Freezing-point behavior of the ternary reciprocal salt pair system involving the cyclohexylamine and morpholine salts of stearic and palmitic acids View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1958-12

AUTHORS

Robert R. Mod, Frank C. Magne, Evald L. Skau

ABSTRACT

Binary and quasi-binary freezing-point data have been obtained to establish the freezing-point diagram for the ternary reciprocal salt pair system involving cyclohexylamine stearate, cyclohexylamine palmitate, morpholine stearate, and morpholine palmitate. The compositions and freezing points of the ternary peritectic and eutectic mixtures have been determined. Cyclohexylamine palmitate and morpholine stearate are the “stable salt pair.” From the diagram it is possible to predict the freezing behavior of any molten mixture of these salts, including the temperature at which crystals of each component will appear on cooling, the yields of these crystals and the composition of the liquid phase at various temperatures, and the temperature at which maximum yields of crystals of the specific salts can be obtained. The data supply fundamental information in connection with the crystallization of mixed amine salts in the purification of palmitic and stearic acids. More... »

PAGES

688-691

References to SciGraph publications

  • 1958-09. Preparation of pure palmitic acid and a by-product plasticizer from cottonseed oil in JOURNAL OF THE AMERICAN OIL CHEMISTS' SOCIETY
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/bf02638779

    DOI

    http://dx.doi.org/10.1007/bf02638779

    DIMENSIONS

    https://app.dimensions.ai/details/publication/pub.1020170096


    Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
    Incoming Citations Browse incoming citations for this publication using opencitations.net

    JSON-LD is the canonical representation for SciGraph data.

    TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

    [
      {
        "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
        "about": [
          {
            "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/09", 
            "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
            "name": "Engineering", 
            "type": "DefinedTerm"
          }, 
          {
            "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0904", 
            "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
            "name": "Chemical Engineering", 
            "type": "DefinedTerm"
          }
        ], 
        "author": [
          {
            "affiliation": {
              "alternateName": "Southern Regional Research Laboratory, New Orleans, Louisiana", 
              "id": "http://www.grid.ac/institutes/grid.507314.4", 
              "name": [
                "Southern Regional Research Laboratory, New Orleans, Louisiana"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Mod", 
            "givenName": "Robert R.", 
            "id": "sg:person.011073123343.10", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011073123343.10"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Southern Regional Research Laboratory, New Orleans, Louisiana", 
              "id": "http://www.grid.ac/institutes/grid.507314.4", 
              "name": [
                "Southern Regional Research Laboratory, New Orleans, Louisiana"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Magne", 
            "givenName": "Frank C.", 
            "id": "sg:person.012476571651.61", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012476571651.61"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Southern Regional Research Laboratory, New Orleans, Louisiana", 
              "id": "http://www.grid.ac/institutes/grid.507314.4", 
              "name": [
                "Southern Regional Research Laboratory, New Orleans, Louisiana"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Skau", 
            "givenName": "Evald L.", 
            "id": "sg:person.014423631546.73", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014423631546.73"
            ], 
            "type": "Person"
          }
        ], 
        "citation": [
          {
            "id": "sg:pub.10.1007/bf02539921", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1034951694", 
              "https://doi.org/10.1007/bf02539921"
            ], 
            "type": "CreativeWork"
          }
        ], 
        "datePublished": "1958-12", 
        "datePublishedReg": "1958-12-01", 
        "description": "Binary and quasi-binary freezing-point data have been obtained to establish the freezing-point diagram for the ternary reciprocal salt pair system involving cyclohexylamine stearate, cyclohexylamine palmitate, morpholine stearate, and morpholine palmitate. The compositions and freezing points of the ternary peritectic and eutectic mixtures have been determined. Cyclohexylamine palmitate and morpholine stearate are the \u201cstable salt pair.\u201d From the diagram it is possible to predict the freezing behavior of any molten mixture of these salts, including the temperature at which crystals of each component will appear on cooling, the yields of these crystals and the composition of the liquid phase at various temperatures, and the temperature at which maximum yields of crystals of the specific salts can be obtained. The data supply fundamental information in connection with the crystallization of mixed amine salts in the purification of palmitic and stearic acids.", 
        "genre": "article", 
        "id": "sg:pub.10.1007/bf02638779", 
        "isAccessibleForFree": false, 
        "isPartOf": [
          {
            "id": "sg:journal.1082739", 
            "issn": [
              "0003-021X", 
              "1558-9331"
            ], 
            "name": "Journal of the American Oil Chemists' Society", 
            "publisher": "Wiley", 
            "type": "Periodical"
          }, 
          {
            "issueNumber": "12", 
            "type": "PublicationIssue"
          }, 
          {
            "type": "PublicationVolume", 
            "volumeNumber": "35"
          }
        ], 
        "keywords": [
          "palmitate", 
          "freezing behavior", 
          "palmitic acid", 
          "acid", 
          "stearic acid", 
          "morpholine salt", 
          "data", 
          "stearate", 
          "system", 
          "eutectic mixture", 
          "information", 
          "point", 
          "behavior", 
          "salt", 
          "components", 
          "composition", 
          "phase", 
          "fundamental information", 
          "connection", 
          "pairs", 
          "purification", 
          "mixture", 
          "freezing-point diagrams", 
          "amine salts", 
          "cyclohexylamine", 
          "yield", 
          "temperature", 
          "specific salts", 
          "freezing point data", 
          "diagram", 
          "pair system", 
          "crystals", 
          "maximum yield", 
          "salt pairs", 
          "liquid phase", 
          "molten mixtures", 
          "crystallization"
        ], 
        "name": "Freezing-point behavior of the ternary reciprocal salt pair system involving the cyclohexylamine and morpholine salts of stearic and palmitic acids", 
        "pagination": "688-691", 
        "productId": [
          {
            "name": "dimensions_id", 
            "type": "PropertyValue", 
            "value": [
              "pub.1020170096"
            ]
          }, 
          {
            "name": "doi", 
            "type": "PropertyValue", 
            "value": [
              "10.1007/bf02638779"
            ]
          }
        ], 
        "sameAs": [
          "https://doi.org/10.1007/bf02638779", 
          "https://app.dimensions.ai/details/publication/pub.1020170096"
        ], 
        "sdDataset": "articles", 
        "sdDatePublished": "2022-09-02T16:01", 
        "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
        "sdPublisher": {
          "name": "Springer Nature - SN SciGraph project", 
          "type": "Organization"
        }, 
        "sdSource": "s3://com-springernature-scigraph/baseset/20220902/entities/gbq_results/article/article_72.jsonl", 
        "type": "ScholarlyArticle", 
        "url": "https://doi.org/10.1007/bf02638779"
      }
    ]
     

    Download the RDF metadata as:  json-ld nt turtle xml License info

    HOW TO GET THIS DATA PROGRAMMATICALLY:

    JSON-LD is a popular format for linked data which is fully compatible with JSON.

    curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf02638779'

    N-Triples is a line-based linked data format ideal for batch operations.

    curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf02638779'

    Turtle is a human-readable linked data format.

    curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf02638779'

    RDF/XML is a standard XML format for linked data.

    curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf02638779'


     

    This table displays all metadata directly associated to this object as RDF triples.

    112 TRIPLES      21 PREDICATES      63 URIs      54 LITERALS      6 BLANK NODES

    Subject Predicate Object
    1 sg:pub.10.1007/bf02638779 schema:about anzsrc-for:09
    2 anzsrc-for:0904
    3 schema:author N648f3fd4719f46ee908634771ff6cc16
    4 schema:citation sg:pub.10.1007/bf02539921
    5 schema:datePublished 1958-12
    6 schema:datePublishedReg 1958-12-01
    7 schema:description Binary and quasi-binary freezing-point data have been obtained to establish the freezing-point diagram for the ternary reciprocal salt pair system involving cyclohexylamine stearate, cyclohexylamine palmitate, morpholine stearate, and morpholine palmitate. The compositions and freezing points of the ternary peritectic and eutectic mixtures have been determined. Cyclohexylamine palmitate and morpholine stearate are the “stable salt pair.” From the diagram it is possible to predict the freezing behavior of any molten mixture of these salts, including the temperature at which crystals of each component will appear on cooling, the yields of these crystals and the composition of the liquid phase at various temperatures, and the temperature at which maximum yields of crystals of the specific salts can be obtained. The data supply fundamental information in connection with the crystallization of mixed amine salts in the purification of palmitic and stearic acids.
    8 schema:genre article
    9 schema:isAccessibleForFree false
    10 schema:isPartOf N065babb10dde4e1d90070e652ba16aef
    11 Nf56423c67b10464c88725a534acdeffe
    12 sg:journal.1082739
    13 schema:keywords acid
    14 amine salts
    15 behavior
    16 components
    17 composition
    18 connection
    19 crystallization
    20 crystals
    21 cyclohexylamine
    22 data
    23 diagram
    24 eutectic mixture
    25 freezing behavior
    26 freezing point data
    27 freezing-point diagrams
    28 fundamental information
    29 information
    30 liquid phase
    31 maximum yield
    32 mixture
    33 molten mixtures
    34 morpholine salt
    35 pair system
    36 pairs
    37 palmitate
    38 palmitic acid
    39 phase
    40 point
    41 purification
    42 salt
    43 salt pairs
    44 specific salts
    45 stearate
    46 stearic acid
    47 system
    48 temperature
    49 yield
    50 schema:name Freezing-point behavior of the ternary reciprocal salt pair system involving the cyclohexylamine and morpholine salts of stearic and palmitic acids
    51 schema:pagination 688-691
    52 schema:productId N8a9f4180070c458cbde3ed9d77732d8f
    53 N9bedd0e355ce485fbb47072b6d63da0f
    54 schema:sameAs https://app.dimensions.ai/details/publication/pub.1020170096
    55 https://doi.org/10.1007/bf02638779
    56 schema:sdDatePublished 2022-09-02T16:01
    57 schema:sdLicense https://scigraph.springernature.com/explorer/license/
    58 schema:sdPublisher Nd9529dbd7b224f56b6b53bf436c0c88d
    59 schema:url https://doi.org/10.1007/bf02638779
    60 sgo:license sg:explorer/license/
    61 sgo:sdDataset articles
    62 rdf:type schema:ScholarlyArticle
    63 N065babb10dde4e1d90070e652ba16aef schema:volumeNumber 35
    64 rdf:type schema:PublicationVolume
    65 N1ce8e5203b12418ca2f9efb93c9ea611 rdf:first sg:person.012476571651.61
    66 rdf:rest N3be5f8b812074dcc92500e3f28371ddb
    67 N3be5f8b812074dcc92500e3f28371ddb rdf:first sg:person.014423631546.73
    68 rdf:rest rdf:nil
    69 N648f3fd4719f46ee908634771ff6cc16 rdf:first sg:person.011073123343.10
    70 rdf:rest N1ce8e5203b12418ca2f9efb93c9ea611
    71 N8a9f4180070c458cbde3ed9d77732d8f schema:name doi
    72 schema:value 10.1007/bf02638779
    73 rdf:type schema:PropertyValue
    74 N9bedd0e355ce485fbb47072b6d63da0f schema:name dimensions_id
    75 schema:value pub.1020170096
    76 rdf:type schema:PropertyValue
    77 Nd9529dbd7b224f56b6b53bf436c0c88d schema:name Springer Nature - SN SciGraph project
    78 rdf:type schema:Organization
    79 Nf56423c67b10464c88725a534acdeffe schema:issueNumber 12
    80 rdf:type schema:PublicationIssue
    81 anzsrc-for:09 schema:inDefinedTermSet anzsrc-for:
    82 schema:name Engineering
    83 rdf:type schema:DefinedTerm
    84 anzsrc-for:0904 schema:inDefinedTermSet anzsrc-for:
    85 schema:name Chemical Engineering
    86 rdf:type schema:DefinedTerm
    87 sg:journal.1082739 schema:issn 0003-021X
    88 1558-9331
    89 schema:name Journal of the American Oil Chemists' Society
    90 schema:publisher Wiley
    91 rdf:type schema:Periodical
    92 sg:person.011073123343.10 schema:affiliation grid-institutes:grid.507314.4
    93 schema:familyName Mod
    94 schema:givenName Robert R.
    95 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011073123343.10
    96 rdf:type schema:Person
    97 sg:person.012476571651.61 schema:affiliation grid-institutes:grid.507314.4
    98 schema:familyName Magne
    99 schema:givenName Frank C.
    100 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012476571651.61
    101 rdf:type schema:Person
    102 sg:person.014423631546.73 schema:affiliation grid-institutes:grid.507314.4
    103 schema:familyName Skau
    104 schema:givenName Evald L.
    105 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014423631546.73
    106 rdf:type schema:Person
    107 sg:pub.10.1007/bf02539921 schema:sameAs https://app.dimensions.ai/details/publication/pub.1034951694
    108 https://doi.org/10.1007/bf02539921
    109 rdf:type schema:CreativeWork
    110 grid-institutes:grid.507314.4 schema:alternateName Southern Regional Research Laboratory, New Orleans, Louisiana
    111 schema:name Southern Regional Research Laboratory, New Orleans, Louisiana
    112 rdf:type schema:Organization
     




    Preview window. Press ESC to close (or click here)


    ...