaffected by ternary bulk gold additions of up to 7 at. pct. More... »

PAGES

1833-1840

Journal

TITLE

Metallurgical Transactions A

ISSUE

8

VOLUME

22

Author Affiliations

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf02646507

DOI

http://dx.doi.org/10.1007/bf02646507

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1006218276


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0912", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Materials Engineering", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/09", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Engineering", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Carnegie Mellon University", 
          "id": "https://www.grid.ac/institutes/grid.147455.6", 
          "name": [
            "Department of Metallurgical Engineering and Materials Science, Carnegie Mellon University, 15213, Pittsburgh, PA"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Hoffmann", 
        "givenName": "M. A.", 
        "id": "sg:person.014272122641.97", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014272122641.97"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Carnegie Mellon University", 
          "id": "https://www.grid.ac/institutes/grid.147455.6", 
          "name": [
            "Department of Metallurgical Engineering and Materials Science, Carnegie Mellon University, 15213, Pittsburgh, PA"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Wynblatt", 
        "givenName": "P.", 
        "id": "sg:person.015403666233.15", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015403666233.15"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1007/bf02670247", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1010891513", 
          "https://doi.org/10.1007/bf02670247"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02670247", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1010891513", 
          "https://doi.org/10.1007/bf02670247"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0036-9748(88)80124-8", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1015198178"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1179/imr.1988.33.1.314", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1017319470"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0036-9748(86)90205-x", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1017683767"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0036-9748(86)90205-x", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1017683767"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0036-9748(88)80125-x", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1021558583"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0039-6028(90)90479-r", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1027946582"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0039-6028(90)90479-r", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1027946582"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02643476", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1031261947", 
          "https://doi.org/10.1007/bf02643476"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02643476", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1031261947", 
          "https://doi.org/10.1007/bf02643476"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02642852", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1033721842", 
          "https://doi.org/10.1007/bf02642852"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02642852", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1033721842", 
          "https://doi.org/10.1007/bf02642852"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1080/01418617908234852", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1035399658"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0039-6028(88)90337-8", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1039202083"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0039-6028(88)90337-8", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1039202083"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1080/14786437708235984", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1039657788"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0036-9748(88)80164-9", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1041433753"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0001-6160(86)90009-x", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1041584426"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0001-6160(86)90009-x", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1041584426"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02646508", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1048206530", 
          "https://doi.org/10.1007/bf02646508"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02646508", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1048206530", 
          "https://doi.org/10.1007/bf02646508"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevb.29.6443", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060534782"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevb.29.6443", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060534782"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevlett.50.1285", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060788409"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevlett.50.1285", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060788409"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1116/1.575020", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1062185067"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1116/1.577125", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1062187172"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "1991-08", 
    "datePublishedReg": "1991-08-01", 
    "description": "The enthalpies and entropies of segregation for silver and gold, along with equilibrium surface composition measurements on three Cu-Ag-Au ternary specimens, are reported and discussed. The experimentally studied compositions were Cu-0.3 at. pct Ag-2.1 at. pct Au, Cu-0.55 at. pct Ag-6.5 at. pct Au, and Cu-1.09 at. pct Ag-6.9 at. pct Au. The experimental enthalpies of segregation, entropies of segregation, and surface compositions are compared with those of binary alloys having nearly identical bulk solute contents in order to isolate ternary effects on surface segregation. The results indicate that the equilibrium surface composition of the ternary alloys is dominated by site competition with respect to the more weakly segregating species (gold). The surface composition of the more strongly surface-active species (silver) is largely unaffected by ternary bulk gold additions of up to 7 at. pct.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/bf02646507", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1317676", 
        "issn": [
          "0360-2133"
        ], 
        "name": "Metallurgical Transactions A", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "8", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "22"
      }
    ], 
    "name": "Surface composition of ternary cu-ag-au alloys: part i. experimental results", 
    "pagination": "1833-1840", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "1d9eff983940a07ddf43ab3c31dbebca07e3b1d91b4a1658c2aa6e1d97e73d19"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/bf02646507"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1006218276"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/bf02646507", 
      "https://app.dimensions.ai/details/publication/pub.1006218276"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-11T13:27", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000370_0000000370/records_46738_00000000.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1007%2FBF02646507"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf02646507'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf02646507'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf02646507'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf02646507'


 

This table displays all metadata directly associated to this object as RDF triples.

125 TRIPLES      21 PREDICATES      45 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/bf02646507 schema:about anzsrc-for:09
2 anzsrc-for:0912
3 schema:author N157580c95ccb4b70a2b2d0ba2bed74d6
4 schema:citation sg:pub.10.1007/bf02642852
5 sg:pub.10.1007/bf02643476
6 sg:pub.10.1007/bf02646508
7 sg:pub.10.1007/bf02670247
8 https://doi.org/10.1016/0001-6160(86)90009-x
9 https://doi.org/10.1016/0036-9748(86)90205-x
10 https://doi.org/10.1016/0039-6028(88)90337-8
11 https://doi.org/10.1016/0039-6028(90)90479-r
12 https://doi.org/10.1016/s0036-9748(88)80124-8
13 https://doi.org/10.1016/s0036-9748(88)80125-x
14 https://doi.org/10.1016/s0036-9748(88)80164-9
15 https://doi.org/10.1080/01418617908234852
16 https://doi.org/10.1080/14786437708235984
17 https://doi.org/10.1103/physrevb.29.6443
18 https://doi.org/10.1103/physrevlett.50.1285
19 https://doi.org/10.1116/1.575020
20 https://doi.org/10.1116/1.577125
21 https://doi.org/10.1179/imr.1988.33.1.314
22 schema:datePublished 1991-08
23 schema:datePublishedReg 1991-08-01
24 schema:description The enthalpies and entropies of segregation for silver and gold, along with equilibrium surface composition measurements on three Cu-Ag-Au ternary specimens, are reported and discussed. The experimentally studied compositions were Cu-0.3 at. pct Ag-2.1 at. pct Au, Cu-0.55 at. pct Ag-6.5 at. pct Au, and Cu-1.09 at. pct Ag-6.9 at. pct Au. The experimental enthalpies of segregation, entropies of segregation, and surface compositions are compared with those of binary alloys having nearly identical bulk solute contents in order to isolate ternary effects on surface segregation. The results indicate that the equilibrium surface composition of the ternary alloys is dominated by site competition with respect to the more weakly segregating species (gold). The surface composition of the more strongly surface-active species (silver) is largely unaffected by ternary bulk gold additions of up to 7 at. pct.
25 schema:genre research_article
26 schema:inLanguage en
27 schema:isAccessibleForFree false
28 schema:isPartOf Nd194781a777d41f09d30e549033d2905
29 Nfdf8583da1a646e196054a87fd083a9e
30 sg:journal.1317676
31 schema:name Surface composition of ternary cu-ag-au alloys: part i. experimental results
32 schema:pagination 1833-1840
33 schema:productId N0f6e6fccb38a4722ba9625cc0aa19625
34 Na1f610b9654d48e6a1918b16418f9a83
35 Nda9f7bc2c5a140fe910fac9c273de700
36 schema:sameAs https://app.dimensions.ai/details/publication/pub.1006218276
37 https://doi.org/10.1007/bf02646507
38 schema:sdDatePublished 2019-04-11T13:27
39 schema:sdLicense https://scigraph.springernature.com/explorer/license/
40 schema:sdPublisher N8ed254bb8f844e0294cb781997d84a3c
41 schema:url http://link.springer.com/10.1007%2FBF02646507
42 sgo:license sg:explorer/license/
43 sgo:sdDataset articles
44 rdf:type schema:ScholarlyArticle
45 N0f6e6fccb38a4722ba9625cc0aa19625 schema:name readcube_id
46 schema:value 1d9eff983940a07ddf43ab3c31dbebca07e3b1d91b4a1658c2aa6e1d97e73d19
47 rdf:type schema:PropertyValue
48 N157580c95ccb4b70a2b2d0ba2bed74d6 rdf:first sg:person.014272122641.97
49 rdf:rest N4c97f1eb089f494ab1e1e0cb4294c0e7
50 N4c97f1eb089f494ab1e1e0cb4294c0e7 rdf:first sg:person.015403666233.15
51 rdf:rest rdf:nil
52 N8ed254bb8f844e0294cb781997d84a3c schema:name Springer Nature - SN SciGraph project
53 rdf:type schema:Organization
54 Na1f610b9654d48e6a1918b16418f9a83 schema:name dimensions_id
55 schema:value pub.1006218276
56 rdf:type schema:PropertyValue
57 Nd194781a777d41f09d30e549033d2905 schema:volumeNumber 22
58 rdf:type schema:PublicationVolume
59 Nda9f7bc2c5a140fe910fac9c273de700 schema:name doi
60 schema:value 10.1007/bf02646507
61 rdf:type schema:PropertyValue
62 Nfdf8583da1a646e196054a87fd083a9e schema:issueNumber 8
63 rdf:type schema:PublicationIssue
64 anzsrc-for:09 schema:inDefinedTermSet anzsrc-for:
65 schema:name Engineering
66 rdf:type schema:DefinedTerm
67 anzsrc-for:0912 schema:inDefinedTermSet anzsrc-for:
68 schema:name Materials Engineering
69 rdf:type schema:DefinedTerm
70 sg:journal.1317676 schema:issn 0360-2133
71 schema:name Metallurgical Transactions A
72 rdf:type schema:Periodical
73 sg:person.014272122641.97 schema:affiliation https://www.grid.ac/institutes/grid.147455.6
74 schema:familyName Hoffmann
75 schema:givenName M. A.
76 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014272122641.97
77 rdf:type schema:Person
78 sg:person.015403666233.15 schema:affiliation https://www.grid.ac/institutes/grid.147455.6
79 schema:familyName Wynblatt
80 schema:givenName P.
81 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015403666233.15
82 rdf:type schema:Person
83 sg:pub.10.1007/bf02642852 schema:sameAs https://app.dimensions.ai/details/publication/pub.1033721842
84 https://doi.org/10.1007/bf02642852
85 rdf:type schema:CreativeWork
86 sg:pub.10.1007/bf02643476 schema:sameAs https://app.dimensions.ai/details/publication/pub.1031261947
87 https://doi.org/10.1007/bf02643476
88 rdf:type schema:CreativeWork
89 sg:pub.10.1007/bf02646508 schema:sameAs https://app.dimensions.ai/details/publication/pub.1048206530
90 https://doi.org/10.1007/bf02646508
91 rdf:type schema:CreativeWork
92 sg:pub.10.1007/bf02670247 schema:sameAs https://app.dimensions.ai/details/publication/pub.1010891513
93 https://doi.org/10.1007/bf02670247
94 rdf:type schema:CreativeWork
95 https://doi.org/10.1016/0001-6160(86)90009-x schema:sameAs https://app.dimensions.ai/details/publication/pub.1041584426
96 rdf:type schema:CreativeWork
97 https://doi.org/10.1016/0036-9748(86)90205-x schema:sameAs https://app.dimensions.ai/details/publication/pub.1017683767
98 rdf:type schema:CreativeWork
99 https://doi.org/10.1016/0039-6028(88)90337-8 schema:sameAs https://app.dimensions.ai/details/publication/pub.1039202083
100 rdf:type schema:CreativeWork
101 https://doi.org/10.1016/0039-6028(90)90479-r schema:sameAs https://app.dimensions.ai/details/publication/pub.1027946582
102 rdf:type schema:CreativeWork
103 https://doi.org/10.1016/s0036-9748(88)80124-8 schema:sameAs https://app.dimensions.ai/details/publication/pub.1015198178
104 rdf:type schema:CreativeWork
105 https://doi.org/10.1016/s0036-9748(88)80125-x schema:sameAs https://app.dimensions.ai/details/publication/pub.1021558583
106 rdf:type schema:CreativeWork
107 https://doi.org/10.1016/s0036-9748(88)80164-9 schema:sameAs https://app.dimensions.ai/details/publication/pub.1041433753
108 rdf:type schema:CreativeWork
109 https://doi.org/10.1080/01418617908234852 schema:sameAs https://app.dimensions.ai/details/publication/pub.1035399658
110 rdf:type schema:CreativeWork
111 https://doi.org/10.1080/14786437708235984 schema:sameAs https://app.dimensions.ai/details/publication/pub.1039657788
112 rdf:type schema:CreativeWork
113 https://doi.org/10.1103/physrevb.29.6443 schema:sameAs https://app.dimensions.ai/details/publication/pub.1060534782
114 rdf:type schema:CreativeWork
115 https://doi.org/10.1103/physrevlett.50.1285 schema:sameAs https://app.dimensions.ai/details/publication/pub.1060788409
116 rdf:type schema:CreativeWork
117 https://doi.org/10.1116/1.575020 schema:sameAs https://app.dimensions.ai/details/publication/pub.1062185067
118 rdf:type schema:CreativeWork
119 https://doi.org/10.1116/1.577125 schema:sameAs https://app.dimensions.ai/details/publication/pub.1062187172
120 rdf:type schema:CreativeWork
121 https://doi.org/10.1179/imr.1988.33.1.314 schema:sameAs https://app.dimensions.ai/details/publication/pub.1017319470
122 rdf:type schema:CreativeWork
123 https://www.grid.ac/institutes/grid.147455.6 schema:alternateName Carnegie Mellon University
124 schema:name Department of Metallurgical Engineering and Materials Science, Carnegie Mellon University, 15213, Pittsburgh, PA
125 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...