Reactions of unsaturated fatty alcohols. V. Preparation and properties of some copolymers of unsaturated fatty vinyl ethers with lower alkyl ... View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1958-07

AUTHORS

L. E. Gast, Wilma J. Schneider, J. L. O’Donnell, J. C. Cowan, H. M. Teeter

ABSTRACT

Soybean vinyl ethers derived from soybean alcohols were copolymerized with lower alkyl vinyl ethers,e.g., ethyl, butyl, isobutyl, 2-chloroethyl, 2-methoxyethyl, and 2-ethylhexyl, in methylene chloride at −30°C., using boron trifluoride etherate catalyst. Molecular weights ranging from 2,000 to 4,000 were obtained on these copolymers by cryoscopic measurements in cyclohexane. An analytical method, using infrared spectroscopy, was employed to determine the composition of the copolymers.The properties of each alkyl-soybean vinyl ether copolymer were studied at three molar compositions,e.g., 3∶1, 1∶1, and 1∶3. The products were water-white to amber viscous liquids and were soluble in aromatic, chlorinated, and gasoline type of solvents.Copolymers films were prepared under conditions that were shown to produce extensive degradation of some homopolymer films in order to magnify small differences in properties. These films were hard, wrinkle-free, and resistant to most common solvents, also were 20 to 500 times more resistant to 5% aqueous alkali than soybean vinyl ether polymer prepared under the same conditions.Copolymer films were baked on silver chloride plates and examined in the infrared. Oxidative degradation of the C−O−C ether linkage was observed in all copolymer films; however the 2-chloroethyl-soybean copolymer series was least susceptible to this degradation. More... »

PAGES

347-350

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf02640549

DOI

http://dx.doi.org/10.1007/bf02640549

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1022938642


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/09", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Engineering", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0904", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Engineering", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Northern Utilization Research and Development Division, Agricultural Research Service, U. S. Department of Agriculture, Peoria, Illinois", 
          "id": "http://www.grid.ac/institutes/grid.508983.f", 
          "name": [
            "Northern Utilization Research and Development Division, Agricultural Research Service, U. S. Department of Agriculture, Peoria, Illinois"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Gast", 
        "givenName": "L. E.", 
        "id": "sg:person.012611112157.09", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012611112157.09"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Northern Utilization Research and Development Division, Agricultural Research Service, U. S. Department of Agriculture, Peoria, Illinois", 
          "id": "http://www.grid.ac/institutes/grid.508983.f", 
          "name": [
            "Northern Utilization Research and Development Division, Agricultural Research Service, U. S. Department of Agriculture, Peoria, Illinois"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Schneider", 
        "givenName": "Wilma J.", 
        "id": "sg:person.016053723577.83", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016053723577.83"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Northern Utilization Research and Development Division, Agricultural Research Service, U. S. Department of Agriculture, Peoria, Illinois", 
          "id": "http://www.grid.ac/institutes/grid.508983.f", 
          "name": [
            "Northern Utilization Research and Development Division, Agricultural Research Service, U. S. Department of Agriculture, Peoria, Illinois"
          ], 
          "type": "Organization"
        }, 
        "familyName": "O\u2019Donnell", 
        "givenName": "J. L.", 
        "id": "sg:person.012230024636.26", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012230024636.26"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Northern Utilization Research and Development Division, Agricultural Research Service, U. S. Department of Agriculture, Peoria, Illinois", 
          "id": "http://www.grid.ac/institutes/grid.508983.f", 
          "name": [
            "Northern Utilization Research and Development Division, Agricultural Research Service, U. S. Department of Agriculture, Peoria, Illinois"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Cowan", 
        "givenName": "J. C.", 
        "id": "sg:person.010137462221.36", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010137462221.36"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Northern Utilization Research and Development Division, Agricultural Research Service, U. S. Department of Agriculture, Peoria, Illinois", 
          "id": "http://www.grid.ac/institutes/grid.508983.f", 
          "name": [
            "Northern Utilization Research and Development Division, Agricultural Research Service, U. S. Department of Agriculture, Peoria, Illinois"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Teeter", 
        "givenName": "H. M.", 
        "id": "sg:person.011611327116.20", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011611327116.20"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1007/bf02640259", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1000349021", 
          "https://doi.org/10.1007/bf02640259"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02630766", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1021914637", 
          "https://doi.org/10.1007/bf02630766"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02638831", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1003231306", 
          "https://doi.org/10.1007/bf02638831"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "1958-07", 
    "datePublishedReg": "1958-07-01", 
    "description": "Soybean vinyl ethers derived from soybean alcohols were copolymerized with lower alkyl vinyl ethers,e.g., ethyl, butyl, isobutyl, 2-chloroethyl, 2-methoxyethyl, and 2-ethylhexyl, in methylene chloride at \u221230\u00b0C., using boron trifluoride etherate catalyst. Molecular weights ranging from 2,000 to 4,000 were obtained on these copolymers by cryoscopic measurements in cyclohexane. An analytical method, using infrared spectroscopy, was employed to determine the composition of the copolymers.The properties of each alkyl-soybean vinyl ether copolymer were studied at three molar compositions,e.g., 3\u22361, 1\u22361, and 1\u22363. The products were water-white to amber viscous liquids and were soluble in aromatic, chlorinated, and gasoline type of solvents.Copolymers films were prepared under conditions that were shown to produce extensive degradation of some homopolymer films in order to magnify small differences in properties. These films were hard, wrinkle-free, and resistant to most common solvents, also were 20 to 500 times more resistant to 5% aqueous alkali than soybean vinyl ether polymer prepared under the same conditions.Copolymer films were baked on silver chloride plates and examined in the infrared. Oxidative degradation of the C\u2212O\u2212C ether linkage was observed in all copolymer films; however the 2-chloroethyl-soybean copolymer series was least susceptible to this degradation.", 
    "genre": "article", 
    "id": "sg:pub.10.1007/bf02640549", 
    "inLanguage": "en", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1082739", 
        "issn": [
          "0003-021X", 
          "1558-9331"
        ], 
        "name": "Journal of the American Oil Chemists' Society", 
        "publisher": "Wiley", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "7", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "35"
      }
    ], 
    "keywords": [
      "alkyl vinyl ethers", 
      "vinyl ether", 
      "copolymer films", 
      "vinyl ether polymers", 
      "most common solvents", 
      "vinyl ether copolymers", 
      "unsaturated fatty alcohols", 
      "boron trifluoride etherate catalyst", 
      "ether polymers", 
      "common solvents", 
      "copolymer series", 
      "homopolymer films", 
      "cryoscopic measurements", 
      "ether copolymer", 
      "ether linkage", 
      "oxidative degradation", 
      "aqueous alkali", 
      "copolymers", 
      "molar composition", 
      "methylene chloride", 
      "gasoline type", 
      "ether", 
      "molecular weight", 
      "analytical method", 
      "solvent", 
      "fatty alcohols", 
      "films", 
      "same conditions", 
      "properties", 
      "catalyst", 
      "viscous liquid", 
      "polymers", 
      "spectroscopy", 
      "alcohol", 
      "extensive degradation", 
      "degradation", 
      "cyclohexane", 
      "Infrared", 
      "butyl", 
      "isobutyl", 
      "composition", 
      "reaction", 
      "ethyl", 
      "chloride", 
      "liquid", 
      "preparation", 
      "alkali", 
      "products", 
      "small differences", 
      "conditions", 
      "series", 
      "measurements", 
      "linkage", 
      "method", 
      "weight", 
      "order", 
      "types", 
      "time", 
      "plate", 
      "differences", 
      "Soybean vinyl ethers", 
      "soybean alcohols", 
      "lower alkyl vinyl ethers", 
      "trifluoride etherate catalyst", 
      "etherate catalyst", 
      "alkyl-soybean vinyl ether copolymer", 
      "soybean vinyl ether polymer", 
      "silver chloride plates", 
      "chloride plates", 
      "unsaturated fatty vinyl ethers", 
      "fatty vinyl ethers"
    ], 
    "name": "Reactions of unsaturated fatty alcohols. V. Preparation and properties of some copolymers of unsaturated fatty vinyl ethers with lower alkyl vinyl ethers", 
    "pagination": "347-350", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1022938642"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/bf02640549"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/bf02640549", 
      "https://app.dimensions.ai/details/publication/pub.1022938642"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-01-01T18:42", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20220101/entities/gbq_results/article/article_72.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1007/bf02640549"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf02640549'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf02640549'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf02640549'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf02640549'


 

This table displays all metadata directly associated to this object as RDF triples.

169 TRIPLES      22 PREDICATES      100 URIs      89 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/bf02640549 schema:about anzsrc-for:09
2 anzsrc-for:0904
3 schema:author N947e9e4780be40eeb03ed259628fd9fc
4 schema:citation sg:pub.10.1007/bf02630766
5 sg:pub.10.1007/bf02638831
6 sg:pub.10.1007/bf02640259
7 schema:datePublished 1958-07
8 schema:datePublishedReg 1958-07-01
9 schema:description Soybean vinyl ethers derived from soybean alcohols were copolymerized with lower alkyl vinyl ethers,e.g., ethyl, butyl, isobutyl, 2-chloroethyl, 2-methoxyethyl, and 2-ethylhexyl, in methylene chloride at −30°C., using boron trifluoride etherate catalyst. Molecular weights ranging from 2,000 to 4,000 were obtained on these copolymers by cryoscopic measurements in cyclohexane. An analytical method, using infrared spectroscopy, was employed to determine the composition of the copolymers.The properties of each alkyl-soybean vinyl ether copolymer were studied at three molar compositions,e.g., 3∶1, 1∶1, and 1∶3. The products were water-white to amber viscous liquids and were soluble in aromatic, chlorinated, and gasoline type of solvents.Copolymers films were prepared under conditions that were shown to produce extensive degradation of some homopolymer films in order to magnify small differences in properties. These films were hard, wrinkle-free, and resistant to most common solvents, also were 20 to 500 times more resistant to 5% aqueous alkali than soybean vinyl ether polymer prepared under the same conditions.Copolymer films were baked on silver chloride plates and examined in the infrared. Oxidative degradation of the C−O−C ether linkage was observed in all copolymer films; however the 2-chloroethyl-soybean copolymer series was least susceptible to this degradation.
10 schema:genre article
11 schema:inLanguage en
12 schema:isAccessibleForFree false
13 schema:isPartOf N9e14d97886254df4818db20b0ffbb003
14 Nee01c922ac6441388e2fdbd8a64068cf
15 sg:journal.1082739
16 schema:keywords Infrared
17 Soybean vinyl ethers
18 alcohol
19 alkali
20 alkyl vinyl ethers
21 alkyl-soybean vinyl ether copolymer
22 analytical method
23 aqueous alkali
24 boron trifluoride etherate catalyst
25 butyl
26 catalyst
27 chloride
28 chloride plates
29 common solvents
30 composition
31 conditions
32 copolymer films
33 copolymer series
34 copolymers
35 cryoscopic measurements
36 cyclohexane
37 degradation
38 differences
39 ether
40 ether copolymer
41 ether linkage
42 ether polymers
43 etherate catalyst
44 ethyl
45 extensive degradation
46 fatty alcohols
47 fatty vinyl ethers
48 films
49 gasoline type
50 homopolymer films
51 isobutyl
52 linkage
53 liquid
54 lower alkyl vinyl ethers
55 measurements
56 method
57 methylene chloride
58 molar composition
59 molecular weight
60 most common solvents
61 order
62 oxidative degradation
63 plate
64 polymers
65 preparation
66 products
67 properties
68 reaction
69 same conditions
70 series
71 silver chloride plates
72 small differences
73 solvent
74 soybean alcohols
75 soybean vinyl ether polymer
76 spectroscopy
77 time
78 trifluoride etherate catalyst
79 types
80 unsaturated fatty alcohols
81 unsaturated fatty vinyl ethers
82 vinyl ether
83 vinyl ether copolymers
84 vinyl ether polymers
85 viscous liquid
86 weight
87 schema:name Reactions of unsaturated fatty alcohols. V. Preparation and properties of some copolymers of unsaturated fatty vinyl ethers with lower alkyl vinyl ethers
88 schema:pagination 347-350
89 schema:productId N27039cc5c93845ac90ea2b9369223a70
90 N2b420933859a4083a83890041f9c9e5d
91 schema:sameAs https://app.dimensions.ai/details/publication/pub.1022938642
92 https://doi.org/10.1007/bf02640549
93 schema:sdDatePublished 2022-01-01T18:42
94 schema:sdLicense https://scigraph.springernature.com/explorer/license/
95 schema:sdPublisher Nbfda54bfb9064bb3a10fcb41e69301a5
96 schema:url https://doi.org/10.1007/bf02640549
97 sgo:license sg:explorer/license/
98 sgo:sdDataset articles
99 rdf:type schema:ScholarlyArticle
100 N12e85107b5ac4739b672f4628d8aa97b rdf:first sg:person.011611327116.20
101 rdf:rest rdf:nil
102 N27039cc5c93845ac90ea2b9369223a70 schema:name dimensions_id
103 schema:value pub.1022938642
104 rdf:type schema:PropertyValue
105 N2b420933859a4083a83890041f9c9e5d schema:name doi
106 schema:value 10.1007/bf02640549
107 rdf:type schema:PropertyValue
108 N727826ca5a3c41c58962cfd83ee3042f rdf:first sg:person.012230024636.26
109 rdf:rest N90e1fb3e72754a75b8205c4286380cb5
110 N87995c8815b5431fafacaf9429d391f8 rdf:first sg:person.016053723577.83
111 rdf:rest N727826ca5a3c41c58962cfd83ee3042f
112 N90e1fb3e72754a75b8205c4286380cb5 rdf:first sg:person.010137462221.36
113 rdf:rest N12e85107b5ac4739b672f4628d8aa97b
114 N947e9e4780be40eeb03ed259628fd9fc rdf:first sg:person.012611112157.09
115 rdf:rest N87995c8815b5431fafacaf9429d391f8
116 N9e14d97886254df4818db20b0ffbb003 schema:issueNumber 7
117 rdf:type schema:PublicationIssue
118 Nbfda54bfb9064bb3a10fcb41e69301a5 schema:name Springer Nature - SN SciGraph project
119 rdf:type schema:Organization
120 Nee01c922ac6441388e2fdbd8a64068cf schema:volumeNumber 35
121 rdf:type schema:PublicationVolume
122 anzsrc-for:09 schema:inDefinedTermSet anzsrc-for:
123 schema:name Engineering
124 rdf:type schema:DefinedTerm
125 anzsrc-for:0904 schema:inDefinedTermSet anzsrc-for:
126 schema:name Chemical Engineering
127 rdf:type schema:DefinedTerm
128 sg:journal.1082739 schema:issn 0003-021X
129 1558-9331
130 schema:name Journal of the American Oil Chemists' Society
131 schema:publisher Wiley
132 rdf:type schema:Periodical
133 sg:person.010137462221.36 schema:affiliation grid-institutes:grid.508983.f
134 schema:familyName Cowan
135 schema:givenName J. C.
136 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010137462221.36
137 rdf:type schema:Person
138 sg:person.011611327116.20 schema:affiliation grid-institutes:grid.508983.f
139 schema:familyName Teeter
140 schema:givenName H. M.
141 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011611327116.20
142 rdf:type schema:Person
143 sg:person.012230024636.26 schema:affiliation grid-institutes:grid.508983.f
144 schema:familyName O’Donnell
145 schema:givenName J. L.
146 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012230024636.26
147 rdf:type schema:Person
148 sg:person.012611112157.09 schema:affiliation grid-institutes:grid.508983.f
149 schema:familyName Gast
150 schema:givenName L. E.
151 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012611112157.09
152 rdf:type schema:Person
153 sg:person.016053723577.83 schema:affiliation grid-institutes:grid.508983.f
154 schema:familyName Schneider
155 schema:givenName Wilma J.
156 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016053723577.83
157 rdf:type schema:Person
158 sg:pub.10.1007/bf02630766 schema:sameAs https://app.dimensions.ai/details/publication/pub.1021914637
159 https://doi.org/10.1007/bf02630766
160 rdf:type schema:CreativeWork
161 sg:pub.10.1007/bf02638831 schema:sameAs https://app.dimensions.ai/details/publication/pub.1003231306
162 https://doi.org/10.1007/bf02638831
163 rdf:type schema:CreativeWork
164 sg:pub.10.1007/bf02640259 schema:sameAs https://app.dimensions.ai/details/publication/pub.1000349021
165 https://doi.org/10.1007/bf02640259
166 rdf:type schema:CreativeWork
167 grid-institutes:grid.508983.f schema:alternateName Northern Utilization Research and Development Division, Agricultural Research Service, U. S. Department of Agriculture, Peoria, Illinois
168 schema:name Northern Utilization Research and Development Division, Agricultural Research Service, U. S. Department of Agriculture, Peoria, Illinois
169 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...