The mechanical behavior of nonstoichiometric compounds Ni3Si, Ni3Ge, and Fe3Ga View Full Text


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Article Info

DATE

1984-01

AUTHORS

Tomoo Suzuki, Yoshihiro Oya, Shouichi Ochiai

ABSTRACT

The compression flow stress of the three kinds of nonstoichiometric Ll2 compounds has been measured as a function of composition in the temperature range from 77 to 800 K. The effect of nonstoichiometry on the positive temperature dependence of strength and the defect strengthening in polycrystalline Ni3Si, Ni3Ge, and Fe3Ga alloys are quite similar to those found previously in Ni3Al and Ni3Ga alloys. However, the more intensive positive temperature dependence of strength, the limited homogeneity range within the nickel-rich side of stoichiometry and the lattice contraction in forming Ll2 ordered structure observed in Ni3Si and Ni3Ge are concluded to be characteristic nature of compounds containing 4B-subgroup elements as the minority component. The difference of the extent of homogeneity range in various Ll2 compounds is explained by an asymmetric index deduced from the consideration of the shape of free energy curve in the vicinity of stoichiometry. All these characteristic natures are discussed in terms of the change in bond strength. More... »

PAGES

173-181

Journal

TITLE

Metallurgical Transactions A

ISSUE

1

VOLUME

15

Author Affiliations

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf02644399

DOI

http://dx.doi.org/10.1007/bf02644399

DIMENSIONS

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