Castor oil-derived plasticizers. Some nitrogen-containing derivatives as plasticizers for vinyl chloride-vinyl acetate copolymer and cellulose acetate resins View Full Text


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Article Info

DATE

1959-12

AUTHORS

Frank C. Magne, Harold P. Dupuy, Leo A. Goldblatt

ABSTRACT

Eight nitrogen-containing derivatives of ricinoleic acid, namely, 4-ricinoleoylmorpholine, 4-(12-hydroxystearoyl) morpholine, 4-(12-acetoxyoleoyl) morpholine, 4-(12-acetoxystearoyl) morpholine, 4-(12-β-cyanoethoxyoleoyl) morpholine, 4-(12-β-cyanoethoxystearoyl) morpholine, 1,12-bis(β-cyanoethoxy)-9-octadecene, and 1,12-bis(β-cyanoethoxy)octadecane were screened for their plasticizer characteristics. 1,12-Diacetoxy-9-octadecene and 1,12-diacetoxyoctadecane were also screened to compare cyanoethylated with acetylated derivatives.All of these materials, except 4-(12-hydroxystearoyl)morpholine, were found to be satisfactory primary plasticizers for vinyl chloride-vinyl acetate copolymer. In general, these derivatives are quite similar to di(2-ethylhexyl) phthalate in plasticizing performance. However 1,12-bis(β-cyanoethoxy)-9-octadecene and 1,12-bis(β-cyanoethoxy)octadecane have exceptionally good low-temperature properties. It was also found that 4-ricinoleoylmorpholine, 4-(12-acetoxyoleoyl)morphine, 4-(12-β-cyanoethoxyoleoyl)morpholine, and 4-(12-β-cyanoethoxystearoyl)morpholine were satisfactory plasticizers for cellulose acetate. More... »

PAGES

635-637

References to SciGraph publications

  • 1959-12. The cyanoethylation and infrared spectra of some ricinoleic acid derivatives in JOURNAL OF THE AMERICAN OIL CHEMISTS' SOCIETY
  • 1958-02. The preparation and infrared spectra of morpholides of ricinoleic acid and some of its derivatives in JOURNAL OF THE AMERICAN OIL CHEMISTS' SOCIETY
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/bf02640274

    DOI

    http://dx.doi.org/10.1007/bf02640274

    DIMENSIONS

    https://app.dimensions.ai/details/publication/pub.1002911840


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